Preparation and application of plant growth regulator N,N-diethylaminoethyl butyrate

A technology of diethylaminoethyl ester and diethylaminoethanol, which is applied in the field of plant growth regulator butyric acid-N, can solve the problem that the variety and quantity cannot meet the market demand, the vigor of seeds is easily reduced, and the flowers are rotten and seedlings are lacking. and other problems, to achieve the effects of broad development and application prospects, simple and feasible preparation methods, and well-developed root systems.

Pending Publication Date: 2020-07-03
河南福联生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In recent years, the research and application of plant growth regulators in my country have also developed rapidly, but their varieties and quantities cannot meet the needs of the market.
In many areas of our country, the problem of rotten seeds and lack of seedlings of vegetables and flowers has been very serious. The main reason is that after the seeds are harvested, the vigor of the seeds is easily reduced or even lost during the drying and storage process.

Method used

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  • Preparation and application of plant growth regulator N,N-diethylaminoethyl butyrate
  • Preparation and application of plant growth regulator N,N-diethylaminoethyl butyrate
  • Preparation and application of plant growth regulator N,N-diethylaminoethyl butyrate

Examples

Experimental program
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Effect test

Embodiment 1

[0032] A plant growth regulator butyric acid-N, the preparation of N-diethylaminoethyl ester hydrochloride comprises the steps:

[0033] Step 1, in a three-necked flask, add 200 grams of diethylaminoethanol, dissolve in dichloromethane, stir and cool down in a cryogenic cold trap;

[0034] Step 2, when the temperature is lowered to 0 degrees Celsius, 180 grams of butyryl chloride is added dropwise for 1 hour, and the dropping temperature is controlled at -10 to 20 degrees Celsius;

[0035] Step 3: React at a low temperature of -10 to 20 degrees Celsius for two hours, then stir at room temperature for three hours, stop stirring, and vacuumize to remove the solvent to obtain butyric acid-N,N-diethylaminoethyl ester hydrochloride .

Embodiment 2

[0037] A plant growth regulator butyric acid-N, the preparation of N-diethylaminoethyl ester hydrochloride comprises the steps:

[0038] Step 1, in a three-necked flask, add 100 grams of diethylaminoethanol, stir and cool down in a cryogenic cold trap;

[0039]Step 2, when the temperature is lowered to 0 degrees Celsius, 80 grams of butyryl chloride is added dropwise for 1 hour, and the dropping temperature is controlled at -10 to 20 degrees Celsius;

[0040] Step 3: react at low temperature at -10 to 20 degrees Celsius for 3 hours, then stir at 40 to 60 degrees Celsius for 2 hours, stop stirring, discharge, and cool to obtain butyric acid-N,N-diethylaminoethyl White solid of ester hydrochloride.

Embodiment 3

[0042] A plant growth regulator butyric acid-N, the preparation of N-diethylaminoethyl citrate comprises the steps:

[0043] Step 1: In a three-necked flask, add 200 grams of diethylaminoethanol, dissolve in dichloromethane, stir and cool in a cryogenic cold trap, and when the temperature drops to 0 degrees Celsius, add 180 grams of butyryl chloride dropwise for 1 hour. The dropping temperature is controlled at -10 to 20 degrees Celsius; react at low temperature for two hours, then stir at room temperature for three hours, stop stirring, and remove the solvent by vacuuming to obtain butyric acid-N,N-diethylaminoethyl ester hydrochloride Salt.

[0044] Step 2, neutralize butyric acid-N,N-diethylaminoethyl hydrochloride with aqueous sodium bicarbonate solution, and extract with ethyl acetate to obtain butyric acid-N,N-diethylaminoethyl ester, Its yield was 92%.

[0045] Wherein except using sodium bicarbonate to carry out neutralization reaction as alkali, also can replace the...

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Abstract

The invention discloses a preparation method of a plant growth regulator N,N-diethylaminoethyl butyrate. The preparation method comprises the following steps: 1, preparing N,N-diethylaminoethyl butyrate hydrochloride according to a reaction principle shown in the description; 2, carrying out alkali neutralization and extraction to obtain N,N-diethylaminoethyl butyrate; and 3, preparing N,N-diethylaminoethyl butyrate citrate by using a solvent method or a solvent-free method. The intermediate N,N-diethylaminoethyl butyrate hydrochloride and the finally obtained N,N-diethylaminoethyl butyrate citrate can be used as plant growth regulators to be applied, and specifically, the intermediate N,N-diethylaminoethyl butyrate hydrochloride and the finally obtained N,N-diethylaminoethyl butyrate citrate are sprayed or irrigated to crops, commercial crops and fruit plants. The N,N-diethylaminoethyl butyrate is prepared through a low-temperature normal-pressure reaction, and the raw materials are easy to obtain and are low in price, so the preparation method is simple, convenient and feasible; and the using method is simple, and the N,N-diethylaminoethyl butyrate can be compounded with multiplecomponents according to different purposes, so the application field of the N,N-diethylaminoethyl butyrate is expanded, efficiency is high, and cost is low.

Description

technical field [0001] The invention relates to the fields of chemical industry and agriculture, in particular to the preparation and application of a plant growth regulator butyric acid-N,N-diethylaminoethyl ester salt. Background technique [0002] N, N-diethylaminoethanol hexanoate (being commonly called as DA-6) is as efficient plant growth regulator in the prior art, has the multiple functions of auxin, gibberellin and cytokinin, by enhancing plant photosynthesis and Plant enzyme activity can promote cell division, elongation and plant carbon and nitrogen metabolism, etc. It has the effects of increasing yield, early maturity, improving quality, disease resistance and stress resistance. It can induce the synthesis of β-carotene in plants and increase the content of β-carotene; it can also greatly increase the yield of crops and significantly improve the quality of products; and it has high efficiency, low toxicity, safe use, and low production and use costs. It has bee...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C219/06C07C213/06C07C213/08C07C213/10C07C59/265C07C51/41A01N37/12A01P21/00
CPCC07C213/06C07C213/08C07C213/10C07C51/412C07C219/06C07C59/265Y02A40/10
Inventor 刘福琳申晓静
Owner 河南福联生物科技有限公司
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