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Fire suppressant foam forming compositions, precursors, their uses and methods of making them

A technology of composition and water-based composition, which is applied in the field of fire extinguishing foam and improves the fire extinguishing properties of foam, and can solve the problems of low foam stability and the like

Inactive Publication Date: 2020-11-24
IMERTECH SAS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, low foam stability is expected without the use of foam stabilizers

Method used

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  • Fire suppressant foam forming compositions, precursors, their uses and methods of making them
  • Fire suppressant foam forming compositions, precursors, their uses and methods of making them

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 to 5

[0076] The foam stabilization properties of various inorganic particulate materials were tested.

[0077] Various inorganic particulate materials (10% by weight) were mixed into a 0.3% by weight foam solution of sodium lauryl ether sulfate (MEYCO SLF30, supplied by BASF) in water, and the resulting composition was mixed using a laboratory foam generator. The resulting foam (60 g) was filled into a funnel basin with a frit coarse enough that the mineral particles did not block the drainage of the foam, thereby affecting the result, with a collector at the bottom and allowed to stand. The disintegration of any foam was measured by measuring the amount of water collected below the funnel basin.

[0078] The particulate inorganic materials tested are shown in Table I:

[0079] Table I

[0080] Example mineral 1 CaCO 3

2 dolomite 3 Kaolin 4 and 5 talc Comparative example 1 none

[0081] Observe the amount of water collected for...

Embodiment 6 and 7

[0086] In another test series, a 3% by weight foam solution of sodium lauryl ether sulfate (MEYCO SLF 30, supplied by BASF) in water (without inorganic particulates) was compared with other surfactants with and without inorganic particulates . Polymer A is sodium lauryl sulfate (SLS) and polymer B is tetradecyltrimethylammonium bromide (TTAB). The compositions shown in Table III were mixed using a laboratory foam generator. The talc used in Examples 6 and 7 was d 95 6.2μm and d 50 1.8 μm coarse crystalline talc (according to Sedigraph – ISO 13317-3).

[0087] Table III

[0088] Example combination Comparative example 2 Water, 3% by weight MEYCO SLF 30 Comparative example 3 Water, 3 wt% SLS Example 6 Water, 5% by weight talc, 0.05% by weight SLS Example 7 Water, 5 wt% talc, 0.05 wt% TTAB

[0089] The resulting foam (60 g) was filled into a funnel basin with a frit and a collector at the bottom and allowed to stand. Also, measure...

Embodiment 8 and 9

[0094]Foams were tested using deionized water (Example 8) or standard tap water (Example 9) in the presence of various amounts of talc and tetradecyltrimethylammonium bromide (TTAB). The talc used was microcrystalline talc supplied by Imerys Talc with a BET surface area of ​​21m 2 / g (ISO 9277), with a median particle size of 1.1 μm (according to Sedigraph – ISO13317-3). TTAB is used as a 5% aqueous stock solution. Foams were prepared by combining the talc and TTAB stock solutions and making up to 100 grams using deionized or tap water. The resulting composition was mixed using a laboratory foam generator. The resulting foam was filled into a funnel basin with a frit and a collector at the bottom and allowed to stand. The disintegration of any foam was measured by measuring the amount of water collected under the funnel sump. Various test parameters are shown in Table V.

[0095] Table V

[0096] Example parameter Example 8a 0.05 wt% TTAB, 2.5 wt% talc...

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Abstract

The present invention relates to aqueous compositions for suppressing fires, comprising surfactants and / or hydrotropes, particulate inorganic materials selected from the group consisting of perlite, talc, calcium carbonate, kaolin, dolomite, mica, and bentonite, and combinations thereof, and optionally one or more additives. The invention further relates to uses of such particulate inorganic materials, as well as dry precursor compositions, fire suppressing compositions, and methods of making them.

Description

technical field [0001] The present invention relates to aqueous and dry compositions for forming foams suitable as fire extinguishing compositions, and to fire extinguishing foams. The present invention also relates to the use of particulate inorganic materials in the formation of foams, methods for improving the stability of foams, and methods for improving the fire-extinguishing properties of foams. Background technique [0002] Water-based foams are used to tackle so-called Class B (liquid fuel) fires. This foam is especially useful in exterior environments when dealing with large-scale fires and fire risks. Examples of applications are for suppression and prevention of aircraft and ship fires, civil aviation installations such as airports, and industrial installations where large quantities of potentially flammable liquids are used or stored, such as petrochemical refineries, oil and gas rigs and platforms. Other extinguishing media applied in tanks are more commonly u...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A62D1/02
CPCA62D1/0071A62D1/0085A62D1/0042A62C99/0036A62D1/00
Inventor M·格林希尔-胡佩尔A·博拉斯G·科莱德
Owner IMERTECH SAS