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A kind of low-permeability oil reservoir acid-sensitive self-generated temporary plugging and diverting agent and its preparation method and application

A low-permeability, oil-reservoir technology, applied in chemical instruments and methods, reagents, and earth-moving drilling and production, etc., can solve the problem of uneven water absorption in water injection wells, and achieve low plugging performance, improve uneven water absorption, and improve water drive. degree of effect

Active Publication Date: 2022-07-05
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] Another object of the present invention is to provide the application of acid-sensitive self-generated temporary plugging and diverting agent for low-permeability oil reservoirs, which can effectively adjust and improve the problem of uneven water absorption of water injection wells in low-permeability oilfields

Method used

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  • A kind of low-permeability oil reservoir acid-sensitive self-generated temporary plugging and diverting agent and its preparation method and application
  • A kind of low-permeability oil reservoir acid-sensitive self-generated temporary plugging and diverting agent and its preparation method and application
  • A kind of low-permeability oil reservoir acid-sensitive self-generated temporary plugging and diverting agent and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] This embodiment provides an acid-sensitive self-generated temporary plugging and diverting agent for low-permeability oil reservoirs, which is composed of the following weight percentages: 10-20% of sodium stearate, 6-15% of sodium humate, and 10.5% of silicate. ~25%, benzoate 8.5~11.5%, polyamino polycarboxy polymer 10~16%, surfactant 4~6%, potassium chloride 3-8%, and the rest is water.

[0037] Principle of the present invention:

[0038] The acid-sensitive self-generated temporary plugging and diverting agent for low-permeability oil reservoirs of the invention is pumped into the formation, enters the pores with different pore diameters of the formation respectively, automatically matches the size of the formation pore roar, and then pumps into the acid solution, and gradually enters the pores filled with the temporary plugging agent solution. Due to the low pH value, the main components of the temporary plugging agent react with the acid solution to form solid part...

Embodiment 2

[0044] On the basis of Example 1, this example provides an acid-sensitive self-generated temporary plugging and diverting agent for low-permeability oil reservoirs, which is composed of the following weight percentages: 10% of sodium stearate, 15% of sodium humate, Silicate 10.5%, benzoate 8.5%, polyamino polycarboxy polymer 10%, surfactant 6%, potassium chloride 3%, water 37%.

[0045] making process:

[0046] Step 1) The reaction kettle is heated to 30°C and kept at a constant temperature, followed by adding water, sodium stearate, sodium humate, silicate and benzoate in the formula amount, and stirring while adding;

[0047] Step 2) Add the formula amount of polyamino polycarboxy polymer and surfactant to the above solution in turn, then the temperature is raised to 40°C, and the temperature is uniformly stirred for 30 minutes;

[0048] Step 3) Add the formula amount of potassium chloride to the above solution, stir evenly, cool the solution to room temperature, and then w...

Embodiment 3

[0057] On the basis of Example 1, this example provides an acid-sensitive self-generated temporary plugging and diverting agent for low-permeability oil reservoirs, which is composed of the following weight percentages: 15% of sodium stearate, 10% of sodium humate, Silicate 15%, benzoate 10%, polyamino polycarboxy polymer 12%, surfactant 5%, potassium chloride 5%, water 28%.

[0058] making process:

[0059] Step 1) The reaction kettle is heated to 40°C and kept at a constant temperature, followed by adding water, sodium stearate, sodium humate, silicate and benzoate in the formula amount, and stirring while adding;

[0060] Step 2) Add the formula amount of polyamino polycarboxy polymer and surfactant to the above solution in turn, then the temperature is raised to 45°C, and the temperature is uniformly stirred for 35 minutes;

[0061] Step 3) Add the formula amount of potassium chloride to the above solution, stir evenly, cool the solution to room temperature, and then weig...

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Abstract

The invention provides an acid-sensitive self-generated temporary plugging and diverting agent for low-permeability oil reservoirs and a preparation method and application thereof. , silicate 10.5~25%, benzoate 8.5~11.5%, polyamino polycarboxy polymer 10~16%, surfactant 4~6%, potassium chloride 3-8%, and the rest is water. The invention reacts with the acid solution in the pores to generate insoluble organic solid acid, which plays a temporary plugging role in the formation pore roar. After the acidification measures are restored, the water injection is gradually dissolved, and the formation seepage channel is completely restored. The invention can cleverly avoid the matching problem between particle size and pore roar when the particle-type temporary plugging agent is injected into the formation, and at the same time maintain the plugging strength of the solid-type plugging agent. Particles with moderate particle size play a temporary blocking role, solving the problem of low blocking performance of gel-based temporary plugging agents.

Description

technical field [0001] The invention belongs to the technical field of water flooding development in low-permeability oil fields, and in particular relates to an acid-sensitive self-generated temporary plugging and diverting agent for low-permeability oil reservoirs and a preparation method and application thereof. Background technique [0002] Due to the plane and vertical heterogeneity of reservoir physical properties, temporary plugging and diverting techniques may be required for drilling, oil testing and fracturing, water injection profile adjustment and repeated stimulation measures during oilfield development. At present, there are three main types of temporary plugging and shunting technology: particle / powder type, liquid / gel type and foam type. [0003] Particle-based temporary plugging agents mainly include petroleum resins, hydrocarbon resins, phenolic resins, epoxy resins, urea-formaldehyde resins, inorganic salts, etc. Due to their own particle size problems, it...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/504C09K8/508C09K8/514E21B33/13
CPCC09K8/5086C09K8/5045C09K8/514E21B33/13Y02P20/141
Inventor 唐泽玮姚斌姬振宁王守虎张随望隋蕾陆小兵王勇王尔珍邓志颖
Owner PETROCHINA CO LTD