Preparation and application of plant growth regulator N,N-diethylaminoethyl butyrate
A technology of diethylaminoethyl ester and diethylaminoethanol, which is applied in the field of plant growth regulator butyric acid-N, can solve the problem that the variety and quantity cannot meet the market demand, the vigor of seeds is easily reduced, and the flowers are rotten and seedlings are lacking. and other problems, to achieve the effects of broad development and application prospects, simple and feasible preparation methods, and well-developed root systems.
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Embodiment 1
[0032] A plant growth regulator butyric acid-N, the preparation of N-diethylaminoethyl ester hydrochloride comprises the steps:
[0033] Step 1, in a three-necked flask, add 200 grams of diethylaminoethanol, dissolve in dichloromethane, stir and cool down in a cryogenic cold trap;
[0034] Step 2, when the temperature is lowered to 0 degrees Celsius, 180 grams of butyryl chloride is added dropwise for 1 hour, and the dropping temperature is controlled at -10 to 20 degrees Celsius;
[0035] Step 3: React at a low temperature of -10 to 20 degrees Celsius for two hours, then stir at room temperature for three hours, stop stirring, and vacuumize to remove the solvent to obtain butyric acid-N,N-diethylaminoethyl ester hydrochloride .
Embodiment 2
[0037] A plant growth regulator butyric acid-N, the preparation of N-diethylaminoethyl ester hydrochloride comprises the steps:
[0038] Step 1, in a three-necked flask, add 100 grams of diethylaminoethanol, stir and cool down in a cryogenic cold trap;
[0039]Step 2, when the temperature is lowered to 0 degrees Celsius, 80 grams of butyryl chloride is added dropwise for 1 hour, and the dropping temperature is controlled at -10 to 20 degrees Celsius;
[0040] Step 3: react at low temperature at -10 to 20 degrees Celsius for 3 hours, then stir at 40 to 60 degrees Celsius for 2 hours, stop stirring, discharge, and cool to obtain butyric acid-N,N-diethylaminoethyl White solid of ester hydrochloride.
Embodiment 3
[0042] A plant growth regulator butyric acid-N, the preparation of N-diethylaminoethyl citrate comprises the steps:
[0043] Step 1: In a three-necked flask, add 200 grams of diethylaminoethanol, dissolve in dichloromethane, stir and cool in a cryogenic cold trap, and when the temperature drops to 0 degrees Celsius, add 180 grams of butyryl chloride dropwise for 1 hour. The dropping temperature is controlled at -10 to 20 degrees Celsius; react at low temperature for two hours, then stir at room temperature for three hours, stop stirring, and remove the solvent by vacuuming to obtain butyric acid-N,N-diethylaminoethyl ester hydrochloride Salt.
[0044] Step 2, neutralize butyric acid-N,N-diethylaminoethyl hydrochloride with aqueous sodium bicarbonate solution, and extract with ethyl acetate to obtain butyric acid-N,N-diethylaminoethyl ester, Its yield was 92%.
[0045] Wherein except using sodium bicarbonate to carry out neutralization reaction as alkali, also can replace the...
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