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Combined adsorbent for flue gas desulfurization and denitrification and flue gas desulfurization and denitrification method

A technology of desulfurization and denitrification and adsorbent, which is applied in the field of desulfurization and denitrification technology, can solve the problems of desulfurization agent can not be reused, high removal rate, low loss of adsorbent, etc., achieve no secondary pollution industrial application prospect, pollutant removal The effect of high efficiency and low loss of adsorbent

Inactive Publication Date: 2020-11-24
江苏稚盛实业发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] In view of the shortcomings of the prior art described above, the purpose of the present invention is to provide a combined adsorbent for flue gas desulfurization and denitrification, which is used to solve the problem of high desulfurization and denitrification costs in the prior art, desulfurization agents that cannot be reused, and secondary At the same time, the present invention will also provide a flue gas desulfurization and denitrification method using a combined adsorbent; the present invention has the advantages of no water consumption, no low-quality by-products, no lime and synthetic ammonia consumption, investment and occupation of environmental protection pressure Small area, low loss of adsorbent, long life, high pollutant removal rate, no secondary pollution, the characteristics of realizing the resource utilization of flue gas and the advantages of good industrial application prospects

Method used

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  • Combined adsorbent for flue gas desulfurization and denitrification and flue gas desulfurization and denitrification method
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Embodiment 1

[0042] A combined adsorbent for flue gas desulfurization and denitrification, the combined adsorbent is composed of a low-temperature adsorbent and a high-temperature adsorbent;

[0043] The high-temperature adsorbent includes the following components in parts by weight: 35 parts of mercerized molecular sieve, 15 parts of iron oxide, and 15 parts of binder;

[0044] The low-temperature adsorbent includes the following components in parts by weight: 50 parts of MCM-41 molecular sieve, 5 parts of magnesium oxide, and 15 parts of binder;

[0045] Among them, the specific surface area of ​​mercerized molecular sieve is 280m 2 / g, the specific surface area of ​​MCM-41 molecular sieve is 1156m 2 / g.

[0046] The binder is obtained by mixing alumina and kaolin at a mass ratio of 1:6.

[0047] A method for flue gas desulfurization and denitrification using the above combined adsorbent, comprising the steps of:

[0048] Step 1, flue gas dust removal: transport the flue gas to be tr...

Embodiment 2

[0053] A combined adsorbent for flue gas desulfurization and denitrification, the combined adsorbent is composed of a low-temperature adsorbent and a high-temperature adsorbent;

[0054] The high-temperature adsorbent includes the following components in parts by weight: 40 parts of ZSM-5 molecular sieve, 20 parts of calcium oxide, and 15 parts of bentonite; the low-temperature adsorbent includes the following components in parts by weight: 50 parts of Silica, 20 parts of bentonite;

[0055] Among them, the specific surface area of ​​ZSM-5 molecular sieve is 350m 2 / g, the specific surface area of ​​silicon oxide is 600m 2 / g.

[0056] A method for flue gas desulfurization and denitrification using the above combined adsorbent, comprising the steps of:

[0057] Step 1, flue gas dust removal: transport the flue gas to be treated to the electrostatic precipitator for dust removal pretreatment;

[0058] Step 2. Adsorption desulfurization and denitrification: transport the dus...

Embodiment 3

[0062] A combined adsorbent for flue gas desulfurization and denitrification, the combined adsorbent is composed of a low-temperature adsorbent and a high-temperature adsorbent;

[0063] The high-temperature adsorbent includes the following components in parts by weight: 60 parts of Y-type molecular sieve, 40 parts of nickel oxide, and 25 parts of binder;

[0064] The low-temperature adsorbent includes the following components in parts by weight: 60 parts of activated carbon, 25 parts of binder;

[0065] Among them, the specific surface area of ​​Y-type molecular sieve is 742m 2 / g, the surface area of ​​activated carbon is 890m 2 / g;

[0066] The binder is prepared by mixing alumina and attapulgite at a mass ratio of 1:5.

[0067] A method for flue gas desulfurization and denitrification using the above combined adsorbent, comprising the steps of:

[0068] Step 1, flue gas dust removal: transport the flue gas to be treated to the electrostatic precipitator for dust remova...

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Abstract

The invention relates to the technical field of a desulfurization and denitrification process, in particular to a combined adsorbent for flue gas desulfurization and denitrification and a flue gas desulfurization and denitrification method. The combined adsorbent consists of a low-temperature adsorbent and a high-temperature adsorbent, wherein the high-temperature adsorbent comprises a porous carrier, a metal oxide and a binder; and the low-temperature adsorbent comprises a porous carrier and a binder, and possibly contains a metal oxide. The flue gas desulfurization and denitrification methodcomprises the following steps of flue gas dedusting, combined adsorption desulfurization and denitrification, and adsorbent regeneration and sulfur dioxide curing. The problems that in the prior art,the desulfurization and denitrification cost is high, a desulfurizing agent cannot be reused, and secondary pollution is caused are solved. The method has the characteristics of no water consumption,no low-quality byproducts, no consumption of lime and synthetic ammonia with high environmental protection pressure, low investment, small land occupation, low adsorbent loss, long service life, highpollutant removal rate, no secondary pollution and capability of realizing utilization of sulfur-containing flue gas as resources, has good industrial application prospects, and can be used for fluegas treatment of power plants, steel plants and petrochemical plants.

Description

technical field [0001] The invention relates to the technical field of desulfurization and denitrification technology, in particular to a combined adsorbent for desulfurization and denitrification of flue gas and a method for desulfurization and denitrification of flue gas. Background technique [0002] At present, there are about a dozen flue gas desulfurization technologies that have been industrialized and are being researched at home and abroad. These methods can be divided into dry and wet methods in terms of technology, and can be divided into discarding and recycling methods in terms of recovery and utilization of desulfurizers. Among them, the main methods that have been industrialized or pilot-tested are: 1) ammonium sulfite method; 2) citrate method; 3) activated carbon wet desulfurization; 4) wet desulfurization to produce phosphorus and ammonium compound fertilizer; 5) electron beam desulfurization ; 6) Lime-gypsum desulfurization, etc. [0003] At present, wet ...

Claims

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Application Information

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IPC IPC(8): B01J20/10B01J20/12B01J20/14B01J20/16B01J20/18B01J20/30B01J20/20C01B17/04B01D53/02
CPCB01D53/02B01D2253/102B01D2253/104B01D2253/106B01D2253/108B01D2253/11B01D2253/1124B01D2257/302B01D2257/40B01D2257/404B01D2259/40088B01J20/041B01J20/06B01J20/08B01J20/103B01J20/12B01J20/14B01J20/16B01J20/18B01J20/20B01J2220/42B01J2220/4806C01B17/0404
Inventor 陈航
Owner 江苏稚盛实业发展有限公司
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