Weeding agent composition containing pentafluorosurochlor and pyrimethuron
A technology of penoxsulam and pyrimifen, applied in the field of pharmaceutical compounds, can solve problems such as water quality degradation, unfavorable weed control, soil pollution, etc., and achieve the effects of improving control and ensuring normal growth
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Embodiment 1
[0024] The present invention provides a technical solution, a herbicide composition of penoxsulam and pyrizamid, which comprises the following formula composition: penoxsulam, pyrizamid and oxazicone, mixed in a certain proportion , the formula is made of the following raw materials in parts by weight: 3-7 parts by weight of penoxsulam, 3-6 parts by weight of pyriflumexime, and 5-9 parts by weight of oxaziclozone.
[0025] According to the above technical scheme, the preparation method of penoxsulam: under the protection of nitrogen, dissolve sodium hydride in 1,2-methoxyethane, cool to 10°C in an ice bath, add intermediates, and react slightly Exothermic, cool to 6°C with an ice bath, after 10 minutes, add 2,2-difluoroethanol, the reaction is slightly exothermic, after about 1 hour, remove the ice bath, the temperature rises to about 28°C, the reaction solution is stirred overnight, At 5-10°C, add 5% hydrochloric acid into the reaction solution, cool it in an ice bath, stir t...
Embodiment 2
[0028] The present invention provides a technical solution, a herbicide composition of penoxsulam and pyriflubac-methyl, which comprises the following formula composition: penoxsulam, pyrimiflubac-methyl and pyrazosulfuron-methyl, mixed in a certain proportion Composition, the formula is made of the following raw materials in parts by weight: 3-7 parts by weight of penoxsulam, 3-6 parts by weight of pyriflumefen, and 4-8 parts by weight of closulfuron-methyl.
[0029] According to the above technical scheme, the preparation method of penoxsulam: under the protection of nitrogen, dissolve sodium hydride in 1,2-methoxyethane, cool to 10°C in an ice bath, add intermediates, and react slightly Exothermic, cool to 6°C with an ice bath, after 10 minutes, add 2,2-difluoroethanol, the reaction is slightly exothermic, after about 1 hour, remove the ice bath, the temperature rises to about 28°C, the reaction solution is stirred overnight, At 5-10°C, add 5% hydrochloric acid into the rea...
Embodiment 3
[0036] The present invention provides a technical solution, a herbicide composition of penoxsulam and pyrizachlor, which comprises the following formula composition: penoxsulam, pyrizachlor and pretilachlor, mixed in a certain proportion, The formula is made of the following raw materials in parts by weight: 3-7 parts by weight of penoxsulam, 3-6 parts by weight of pyrizachlor, and 20-40 parts by weight of pretilachlor.
[0037] According to the above technical scheme, the preparation method of penoxsulam: under the protection of nitrogen, dissolve sodium hydride in 1,2-methoxyethane, cool to 10°C in an ice bath, add intermediates, and react slightly Exothermic, cool to 6°C with an ice bath, after 10 minutes, add 2,2-difluoroethanol, the reaction is slightly exothermic, after about 1 hour, remove the ice bath, the temperature rises to about 28°C, the reaction solution is stirred overnight, At 5-10°C, add 5% hydrochloric acid into the reaction solution, cool it in an ice bath, ...
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