Anti-freezing microwave-resistant starch-based tableware and preparation method thereof

A microwave-resistant, starch-based technology, applied in the field of tableware materials, can solve the problems of white pollution, poor hardness, hardening and brittleness, etc., and achieve the effects of improving the strength of weld lines, improving the dispersion effect, and good processability

Active Publication Date: 2020-03-20
江苏中科成长环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the existing fast food is made of polypropylene (PP) material. With the increase of the consumption, the phenomenon of white pollution becomes serious. Plastic pollution, orderly prohibit and restrict the production, sale and practical use of some plastic products, and actively promote recyclable and easily recyclable degradable alternative products
[0003] As an upgraded product of plastic tableware, starch-based materials are usually used to replace some plastic materials. It is acceptable to use starch-based tableware to prepare ordinary tableware, but when low temperature (-18°C) freshness is required, conventional starch-based lunch boxes are used. , the lunch box becomes hard and brittle, and is easily damaged during handling; and after microwave heating, the strength of the lunch box becomes lower and cannot be used normally
[0004] Chinese patent CN 106496652A discloses a starch-foamed disposable tableware, which consists of 86-93 parts by weight of modified corn starch, 0.8-1.2 parts by weight of zinc stearate release agent, and 0.2-0.4 parts by weight of accelerator Potassium sorbate, 1.5 to 2 parts by weight of thickener sodium polyacrylate, 45 to 53 parts by weight of stabilizer, and several parts by weight of water are mixed and stirred to obtain the mixture, and then obtained by hot pressing, although the invention adopts a relatively A large amount of cornstarch is used as a raw material to reduce costs and is safe and environmentally friendly. However, the disposable tableware made from it does not have frost resistance. It becomes hard and brittle after low-temperature freezing, and the hardness becomes poor after heating. It can only be used as ordinary tableware. Used in trains, high-speed rail and other fast food industries that require low-temperature freezing and fresh-keeping transportation

Method used

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  • Anti-freezing microwave-resistant starch-based tableware and preparation method thereof
  • Anti-freezing microwave-resistant starch-based tableware and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A starch-based tableware with antifreeze and microwave resistance, which is composed of the following components in mass percentage:

[0036] Polypropylene 28%

[0037] Starch 60%

[0038] Antifreeze 10%

[0039] LT-1 aluminum titanium composite coupling agent 2%

[0040] Titanate coupling agent 1%.

[0041] The antifreeze agent is prepared by mixing and granulating the following components, wherein the content of vinyl acetate in ethylene vinyl acetate copolymer is 20%, the content of acrylic acid in ethylene acrylic acid copolymer is 25%, ethylene vinyl acetate copolymer, ethylene The acrylic acid copolymer is fed into the screw extruder by side feeding during the antifreeze granulation process, and the extrusion granulation temperature range is 140°C.

[0042] Ethylene vinyl acetate copolymer 10%

[0043] Ethylene acrylic acid copolymer 20%

[0044] Polyethylene 3%

[0045] Maleic anhydride 2%

[0046] Polyolefin Elastomer Balance.

[0047] A preparation met...

Embodiment 2

[0055] A starch-based tableware with antifreeze and microwave resistance, which is composed of the following components in mass percentage:

[0056] Polypropylene 35%

[0057] Starch 47%

[0058] Antifreeze 15%

[0059] LT-1 aluminum titanium composite coupling agent 1%

[0060] Titanate coupling agent 0.5%.

[0061] The antifreeze agent is prepared by mixing and granulating the following components, wherein the content of vinyl acetate in the ethylene vinyl acetate copolymer is 30%, the content of acrylic acid in the ethylene acrylic acid copolymer is 20%, and the ethylene vinyl acetate copolymer 1. Ethylene acrylic acid copolymer is added to the screw extruder by side feeding during the antifreeze granulation process, and the extrusion granulation temperature range is 120°C.

[0062] Ethylene vinyl acetate copolymer 15%

[0063] Ethylene acrylic acid copolymer 15%

[0064] Polyethylene 5%

[0065] Maleic anhydride 1%

[0066] Polyolefin Elastomer Balance.

[0067] A...

Embodiment 3

[0075] A starch-based tableware with antifreeze and microwave resistance, which is composed of the following components in mass percentage:

[0076] Polypropylene 33%

[0077] Starch 60%

[0078] Antifreeze 5%

[0079] LT-1 aluminum titanium composite coupling agent 2%

[0080] Titanate coupling agent 1%.

[0081] The antifreeze agent is prepared by mixing and granulating the following components by mass percentage, wherein the content of vinyl acetate in the ethylene vinyl acetate copolymer is 20%, the content of acrylic acid in the ethylene acrylic acid copolymer is 25%, and the ethylene acetic acid Ethylene copolymer and ethylene acrylic acid copolymer are added to the screw extruder by side feeding during the antifreeze granulation process, and the extruding granulation temperature range is 160°C.

[0082] Ethylene vinyl acetate copolymer 10%

[0083] Ethylene acrylic acid copolymer 15%

[0084] Polyethylene 1%

[0085] Maleic anhydride 1%

[0086] Polyolefin Elast...

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PUM

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Abstract

The invention relates to anti-freezing microwave-resistant starch-based tableware and a preparation method thereof. The anti-freezing microwave-resistant starch-based tableware is composed of polypropylene, starch, an anti-freezing agent and a compatilizer, wherein the anti-freezing agent is prepared by mixing and granulating an ethylene vinyl acetate copolymer, an ethylene acrylic acid copolymer,polypropylene maleic anhydride and a polyolefin elastomer. The anti-freezing microwave-resistant starch-based tableware is good in anti-freezing performance, good in toughness, not prone to damage, resistant to microwave heating, good in strength and applicable to fast food industries needing low-temperature freezing and fresh-keeping transportation, e.g., fast food supplied on trains and high-speed trains.

Description

technical field [0001] The invention belongs to the technical field of tableware materials, and in particular relates to a frost-resistant and microwave-resistant starch-based tableware and a preparation method thereof. Background technique [0002] Trains, high-speed rail, etc. are uniformly equipped with the fast food industry. The fast food made is kept fresh at low temperature, transported, and heated by microwave before eating. This requires the fast food box material to have good frost resistance, good toughness, not easy to be damaged, and resistant to microwave heating. Strength nice features. Most of the existing fast food is made of polypropylene (PP) material. With the increase of the consumption, the phenomenon of white pollution becomes serious. For plastic pollution, orderly prohibit and restrict the production, sale and practical use of some plastic products, and actively promote recyclable and easily recyclable degradable alternatives. [0003] As an upgrad...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L3/02C08L23/12C08L23/08C08L23/06C08K5/1539
CPCC08L3/02C08L2201/08C08L2205/035C08L23/12C08L23/0853C08L23/0869C08L23/06C08K5/1539
Inventor 上官智慧谢建伟吴伯伟马仁海祝忠雷
Owner 江苏中科成长环保科技有限公司
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