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A kind of magnetic microalgae biological adsorption flocculant and method for adsorbing chromium in waste water

A technology of microalgae and flocculant, applied in biological water/sewage treatment, chemical instruments and methods, water pollutants, etc., can solve the problems of difficult separation, inability to metabolize heavy metals, etc., and achieve large adsorption capacity and good removal effect. , the effect of fast adsorption rate

Active Publication Date: 2022-01-18
ZHEJIANG OCEAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It is difficult to separate the adsorbent from wastewater after adsorption, and dead algae cannot metabolize heavy metals, so complex desorption treatment is required for recycling

Method used

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  • A kind of magnetic microalgae biological adsorption flocculant and method for adsorbing chromium in waste water

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A magnetic microalgae biosorption flocculant, including chlorella, magnetic Fe 3 o 4 Nanoparticles, konjac glucomannan and modified carbon fibers. The mass ratio of the modified carbon fiber to konjac glucomannan is 1:7. Its preparation method comprises the following steps:

[0030] (1) Microalgae were inoculated in BG11 medium, and the temperature was 25°C, the shaking frequency was 160rpm, and the light condition was 100μmolm. -2 the s -1 Under the condition of culturing to a concentration of 6.5×10 7 a / mL;

[0031] (2) Add magnetic Fe to the medium 3 o 4 Nanoparticles, add 0.2g magnetic Fe per liter of algae liquid 3 o 4 Nanoparticles, shaken at constant temperature for 3 days to obtain microalgae and magnetic Fe 3 o 4 a polymer solution of nanoparticles;

[0032] (3) Add konjac glucomannan and modified carbon fiber to the polymer solution and mix evenly to obtain a mixed solution. The concentration of konjac glucomannan in the mixed solution is 2.5wt%; ...

Embodiment 2

[0040] A magnetic microalgae biosorption flocculant, including Scenedesmus, magnetic Fe 3 o 4 Nanoparticles, konjac glucomannan and modified carbon fibers. The mass ratio of the modified carbon fiber to konjac glucomannan is 1:6. Its preparation method comprises the following steps:

[0041] (1) Microalgae were inoculated in BG11 medium, and the temperature was 30°C, the shaking frequency was 220rpm, and the light condition was 150μmolm. -2 the s -1 Under the condition of culturing to a concentration of 8×10 7 a / mL;

[0042] (2) Add magnetic Fe to the medium 3 o 4 Nanoparticles, add 0.3g magnetic Fe per liter of algae liquid 3 o 4 Nanoparticles, shaken at constant temperature for 4 days to obtain microalgae and magnetic Fe 3 o 4 a polymer solution of nanoparticles;

[0043] (3) Add konjac glucomannan and modified carbon fiber to the polymer solution and mix evenly to obtain a mixed solution. The concentration of konjac glucomannan in the mixed solution is 3wt%; th...

Embodiment 3

[0051] A magnetic microalgae biosorption flocculant, including botrytis, magnetic Fe 3 o 4 Nanoparticles, konjac glucomannan and modified carbon fibers. The mass ratio of the modified carbon fiber to konjac glucomannan is 1:8. Its preparation method comprises the following steps:

[0052] (1) Microalgae were inoculated in BG11 medium, and the temperature was 20°C, the shaking frequency was 100rpm, and the light condition was 50μmolm. -2 the s -1 Under the condition of culturing to a concentration of 5×10 7 a / mL;

[0053] (2) Add magnetic Fe to the medium 3 o 4 Nanoparticles, add 0.1g magnetic Fe per liter of algae liquid 3 o 4 Nanoparticles, shake at constant temperature for 2 days, get microalgae and magnetic Fe 3 o 4 a polymer solution of nanoparticles;

[0054] (3) Add konjac glucomannan and modified carbon fiber to the polymer solution and mix evenly to obtain a mixed solution. The concentration of konjac glucomannan in the mixed solution is 2wt%; the mixed so...

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Abstract

The invention relates to the technical field of wastewater treatment, and discloses a magnetic microalgae biological adsorption flocculant and a method for adsorbing chromium in wastewater. The magnetic microalgae biosorption flocculant of the present invention comprises microalgae, magnetic Fe 3 o 4 Nanoparticles, konjac glucomannan and modified carbon fibers. Microalgae and Magnetic Fe 3 o 4 Nanoparticle polymers were then mixed and embedded with konjac glucomannan to prepare magnetic microalgae biosorbent flocculants. The modified carbon fiber itself and the konjac glucomannan are cross-linked to form a network structure, which can increase the strength of the magnetic microalgae biosorption flocculant. The magnetic microalgae biological adsorption flocculant has the advantages of large adsorption capacity, fast adsorption rate, simple and convenient operation and the like. It contains magnetic Fe 3 o 4 Nanoparticles can facilitate the rapid recovery of adsorbents after wastewater treatment. The magnetic microalgae bioabsorption flocculant was used for the adsorption and removal of heavy metal ion chromium in wastewater, and a good removal effect was obtained.

Description

technical field [0001] The invention relates to the technical field of wastewater treatment, in particular to a magnetic microalgae biological adsorption flocculant and a method for adsorbing chromium in wastewater. Background technique [0002] Heavy metal chromium pollution mainly comes from inferior cosmetic raw materials, leather preparations, chrome-plated parts of metal parts, industrial pigments, leather tanning, rubber and ceramic raw materials, etc. These pollution sources enter the water environment through industrial and domestic sewage discharges, causing harm to human health and the ecological environment. Great threat. [0003] Common heavy metal chromium treatment methods include chemical precipitation, ion exchange, adsorption and other methods. The adsorption method for the removal of heavy metal pollutants in wastewater has the advantages of flexible and convenient operation, advanced treatment, and the recovery of heavy metal ions in wastewater through de...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/24B01J20/28B01J20/30C02F3/32C02F101/20
CPCB01J20/06B01J20/24C02F3/322B01J20/28009C02F2101/20B01J2220/4825B01J2220/46
Inventor 李晨高锋侯慧巧阚家薇寿晔子张文静
Owner ZHEJIANG OCEAN UNIV