The invention discloses a double-component acrylate structure adhesive for bonding electrophoretic coating materials and a preparation method of the structure adhesive, belonging to the technical field of adhesives. The structure adhesive is prepared by mixing a component A with a component B according to a volume ratio of 10 : (0.1-2), wherein the component A comprises acrylate monomers, acrylic resin, strongly acidic monomers, non-polar rubber, flexible rubber, non-polar organic particles, an accelerator, a stabilizer and paraffin; the component B comprises an initiator, a plasticizer, a thickener and pigment. The structure adhesive can be used for effectively bonding and quickly curing electrophoretic coatings, is high in stripping strength and shear strength, and has the characteristics of being convenient to apply, good in room-temperature storage stability and the like; the bonding surface destruction form is cohesive failure of an adhesive layer.