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Flame-retardant ethylene-propylene-diene monomer rubber sleeve for cables and preparation method thereof

A technology of EPDM rubber and cable, which is applied in the rubber field to achieve the effect of preventing combustion reaction

Inactive Publication Date: 2018-11-23
南通智达光缆材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The buffer layer of the cable is mostly composed of rubber. The existing rubber buffer layer can only play a buffer role. In the case of accidental fire, the rubber will decompose into flammable low-molecular substances at high temperature

Method used

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Examples

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preparation example Construction

[0013] The invention provides a method for preparing a flame-retardant EPDM rubber sheath for cables, the preparation method comprising:

[0014] a. Mix EPDM rubber, fumed white carbon black, chlorinated paraffin, aluminum hydroxide, hexabromocyclododecane, boehmite and sodium molybdate to make masterbatch;

[0015] B, vulcanizing agent and described masterbatch are mixed to carry out vulcanization treatment for the first time;

[0016] c. Carrying out the second vulcanization of the masterbatch after the first vulcanization in an oven to make flame-retardant EPDM rubber for cables;

[0017] d. Extruding the cable with flame-retardant EPDM rubber to make a flame-retardant EPDM rubber sheath for the cable.

[0018] In the step a of the present invention, the consumption of each raw material can be selected in a wide range, but in order to make the flame-retardant EPDM rubber sheath for the cable that makes have more excellent flame retardancy, preferably, in step a Among them...

Embodiment 1

[0027] a, the grade is EPDM rubber 100kg of 4770R, the grade is fumed white carbon black 180kg of A200, 5kg chlorinated paraffin-50, aluminum hydroxide 45kg, hexabromocyclododecane 6kg, boehmite 9kg and Sodium molybdate 0.8kg mixing is made masterbatch;

[0028] b. At 150°C and 11Mpa, mix 0.5 kg of bis-tert-butyl peroxide cumene and 100 kg of the above masterbatch for 17 minutes for the first vulcanization treatment;

[0029] c. At 215 ° C, the masterbatch after the first vulcanization is vulcanized for the second time in an oven for 4 hours to make flame-retardant EPDM rubber for cables;

[0030] d. Extrude the flame-retardant EPDM rubber for the above cable to make a flame-retardant EPDM rubber sheath A1 for the cable.

[0031] The flame retardant performance parameters of the flame retardant EPDM rubber sheath for the cable are shown in Table 1.

Embodiment 2

[0033] a, the grade is EPDM rubber 100kg of 4770R, the grade is fumed white carbon black 190kg of A200, 7kg chlorinated paraffin-50, aluminum hydroxide 55kg, hexabromocyclododecane 8kg, boehmite 10kg and Sodium molybdate 1.2kg mixing is made masterbatch;

[0034] b. At 170°C and 12Mpa, mix 0.8 kg of bis-tert-butyl peroxide cumene and 100 kg of the above masterbatch for 20 minutes for the first vulcanization treatment;

[0035] c. At 220 ° C, the masterbatch after the first vulcanization is vulcanized for the second time in an oven for 5 hours to make flame-retardant EPDM rubber for cables;

[0036] d. Extrude the flame-retardant EPDM rubber for the above cable to make a flame-retardant EPDM rubber sheath A2 for the cable.

[0037] The flame retardant performance parameters of the flame retardant EPDM rubber sheath for the cable are shown in Table 1.

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PUM

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Abstract

The invention discloses a flame-retardant ethylene-propylene-diene monomer rubber sleeve for cables and a preparation method thereof. The preparation method comprises the following steps: a, mixing ethylene-propylene-diene monomer rubber, gas-phase process white carbon black, chlorinated paraffin, aluminum hydroxide, hexabromocyclododecane, boehmite and sodium molybdate to prepare masterbatch; b,mixing a vulcanizing agent with the masterbatch to perform primary vulcanizing; c, performing secondary vulcanizing on the masterbatch subjected to the primary vulcanizing to prepare the flame-retardant ethylene-propylene-diene monomer rubber for the cables; d, performing extrusion molding on the flame-retardant ethylene-propylene-diene monomer rubber for the cables to prepare the flame-retardantethylene-propylene-diene monomer rubber sleeve for the cables. The flame-retardant ethylene-propylene-diene monomer rubber sleeve for the cables has excellent flame retardance.

Description

technical field [0001] The invention relates to rubber, in particular to a flame-retardant EPDM rubber sheath for cables. Background technique [0002] The buffer layer of the cable is mostly composed of rubber. The existing rubber buffer layer can only play a buffer role. In the case of an accidental fire, the rubber will decompose into flammable low-molecular substances at high temperatures. The flammable low-molecular-weight substances will quickly undergo a violent oxidation reaction with oxygen, and the oxidation reaction will release a large amount of heat, which will further promote the decomposition of rubber. Oxidation reaction until the rubber burns out. Contents of the invention [0003] The object of the present invention is to provide a flame-retardant EPDM rubber sheath for cables and a preparation method thereof. The flame-retardant EPDM rubber sheath for cables prepared by the method has excellent flame retardancy. [0004] In order to achieve the above o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/16C08L91/06C08K13/02C08K3/36C08K3/22C08K3/24C08K5/02C08K5/14C08J3/24
CPCC08L23/16C08J3/246C08J2323/16C08J2391/06C08K2003/2227C08L2201/02C08L2203/202C08L91/06C08K13/02C08K3/36C08K3/22C08K3/24C08K5/02C08K5/14
Inventor 姜智
Owner 南通智达光缆材料有限公司