Purine dione as wnt pathway modulator
A pathway and compound technology, applied in anti-inflammatory agents, non-central analgesics, medical preparations containing active ingredients, etc.
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[0224] The following examples provide compounds according to the invention as well as a number of general synthetic schemes for their preparation. Each synthetic scheme has been illustrated with a specific example, and the examples that follow can be prepared by this same general method. Those skilled in the art will readily understand the changes required for the illustrated examples of each synthetic scheme to prepare other related compounds.
[0225] Amine Synthesis
[0226] Suzuki Method A: A stirred solution of aryl halide (1 equiv), boronic acid (1.5 equiv) and sodium carbonate (2 equiv) in toluene (0.08M) and water (0.32M) was charged with argon. Degas for 15 minutes. Tetrakis(triphenylphosphine)palladium(0) (0.05 equiv) was added to the reaction mixture and the reaction mixture was heated to reflux for 16 hours. After the starting material was consumed, the reaction mixture was concentrated and water was added to the reaction mixture and extracted with ethyl acetate...
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