Cathodic electrophoretic paint and preparation method thereof
A cathodic electrophoretic coating and monomer technology, applied in electrophoretic coatings, epoxy resin coatings, polyurea/polyurethane coatings, etc., can solve problems such as uneven extinction and poor extinction effect
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[0050] A method for preparing cathodic electrophoretic paint in one embodiment includes step S110 to step S130. specifically:
[0051] Step S110, reacting the amino group-containing compound with the epoxy resin to obtain a modified epoxy resin.
[0052] Specifically, a ring-opening reaction occurs between the amino group-containing compound and the epoxy resin to obtain a modified epoxy resin. Further, the temperature of the ring-opening reaction is 80°C to 100°C.
[0053] Specifically, the amino group-containing compound is at least one selected from methylamine, N-methylethanolamine and diethanolamine. Further, the amino group-containing compound is diethanolamine.
[0054] Specifically, the epoxy resin is a medium molecular weight epoxy resin, such as E-12, E-14, E-20 and the like. When the molecular weight of the epoxy resin is too small and the compatibility with the acrylic resin is too good, the gloss of the final paint film will be high. When the molecular weight...
Embodiment 1~ Embodiment 3
[0089] (1) Take the components of each embodiment according to Table 1.
[0090] Table 1
[0091]
[0092]
[0093] (2) Mix the polyisocyanate of each embodiment with the corresponding first solvent respectively, then raise the temperature to 45°C-50°C, add the sealing agent corresponding to each embodiment dropwise, the dropping time is 3h-3.5h, after the dropwise Insulated for 4 hours to obtain the blocked isocyanate curing agent of each embodiment.
[0094] (3) The amino group-containing compound, the corresponding epoxy resin and the second solvent of each embodiment were mixed respectively, and then heated to 90° C. for 3 h to obtain the modified epoxy resin of each embodiment.
[0095] (4) At 90°C, after mixing the monomers of the acrylic resins of each embodiment and the initiator, they are added dropwise to the modified epoxy resins corresponding to each embodiment prepared in step (3), and the dropping time is After 3 hours of dripping, the initiator was incub...
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