High fusion bonding strength glass fiber reinforced polypropylene composite material and preparation method thereof

A technology of composite materials and grafted polypropylene, which is applied in the field of high weld line strength glass fiber reinforced polypropylene composite materials and its preparation, can solve the problems of limited increase in polarity, etc., to improve the strength of weld lines and enhance the strength of weld lines Effect

Inactive Publication Date: 2020-01-17
GUANGDONG IND TECHN COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Both of the above two patent applications use chlorosulfonated polyethylene, which plays the role of toughening and improving impact strength. It is a high molecular weight substance, and its molecular weight is much higher than that of sulfonated polyolefin wax. Although chlorosulfonated polyethylene Polyethylene has polar groups and can also increase the polarity in composite materials, but because of its high molecular weight, the increase in polarity is very limited
Therefore, the improvement of the weld line strength by chlorosulfonated polyethylene is very limited, and it can only improve the toughness and impact strength

Method used

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Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0033] In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in combination with the claims and specific embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.

[0034] The raw materials used in the embodiments of the present invention and comparative examples are as follows:

[0035] Polypropylene: Maoming Petrochemical N-Z30S, MFR 25g / 10min;

[0036] Sulfonated polyolefin wax A: the degree of sulfonation is 0.6mmol / g, and the number average molecular weight is about 6000;

[0037] Sulfonated polyolefin wax B: the degree of sulfonation is 0.3mmol / g, and the number average molecular weight is about 5600;

[0038] Sulfonated polyolefin wax C: The degree of sulfonation is 1.0 mmol / g, and the number average molecular weight is about 5800.

[0039] Maleic anhydrid...

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Abstract

The invention relates to a high fusion mark strength glass fiber reinforced polypropylene composite material which comprises the following components in parts by weight: 100 parts of polypropylene, 0.1-2 parts of sulfonated polyolefin wax, 1-10 parts of maleic anhydride grafted polypropylene and 1-50 parts of glass fiber. Due to addition of the sulfonated polyolefin wax and the maleic anhydride grafted polypropylene in compounding of glass fiber reinforced polypropylene, the sulfonated polyolefin wax is enriched at a front flowing end in injection molding, therefore, strong polar groups of a high density are formed at a weld mark, the intermolecular interactions at the weld mark can be greatly improved, and thus the strength of the weld mark of the glass fiber reinforced polypropylene canbe improved.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a glass fiber reinforced polypropylene composite material with high weld line strength and a preparation method thereof. Background technique [0002] After reinforced with glass fiber, polypropylene can greatly improve its strength, rigidity, impact strength and heat distortion temperature, so it is widely used in automobiles, building materials, home appliances and other industries. However, in the application process, it is often found that the position of the weld line of the reinforced polypropylene injection molded part becomes the failure initiation point of the part. This is because although the addition of glass fiber can greatly improve the strength of the material, it is difficult to improve the strength of the weld line. In general, the strength of glass fiber-reinforced weld lines is not higher than that of matrix resin, which is mainly due to the poor com...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/26C08L51/06C08K7/14C08J5/04
CPCC08J5/043C08J2323/12C08J2423/26C08J2451/06C08K7/14
Inventor 陈大华谭寿再陈金伟何亮刘青山
Owner GUANGDONG IND TECHN COLLEGE
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