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Application of a rare earth barium copper oxide material in making high magnetic field superconducting tape or wire

A technology of rare earth barium copper oxide and superconducting tape, which is applied in the usage of superconducting elements, oxide conductors, superconducting devices, etc., can solve the problems of single rare earth element and Yb not appearing, and achieve large critical current density, Good application prospects and excellent strong magnetic field characteristics

Active Publication Date: 2020-05-05
NORTHEASTERN UNIV LIAONING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] When the rare-earth barium-copper-oxygen high-temperature superconducting materials mentioned in the prior art, the RE therein is usually a single rare earth element, or is yttrium (Y), gadolinium (Gd), samarium (Sm), neodymium ( Nd), europium (Eu), dysprosium (Dy), holmium (Ho), erbium (Er), or a combination of two or more, of which there are few related ytterbium-barium-copper oxide materials YbBa 2 Cu 3 o 7-δ There are almost no reports on the application of materials in superconducting strips or wires, and there are almost no research reports on the characteristics and applications of rare earth barium copper oxide superconducting materials containing ytterbium (Yb) ions.
This is mainly because: Most of the previous studies on the optimal selection of rare earth elements RE in REBCO superconducting materials were carried out at 77K temperature, but due to the critical temperature Tc and 77K temperature of the rare earth barium copper oxide material containing ytterbium The current density Jc is relatively low, which makes most researchers almost give up the research and exploration of rare earth barium copper oxide materials containing Yb ions, and causes Yb in rare earth barium copper oxide superconducting materials to never appear in actual production applications.

Method used

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  • Application of a rare earth barium copper oxide material in making high magnetic field superconducting tape or wire
  • Application of a rare earth barium copper oxide material in making high magnetic field superconducting tape or wire

Examples

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Embodiment 1

[0035] This embodiment involves a Gd 0.5 Yb 0.5 Ba 2 Cu 3 o 7-δ It is a superconducting strip of constituent material, and its width is 4 mm. Under 30K temperature and 4.2K temperature respectively to the superconducting strip material of present embodiment, when the magnetic field intensity is constantly raised between 1T~10T, test its critical current I C The change curve with the increase of magnetic field intensity, the result is as follows figure 1 Shown (the abscissa indicates the magnetic field strength T = 1 ~ 10T, and the ordinate indicates the current value of the superconducting strip with a width of 4 mm).

[0036] Preparation:

[0037] REBCO superconducting thin films can be prepared by metal-organic chemical vapor deposition (MOCVD), pulsed laser deposition (PLD) or reactive electron beam co-evaporation (REC). The preparation method of REBCO superconducting tape with Yb is essentially the same as that of REBCO superconducting tape without Yb, except that d...

Embodiment 2

[0044] This embodiment involves a Gd 0.5 Yb 0.5 Ba 2 Cu 3 o 7-δ It is a superconducting thin film composed of materials, and its thickness is about 750nm. Gd of this embodiment 0.5 Yb 0.5 Ba 2 Cu 3 o 7-δ The superconducting thin film is placed in a working environment with a magnetic field strength of 3T, and the temperature is changed between 10K and 77K to test its critical current density J C The change curve with increasing temperature, the results are as follows figure 2 shown.

[0045] In this embodiment, Gd 0.5 Yb 0.5 Ba 2 Cu 3 o 7-δ The superconducting thin film as the constituent material is prepared by MOCVD method.

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Abstract

The invention relates to a superconducting strip or wire applied to a strong magnetic field. A superconducting material is a rare earth barium copper oxide material. A molecular formula is REBa<2>Cu<3>O<7-delta> (REBCO for short). RE is Yb or rare earth ion combination containing the Yb. A rare earth barium copper oxide superconducting material containing the Yb shows an excellent strong magneticfield characteristic under a temperature environment below 50K, in particular, under a temperature below 20K and a strong magnetic field. Critical current density of the REBCO superconducting materialcontaining the Yb is higher than that of the superconducting material containing no Yb. Speed that the critical current density of the REBCO superconducting material containing the Yb is risen and reduced along with magnetic field intensity is slower than the speed that the critical current density of the superconducting material containing no Yb is risen and reduced along with the magnetic fieldintensity. The superconducting strip or wire provided by the invention can be used as a coil winding superconducting material in any strong magnetic field and strong electric device such as magneticresonance imaging, an particle accelerator, a thermonuclear fusion reactor, a tokamak, magnetic separation mineral processing, a motor, a generator and a magnetic energy storage system.

Description

technical field [0001] The invention relates to the technical field of superconducting materials, in particular to a high-temperature superconducting wire or strip with excellent strong magnetic field properties. Background technique [0002] In most strong electric applications, superconducting wires work in a strong magnetic field, so improving the critical current of superconducting wires in a strong magnetic field, that is, high field characteristics (or high magnetic field characteristics), is a key in the field of superconducting materials topic. Rare earth barium copper oxide (REBa 2 Cu 3 o 7-δ , or abbreviated as REBCO, where RE is a rare earth element, such as Y, Gd, Sm, etc.) The high-temperature superconducting film is the core component of the second-band high-temperature superconducting wire, which has excellent loading at liquid nitrogen temperature (77K) At the same time, the rare earth barium copper oxide has the strongest upper critical magnetic field am...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B1/08H01B12/06
CPCY02E40/60
Inventor 陈一民姜平章曙东
Owner NORTHEASTERN UNIV LIAONING
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