Self-cleaning high anti-reflection coating solution and preparation method thereof, and self-cleaning high anti-reflection solar glass
A self-cleaning, solution-based technology, applied in glass tempering, glass manufacturing equipment, manufacturing tools, etc., can solve problems such as difficult to clean, solar glass adhesion, etc., achieve the effect of increasing light transmittance, improving self-cleaning effect, and reducing dosage
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Embodiment 1
[0038] First, the preparation of self-cleaning high-reflection coating solution:
[0039] Step a: Preparation of cationic polystyrene emulsion by soap-free emulsion polymerization:
[0040] According to the mass percentage, the 2% comonolymer acryloyloxyethyl trimethoxy ammonium chloride and 82.5% water were placed in the reaction vessel, 15% styrene was added for stirring, heated to 50 ° C under nitrogen protection, and then 0.5% potassium persulfate initiator aqueous solution was added dropwise, and the cationic polystyrene emulsion was obtained after the reaction.
[0041]Step b, the cationic polystyrene emulsion and solvent ethanol are mixed evenly, the amount of solvent is diluted to dilute the cationic polystyrene emulsion to a solid content of 1%, and then under the condition of stirring at 15 °C, the silicon source material tetramethoxysilane is added to react to obtain a silica coated polystyrene nano-core shell silica microglobule sol. In this step, the mass ratio of the...
Embodiment 2
[0048] The main technical solution of the present embodiment is the same as That of Example 1, the differences are:
[0049] First, the preparation of self-cleaning high-reflection coating solution:
[0050] Step a: Preparation of cationic polystyrene emulsion by soap-free emulsion polymerization:
[0051] According to the percentage of mass, the 2% methacryloyloxyethyltrimethyl ammonium chloride and 2% acryloylaminopropyltrimethyl ammonium chloride of the comonomer monomer, 75% water in the reaction vessel, add 20% styrene stirred, heated to 65 ° C under nitrogen protection, and then added 1% azo diisobutyl amamidamidine hydrochloric acid initiator aqueous solution dropwise, after the reaction to obtain a cationic polystyrene emulsion.
[0052]Step b: Mix the cationic polystyrene emulsion and solvent evenly, and then under the condition of stirring at 20 °C, add a silicon source substance to react to obtain a silica-coated nano-core shell silica microglobule sol coated with polys...
Embodiment 3
[0058] The main technical solution of the present embodiment is the same as That of Example 1, the differences are:
[0059] First, the preparation of self-cleaning high-reflection coating solution:
[0060] Step a: Preparation of cationic polystyrene emulsion by soap-free emulsion polymerization:
[0061] According to the mass percentage, the 0.2% dimethylaminoethyl acrylate and 0.3% diethylaminoethyl methacrylate of the comonomer monomer, 89.4% water in the reaction vessel, add 10% styrene stirred, heated to 73 ° C under nitrogen protection, and then add 0.1% ammonium persulfate and sodium persulfate according to the volume ratio of 1:2 mixed initiator aqueous solution, after the reaction to obtain a cationic polystyrene emulsion.
[0062]Step b, the cationic polystyrene emulsion and solvent mixed evenly, the amount of solvent is to dilute the cationic polystyrene emulsion to a solid content of 17%, and then under the condition of stirring at 28 °C, add a silicon source substanc...
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