Method for producing zinc oxide by utilizing zinc-containing raw ore

A zinc oxide and raw ore technology, applied in the direction of zinc oxide/zinc hydroxide, etc., can solve the problems of poor comprehensive economic benefits, inability to handle, unsatisfactory leaching rate, etc., to solve the problems of process recovery rate and high-quality goods grade, and realize economical Environmentally friendly utilization and the effect of avoiding the pressure of water treatment

Inactive Publication Date: 2018-11-23
CHONGQING DONGQUN TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The selectivity of sulfuric acid leaching method is low, and a large amount of soluble silicon in the ore will be leached, and the generated colloidal silicon is difficult to filter, and the acid leaching method generates a large amount of sulfate residue, which causes great environmental protection treatment pressure; sulfuric acid leaching cannot effectively Treat the zinc silicate, zinc ferrite and other components in the ore
The calcium chloride method cannot effectively deal with the leaching of zinc silicate, zinc ferrite and other components in the raw ore, and the leaching rate is not ideal, requiring high temperature leaching, and the comprehensive economic benefits are not good
In the ammonium chloride method, after the raw ore is leached, the process of recovering the zinc component from the leaching solution is very difficult, which is not suitable for industrial application.
[0007] Therefore, the existing technology is not satisfactory for the utilization of low-grade zinc-containing raw ore

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0123] In a zinc mine in Yunnan, the zinc content is 5.6%, and the oxidation rate of the raw ore is 96.3%. The main form of zinc in this mine is zinc carbonate.

[0124] Get 300 grams of zinc-containing raw ore, put into 900 milliliters of ammonia-ammonium bicarbonate mixed solution (10% of total ammonia mass concentration, 3% of carbonate root mass concentration) and carry out stirring and leaching, the leaching temperature is normal temperature, and the stirring time is 2 hours, Then filter, the filtered liquid contains 1.632% zinc (in zinc oxide equivalent), and the carbonate mass concentration in the liquid is 4.23%, and the increased part is brought in by the zinc carbonate in the raw ore. According to the test data, the recovery rate of soluble zinc in the raw ore during the leaching process is 90.79%, and the recovery rate of total zinc is 87.43%.

[0125] The filtered leachate containing zinc ammonium ions is purified.

[0126] Take 600 ml of purified leaching solutio...

Embodiment 2

[0131] In a zinc mine in Chongqing, the zinc content is 4.7%, and the oxidation rate of the raw ore is 95.52%. The main form of zinc in this mine is zinc silicate.

[0132] Get 300 grams of zinc oxide raw ore, put into 900 milliliters of ammonia-ammonium bicarbonate mixed solution (10% of total ammonia mass concentration, 3% of carbonate root mass concentration) and carry out stirring and leaching, leaching temperature is normal temperature, stirring time is 2 hours, Then filter, after filtering, the zinc oxide in the liquid is 1.367%, the mass concentration of carbonate in the liquid is 3.54%, and the increased part is brought in by the zinc carbonate in the raw ore. According to the inspection data, the recovery rate of soluble zinc in the raw ore during the leaching process is 91.35%, and the recovery rate of total zinc is 87.26%.

[0133] The filtered leachate containing zinc ammonium ions is purified.

[0134] Take 600 ml of purified leaching solution, add 12.18 g of cal...

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PUM

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Abstract

The invention relates to a method for producing zinc oxide by utilizing zinc-containing raw ore. The method comprises an extraction step, an optional purification step, a decarburization step, a calcium zincate synthesis step, an optional rinsing step, a calcination step and a calcium and zinc separation step. According to the method provided by the invention, wet-process leaching and a synthesistechnology are combined to realize economical and environment-friendly utilization of low-grade zinc oxide ore and an applicable range is wide; ammonia steaming is not needed and the method is simpleand feasible; the energy consumption of a technology is greatly reduced; water treatment pressure, high-temperature and high-pressure potential safety hazards and equipment corrosion problems and thelike, which are caused by the ammonia steaming, are also avoided; the environment protection problem in an ammonia circulating problem that surplus water is brought by steam so that the balance of technological water is influenced is solved, and the problems of technological recovery rate and high-quality product grade are solved; the pollution is small and auxiliary materials are recyclable; thesynthesis of calcium zincate under a zinc-ammonia environment is realized for the first time; a zinc oxide product is produced through the calcium zincate.

Description

technical field [0001] The invention belongs to the technical field of inorganic chemical industry, relates to resource utilization of low-grade zinc-containing raw ore, in particular to a method for producing zinc oxide by using low-grade zinc oxide raw ore. Background technique [0002] The production and consumption of zinc in my country ranks first in the world. Domestic zinc resources cannot meet the production requirements, and a large amount of zinc raw materials need to be imported every year. my country is a country rich in zinc oxide resources. The reserves of zinc metal in zinc oxide ore in my country are about 28 million tons, accounting for about 27.7% of the zinc metal reserves in zinc oxide ore in the world. Zinc oxide mines in my country generally have a low zinc grade, with an average grade of less than 5%. At present, the stagnant ore and lean ore reserves that cannot be economically utilized account for the vast majority, among which the mining tailings co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G9/02
CPCC01G9/02C01P2006/80
Inventor 岳辉伟李世川龙忠祥蒋涛刘权锋
Owner CHONGQING DONGQUN TECH CO LTD
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