Special urea-formaldehyde resin adhesive for producing environment-friendly medium-high density boards as well as preparation process and use method of special urea-formaldehyde resin adhesive

A technology of urea-formaldehyde resin glue and high-density board, which is used in adhesives, manufacturing tools, aldehyde/ketone condensation polymer adhesives, etc. Production and other problems, to achieve the effect of less variety of chemical raw materials, guaranteed physical and chemical mechanical indicators, and low grade requirements

Inactive Publication Date: 2020-06-09
成都光禾木业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, in the production of continuous flat-pressed medium and high-density fiberboard, most of the urea-formaldehyde resin adhesives used adopt relatively complicated production processes, and there are many types of main and auxiliary chemical raw materials added, which brings a lot of inconvenience to the production operation and high cost.
Due to the traditional medium and high density fiberboard production process, the temperature requirement in the polycondensation reaction stage is too high, generally 96-98 degrees, and only one polycondensation reaction or two polycondensation reactions are performed, which is not conducive to safe production
Or carry out three polycondensation reactions, but the end point of the second polycondensation reaction and the third polycondensation reaction end point are difficult to accurately detect, there is a greater risk, the production cycle is long, and the bonding strength is low, such as the existing technology 201710952584.6
In addition, if the temperature of the polycondensation reaction is too high, if the salt content in urea is too high, as the polycondensation reaction accelerates and the temperature rises, a large amount of foam will be generated, which is not conducive to the production and operation of medium and high density fiberboard.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] The preparation process of the adhesive is as described above.

[0040] In the present embodiment: the reactor volume is 25 cubic meters, and the mol ratio of the adhesive formula is 1.05;

[0041] According to the volume of the reactor and the molar ratio of the adhesive formula, calculate the amount of formaldehyde; formaldehyde 16200kg (37%);

[0042] According to the volume of the reactor and the molar ratio of the adhesive formula, calculate the amount of urea, urea 11600kg (98%);

[0043] According to the total amount of urea added, calculate the added amount of melamine 580kg (99.0%), (melamine molar amount / urea molar amount)×100%=2.4%;

[0044] According to the total amount of urea added, the amount of industrial salt added is calculated as 677kg, (molar amount of melamine / molar amount of urea)×100%=6.1%;

[0045] The urea is added in four batches; the amount of urea in each batch is based on the molar ratio of each reaction stage, and the amount of urea added...

Embodiment 2

[0048] The preparation process of the adhesive is as described above.

[0049] In the present embodiment: the reactor volume is 25 cubic meters, and the mol ratio of the adhesive formula is 1.08;

[0050] According to the volume of the reactor and the molar ratio of the adhesive formula, calculate the amount of formaldehyde; formaldehyde 16200kg (37%);

[0051] According to the volume of the reactor and the molar ratio of the adhesive formula, calculate the amount of urea, urea 11350kg (98%);

[0052] According to the total amount of urea added, calculate the added amount of melamine 650kg (99.0%), (melamine molar amount / urea molar amount)×100%=2.8%;

[0053] According to the total amount of urea added, calculate the industrial salt addition amount of 702kg, (melamine molar amount / urea molar amount)×100%=6.5%;

[0054] The urea is added in four batches; the amount of urea in each batch is based on the molar ratio of each reaction stage, and the amount of urea added in each b...

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PUM

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Abstract

The invention relates to a special urea-formaldehyde resin adhesive for producing environment-friendly medium-high density fiberboards as well as a preparation process and a use method of the specialurea-formaldehyde resin adhesive, and belongs to the technical field of production of continuous flat-pressing environment-friendly medium-high density fiberboards. According to the technical scheme,formaldehyde, urea, melamine and industrial salt are used as raw materials, and urea is added in four batches; in addition, two auxiliary chemical raw materials including formic acid and caustic sodaare added; and according to the set molar ratio of the adhesive, milk white liquid is formed through a weak base-weak acid-weak base process, and the milk white liquid is the urea-formaldehyde resin adhesive. The production operation process of three times of condensation polymerization and four batches of urea addition is adopted, production control is facilitated, and the quality of the adhesiveis more stable. The main raw materials of the adhesive are formaldehyde and urea, a small amount of melamine is added for modification, industrial salt filling is added, the auxiliary raw materials are formic acid and caustic soda, operation is convenient, the cost is reduced, the manufacturing method is simple, the varieties of chemical raw materials are few, and meanwhile the physicochemical and mechanical indexes and the application effect of the using performance of the product are guaranteed.

Description

technical field [0001] The invention relates to a special urea-formaldehyde resin adhesive for producing environment-friendly medium and high-density boards, a preparation process and a use method thereof, and belongs to the production technical field of continuous flat pressing environment-friendly medium and high-density fiberboards. Background technique [0002] At present, in the production of continuous flat-pressed medium and high-density fiberboard, most of the urea-formaldehyde resin adhesives used are relatively complicated production processes, and there are many types of main and auxiliary chemical raw materials added, which brings a lot of inconvenience to production operations and high costs. Due to the traditional medium and high density fiberboard production process, the temperature requirement in the polycondensation reaction stage is too high, generally 96-98 degrees, and only one polycondensation reaction or two polycondensation reactions are performed, whic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J161/30C08G12/38B27N1/02
CPCB27N1/0209C08G12/38C09J161/30
Inventor 李卓陈文桂
Owner 成都光禾木业有限公司
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