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A printing and dyeing wastewater treatment method for cationic dyes

A cationic dye, printing and dyeing wastewater technology, applied in water/sewage treatment, water/sewage multi-stage treatment, special compound water treatment, etc. Achieve good regeneration efficiency, ensure decolorization effect, and effect of good removal effect

Active Publication Date: 2020-05-05
ZHEJIANG YINGSHANHONG TEXTILE TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional adsorbent is activated carbon, which has strong adsorption capacity and high removal rate, but the regeneration efficiency of activated carbon is low, the water quality of the treated water is difficult to meet the reuse requirements, the cost is high, and the application is limited
[0008] Patent CN101381173B discloses the application of foam separation technology to the treatment of anionic dye printing and dyeing wastewater, but the foam separation and decolorization process has undergone 4 times of decolorization, and the steps are cumbersome, which increases the treatment cost
In addition, the main advantage of the foam separation method is that it is suitable for the separation and recovery of low-concentration substances. In addition to low-concentration cationic dyes, printing and dyeing wastewater also contains a large number of other pollutants with medium concentrations. The direct use of foam separation methods is often not ideal. The effect of wastewater treatment will also affect the decolorization effect of the foam separation step

Method used

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  • A printing and dyeing wastewater treatment method for cationic dyes
  • A printing and dyeing wastewater treatment method for cationic dyes

Examples

Experimental program
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Effect test

Embodiment 1

[0034] A printing and dyeing wastewater treatment method for cationic dyes, the specific steps are as follows:

[0035] (1) Pre-test: detect the pigment component (basic violet 5BN) and its molar concentration of the cationic dye contained in the printing and dyeing wastewater;

[0036] (2) Static adsorption: Add an adsorbent to the printing and dyeing wastewater at a dosage of 0.8g / L, perform static adsorption for 30 minutes, filter to obtain the first treatment solution, and regenerate the adsorbent;

[0037] (3) Foam separation and decolorization: adjust the pH of the first treatment solution to 8, add an anionic surfactant, and use a bubble tower with a tower diameter of 32 mm to carry out decolorization treatment, the temperature is 16 ° C, and the gas volume flow rate is 0.005 m 3 / h, the height of the foam layer is 0.6m, and the decolorization treatment time is 20 minutes. After the foam layer is broken, the foam solution is obtained, and the cationic dye crude product ...

Embodiment 2

[0044] A printing and dyeing wastewater treatment method for cationic dyes, the specific steps are as follows:

[0045] (1) Pre-test: detect the pigment component (basic violet 5BN) and its molar concentration of the cationic dye contained in the printing and dyeing wastewater;

[0046] (2) Static adsorption: Add an adsorbent to the printing and dyeing wastewater at a dosage of 1 g / L, perform static adsorption for 40 minutes, filter to obtain the first treatment solution, and regenerate the adsorbent;

[0047] (3) Foam separation and decolorization: adjust the pH of the first treatment solution to 9, add an anionic surfactant, and use a bubble column with a tower diameter of 32mm to perform decolorization treatment at a temperature of 20°C and a gas volume flow rate of 0.007m 3 / h, the height of the foam layer is 0.8m, and the decolorization treatment time is 30 minutes. After the foam layer is broken, the foam solution is obtained, and the cationic dye crude product and the f...

Embodiment 3

[0054] A printing and dyeing wastewater treatment method for cationic dyes, the specific steps are as follows:

[0055] (1) Pre-test: detect the pigment component (basic brilliant blue BO) and its molar concentration of the cationic dye contained in the printing and dyeing wastewater;

[0056] (2) Static adsorption: Add an adsorbent to the printing and dyeing wastewater at a dosage of 0.8g / L, statically adsorb for 40 minutes, filter to obtain the first treatment solution, and regenerate the adsorbent;

[0057] (3) Foam separation and decolorization: adjust the pH of the first treatment solution to 8, add an anionic surfactant, and use a bubble tower with a tower diameter of 32mm to carry out decolorization treatment at a temperature of 20°C and a gas volume flow rate of 0.005m 3 / h, the height of the foam layer is 0.8m, and the decolorization treatment time is 20 minutes. After the foam layer is broken, the foam solution is obtained, and the cationic dye crude product and the ...

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Abstract

The invention discloses a wastewater treatment method for cationic dyes. Printing and dyeing wastewater is treated through three steps of early detection, static adsorption, and foam separation and decolorization, especially for the printing and dyeing wastewater containing the cationic dyes. Pigment components and the molar concentration of the cationic dyes contained in the printing and dyeing wastewater are determined by the early detection, which is convenient for determining the amount of an anionic surfactant used in the subsequent foam separation and decolorization step, and ensuring the decolorization effect; a adsorbent made from volcanic rock powder, cottonseed hull, dialdehyde starch is used to adsorb the printing and dyeing wastewater statically, so that most of the pollution components in the printing and dyeing wastewater can be adsorbed and removed, and the decolorization effect of the foam separation and decolorization step is ensured; according to the invention, a mixture of fatty alcohol ether phosphate ester and triethanolamine-lauryl sulfate in a specific ratio is used as the anionic surfactant; and the good decolorization effect can be achieved after the staticadsorption treatment and one foam separation and decolorization step.

Description

technical field [0001] The invention relates to a wastewater treatment method, in particular to a printing and dyeing wastewater treatment method for cationic dyes. The invention belongs to the technical field of waste water treatment. Background technique [0002] The printing and dyeing industry is a large discharge of industrial wastewater. The dye printing and dyeing wastewater discharged by it has a large amount of water, high concentration of organic pollutants, deep color, poor biochemical properties, large changes in water quality, and complex components. Therefore, printing and dyeing wastewater is a difficult industrial wastewater to treat. one. [0003] In the field of environmental engineering, dye molecules are often divided into the following three categories according to the ionic state dissociated in aqueous solution: [0004] 1. Cationic dyes, such as basic dyes; [0005] 2. Anionic dyes, such as direct dyes, acid dyes, etc.; [0006] 3. Non-ionic dyes, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/02B01J20/30B01J20/24C02F101/30
CPCB01J20/02B01J20/22B01J20/24C02F1/28C02F1/281C02F1/286C02F9/00C02F2101/308C02F2305/04
Inventor 孙淑娟周瑶瑶高江周华飞陈利华周建炳徐满容
Owner ZHEJIANG YINGSHANHONG TEXTILE TECH CO LTD
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