All-solid secondary cell, outer cladding material for all-solid secondary cell, and method for manufacturing said all-solid secondary cell
A technology for secondary batteries and manufacturing methods, applied in secondary batteries, battery case/sleeve materials, battery electrodes, etc., can solve problems such as liquid leakage, and achieve the effects of high discharge capacity density, low voltage, and excellent cycle characteristics
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[0186] Hereinafter, the present invention will be described in further detail based on examples. In addition, the present invention is not limited thereto and interpreted. In the following examples, "parts" and "%" showing the composition are based on mass unless otherwise specified. Also, "room temperature" means 25°C.
[0187] -Synthesis of sulfide-based inorganic solid electrolyte (Li-P-S-based glass)-
[0188]As a sulfide-based inorganic solid electrolyte, refer to T.Ohtomo, A.Hayashi, M.Tatsumisago, Y.Tsuchida, S.HamGa, K.Kawamoto, Journal of Power Sources, 233, (2013), pp231-235 and A. Hayashi, S. Hama, H. Morimoto, M. Tatsumisago, T. Minami, Chem. Lett., (2001), non-patent literature of pp872-873, Li-P-S type glass was synthesized.
[0189] Specifically, weigh 2.42g lithium sulfide (Li 2 S, Aldrich.Inc manufacture, purity > 99.98%), 3.90g phosphorus pentasulfide (P 2 S 5 , manufactured by Aldrich.Inc, purity>99%), put into an agate mortar, and mixed for 5 minutes ...
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