A kind of SBS adhesive and preparation method thereof
An adhesive, SIS1105 technology, applied in the direction of adhesives, adhesive types, conjugated diene adhesives, etc. The effect of enhanced viscosity, improved adhesion, and increased adhesion
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Embodiment 1
[0027] S1. Completely dissolve the combined rubber of SBS792, SIS1105 and star-shaped SBSLG411 in mass parts of 4.4:2.9:2.9 in the mixed solvent at room temperature to obtain a mixed solution. Described mixed solvent is made up of toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride, wherein, toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride The mass-to-number ratio is 8.5:0.5:4.9:3.7:38:4.9.
[0028] S2. Add 1.6 parts by mass of oleum with a concentration of 20% to the mixed solution obtained in S1, stir at 35°C to cause sulfonation reaction for 3.5 hours, and add 2.2 parts by mass after the sulfonation reaction is completed. 20% urea methanol solution to reduce and neutralize excess oleum, reduce and neutralize excess oleum.
[0029] S3. Add styrene-butadiene rubber SBR1502 with a mass fraction of 4.2, antioxidant 1010 and tackifier resin with a mass fraction of 0.15 to the sulfonated solution obta...
Embodiment 2
[0031] S1. Completely dissolve the combined rubber of SBS792, SIS1105 and star-shaped SBSLG411 in mass parts of 4.4:2.9:2.9 in the mixed solvent at room temperature to obtain a mixed solution. Described mixed solvent is made up of toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride, wherein, toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride The mass-to-number ratio is 8.5:0.5:4.9:3.7:38:4.9.
[0032] S2. Add 1.2 parts by mass of fuming sulfuric acid with a concentration of 20% to the mixed solution obtained in S1, stir at 35°C for 3 hours, and add 1.8 parts by mass of oleum after the sulfonation reaction is completed. 20% urea methanol solution reduces and neutralizes excess oleum, reduces and neutralizes excess oleum.
[0033] S3. Add 3.5 parts by mass of styrene-butadiene rubber SBR1502, 0.15 parts by mass of antioxidant 1010 and tackifying resin to the sulfonated solution obtained in S2, stir and...
Embodiment 3
[0035]Embodiment 3 is a non-sulfonated SBS adhesive, which is a comparative test. The mass parts are SBS792: SIS1105: star SBS LG411: SBR1502 = 4.4: 2.9: 2.9 combined rubber, the mass parts are terpene resin T-100: C5 petroleum resin: rosin = 9.7: 7.3: 4.3 thickening Resin, 0.15 parts by mass of antioxidant 1010, dissolved in a mixed solvent, and prepared into a non-sulfonated modified SBS adhesive. Wherein, mixed solvent is made up of toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride, and the mass parts of toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride The ratio is 8.5:0.5:4.9:3.7:38:4.9.
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