Thermoplastic polyether ester elastomer foaming material and preparation method thereof

A technology of thermoplastic polyether ester and foaming materials, which is applied in the field of preparation of thermoplastic polyether ester TPEE elastomer foaming materials, which can solve problems such as difficulty in continuous foaming and preparation of foaming materials with stable performance, and achieve excellent appearance Effect

Active Publication Date: 2018-11-23
NANTONG DE NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of the present invention is exactly to provide a kind of thermoplastic polyether ester elastomer foaming material and preparation method thereof in order to overcome the defective that above-mentioned prior art exists, specifically propose the

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  • Thermoplastic polyether ester elastomer foaming material and preparation method thereof
  • Thermoplastic polyether ester elastomer foaming material and preparation method thereof

Examples

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Example Embodiment

[0038] Example 1

[0039] A thermoplastic polyether ester elastomer foaming material, wherein the necessary raw materials are: 80 parts of polyether ester TPEE, 0.5 parts of nucleating agent, and 1.5 parts of foaming agent. Among them, the melting temperature T of polyether ester TPEE 2 (Test standard ISO11357) and Vicat softening point temperature T 1 (Test standard ISO 306) difference T 2 -T 1 =75°C, tensile strength (test standard ISO 527)=25Mpa, elongation at break (test standard ISO527) is approximately equal to 850%, the nucleating agent is modified nano-calcium carbonate, and the blowing agent is carbon dioxide.

[0040] In this embodiment, the foam material is preferably prepared by underwater pelletizing and foaming, and the specific process is as follows:

[0041] (1): Take polyether ester TPEE and other raw material components other than foaming agent and add them to the twin-screw extruder, control the temperature to the melting temperature of the material, so ...

Example Embodiment

[0058] Example 2

[0059] A thermoplastic polyether ester elastomer foaming material, wherein the necessary raw materials are: 50 parts of polyether ester TPEE, 0.05 part of nucleating agent, and 0.1 part of foaming agent. Among them, the melting temperature T of polyether ester TPEE 2 (Test standard ISO11357) and Vicat softening point temperature T 1 (Test standard ISO 306) difference T 2 -T 1 It is about 30°C, the tensile strength (test standard ISO 527) is about 30Mpa, the elongation at break (test standard ISO527) is about 600%, the nucleating agent is 2-10um talcum powder, and the foaming agent is nitrogen.

[0060] In this embodiment, the foam material is prepared by underwater granulation and foaming, and the specific process is as follows:

[0061] (1): Take polyether ester TPEE and other raw material components other than the foaming agent and add them to the twin-screw extruder, so that the material is hot-melted under the action of high temperature, high pressur...

Example Embodiment

[0065] Example 3

[0066] A thermoplastic polyether ester elastomer foaming material, wherein the necessary raw materials are: 95 parts of polyether ester TPEE, 0.1 part of nucleating agent, and 5 parts of foaming agent. Among them, the melting temperature T of polyether ester TPEE 2 (Test standard ISO11357) and Vicat softening point temperature T 1(Test standard ISO 306) difference T 2 -T 1 ≥30°C, tensile strength (test standard ISO 527) ≥15Mpa, elongation at break (test standard ISO527) ≥300%, nucleating agent is modified montmorillonite, foaming agent is carbon dioxide and nitrogen by volume ratio 1 :1 mix.

[0067] In this embodiment, the foam material is prepared by underwater granulation and foaming, and the specific process is as follows:

[0068] (1): Take polyether ester TPEE and other raw material components other than the foaming agent and add them to the twin-screw extruder, so that the material is hot-melted under the action of high temperature, high pressure...

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Abstract

The invention relates to a thermoplastic polyether ester elastomer foaming material and a preparation method thereof. The foaming material is prepared from the following raw material components in parts by weight: 50 to 95 parts of polyether ester TPEE (Thermoplastic Polyether Ester Elastomer), 0 to 50 parts of a modified polymer material, 0.05 to 2 parts of a nucleating agent and 0.1 to 5 parts of a foaming agent; when the adding amount of the modified polymer material is 0, the difference (T2-T1) of the melting temperature T2 of the polyether ester TPEE and the Vicat softening point temperature T1 is greater than or equal to 30 DEG C. Compared with the prior art, a continuous foaming formula and a continuous foaming technology of the TPEE are provided, and the problems that the foaming material with stale performance is difficult to prepare by existing TPEE, especially continuous foaming is difficult to realize are solved.

Description

technical field [0001] The invention belongs to the technical field of polymer foaming materials, and relates to a preparation method of a thermoplastic polyether ester TPEE elastomer foaming material. Background technique [0002] Thermoplastic polymer elastic materials are widely used in various production and living facilities, equipment, tools and consumables. With the development of society, the demand for environmental protection, energy saving, consumption reduction, etc., the demand for lightweight materials has become more and more more urgent. Thermoplastic polymer elastic materials have also begun a large number of lightweight experiments and verifications and continued to promote their applications. For example, polypropylene PP foam, polyethylene PE foam, polystyrene PS foam, polyester PET foam, polyamide PA foam and polyurethane TPU foam, etc. The melt strength of thermoplastic polyetherester elastomer TPEE is low, and the polyester part of the skin of the me...

Claims

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Application Information

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IPC IPC(8): C08L67/00C08K3/26C08K3/34C08J9/12C08J9/14
CPCC08J9/122C08J9/141C08J2203/06C08J2203/14C08J2203/182C08J2367/00C08K3/34C08K3/346C08K2003/265C08K2201/011
Inventor 陈乔健郭杨龙
Owner NANTONG DE NEW MATERIAL CO LTD
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