Heat-shrinkable plastic member, composite preform, and composite container
A preform, heat shrinking technology, applied in rigid containers, containers, household containers, etc., can solve problems such as limited means, and achieve the effect of improving production efficiency and improving ease of insertion
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Embodiment 1
[0160] Using a ring-shaped die, an energy storage mold made of Himilan 1706 (manufactured by Dupont-Mitsui Polychemical Co., Ltd., MFR 0.9 g / 10 minutes, 25° C. Volume 3.8×10 8 Pa) 95% by mass, Win-Tech WFX4TA (manufactured by Japan Polypropylene Co., Ltd., metallocene polypropylene, MFR7.0g / 10min, storage modulus 1.0×10 in 25°C environment) as olefin resin (B) 9 Pa) The mixture compounded at a ratio of 5% by mass was melt-extruded to form an undrawn tube with an inner diameter of 16.6 mm, and then the undrawn tube was heated with hot water, pressurized with compressed gas from the inside of the tube, and stretched. Stretching, thereby producing a bottomless cylindrical heat-shrinkable plastic part. In addition, the heat-shrinkable plastic member had an inner diameter of 28.7 mm and a thickness of 307 μm.
Embodiment 2
[0162]For the outermost layer, a mixture of Himilan 1706 95% by mass as the ionomer resin (A) and 5% by mass of Win-TechWFX4TA as the olefin resin (B) was used, and 100% by mass for the adhesive layer The polyolefin-based adhesive resin (Admer SF731, manufactured by Mitsui Chemicals Co., Ltd.), the intermediate layer uses a mixture of ethylene-vinyl alcohol copolymer (EVALSP482B, manufactured by KURARAY Co., Ltd.) in a ratio of 100% by mass as a gas barrier layer , using a 5-layer ring die, the three materials were melted and extruded through a single-screw extruder to form an unstretched tube with an inner diameter of 18.3 mm, and then heated with hot water to heat the unstretched tube from the inside of the tube. Compressed gas is pressurized and stretched to produce a bottomless cylindrical heat-shrinkable plastic member. In addition, the heat-shrinkable plastic member had an inner diameter of 28.7 mm and a thickness of 345 μm (outermost layer 132 μm, adhesive layer 17 μm, ...
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