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A kind of safe discharge method of spent lithium-ion battery

A lithium-ion battery and waste technology, which is applied in the direction of secondary battery charging/discharging, secondary battery, battery recycling, etc., can solve the problems of conductive powder easily adhering to the battery surface, polluting the battery, and easily raising dust, etc., to achieve effective Conducive to large-scale industrial production, simple raw materials and operations, and wide application prospects

Active Publication Date: 2022-04-19
深圳市杰成镍钴新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Resistive load discharge patents, such as CN108550943A, CN106207297B, although this method has a faster discharge speed and a more thorough discharge, it also has problems such as elevated temperature during the discharge process, poor compatibility of battery types, and low degree of automatic operation of load connection.
Conductive powder discharge patents, such as CN106816663A, CN109103534A, CN110176644A, all use conductive carbon powder or graphite powder as the conductive medium for discharge. The advantage of this method is that it is suitable for most battery types, does not produce three wastes during the discharge process, and is easy to operate. However, the contact between the conductive powder is poor, the contact resistance is large, and the discharge is slow. At the same time, the conductive powder is easy to raise dust and pollute the environment during the loading and unloading process. The conductive powder is also easy to adhere to the battery surface during the discharge process, polluting the battery.

Method used

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  • A kind of safe discharge method of spent lithium-ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] The invention provides a method for safely discharging waste lithium-ion batteries, which specifically includes the following steps:

[0043] (1) First spread a layer of spherical aluminum particles with a weight of 2kg, a particle size of 5mm, and a resistance of 0.1Ω in the discharge frame, and then waste 2kg of 18650 steel shells with a rated capacity of 3Ah and an open circuit voltage of 3.6V Put the lithium battery evenly into the discharge frame, then add the remaining aluminum particles and mix them by hand. The total weight of the aluminum particles is 4kg;

[0044] (2) Compacting the waste lithium-ion battery and conductive particles with an initial pressurization pressure of 1000Pa, so that the waste lithium-ion battery is discharged; the internal resistance of the discharge frame is calculated according to the pressurized pressure to be 5Ω, according to the discharge frame The internal resistance of the body, the voltage of the used lithium battery and the ra...

Embodiment 2

[0049] The invention provides a method for safely discharging waste lithium-ion batteries, which specifically includes the following steps:

[0050] (1) First spread a layer of cylindrical graphite particles with a weight of 0.5kg, a particle size of 1mm, and a resistance of 20Ω in the discharge frame, and then waste 1kg of soft bags with a rated capacity of 20Ah and an open circuit voltage of 3.7V Put the lithium battery evenly into the discharge frame, then add the remaining graphite particles, and vibrate them by vibration. The total weight of the graphite particles is 1kg;

[0051] (2) Compacting the waste lithium-ion battery and conductive particles with 5000Pa pressurized pressure in advance, so that the waste lithium-ion battery is discharged; the internal resistance of the discharge frame is calculated according to the pressurized pressure to be 0.35Ω, according to the discharge frame The internal resistance, voltage and rated capacity of the waste lithium-ion battery ...

Embodiment 3

[0055] The invention provides a method for safely discharging waste lithium-ion batteries, which specifically includes the following steps:

[0056] (1) First spread a layer of irregular-shaped iron particles with a weight of 2kg, a particle size of 10mm, and a resistance of 10Ω in the discharge frame, and then scrap a 1kg aluminum shell with a rated capacity of 20Ah and an open circuit voltage of 4.0V Put the lithium battery evenly into the discharge frame, then add the remaining iron particles, and vibrate them, the total weight of the aluminum particles is 5kg;

[0057] (2) Compacting the waste lithium-ion battery and conductive particles with 100000Pa pressurized pressure in advance, so that the waste lithium-ion battery is discharged; the internal resistance of the discharge frame is calculated according to the pressurized pressure to be 0.23Ω, according to the discharge frame The discharge rate of the waste lithium-ion battery is calculated as 0.8C based on the internal ...

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Abstract

The invention provides a safe discharge method for waste lithium-ion batteries. The safe discharge method is to mix waste lithium-ion batteries and conductive particles in a discharge frame so that the waste lithium-ion batteries are discharged. Calculate the internal resistance of the discharge frame in real time, calculate the discharge rate based on the voltage and rated capacity of the waste lithium-ion battery, and dynamically adjust the pressurization pressure to maintain the discharge rate of the waste lithium-ion battery at 0.1-3C; at the same time, monitor the inside of the discharge frame in real time temperature, when the internal temperature is higher than the warning temperature, the pressurized pressure will drop to 40% to 80% of the original pressure; Reduce to 10% to 40% of the original pressure, re-pressurize and discharge until the discharge is completed. The safe discharge method of the invention is simple in operation, fast in discharge speed, environmentally friendly and pollution-free, and can realize industrial scale production.

Description

technical field [0001] The invention belongs to the technical field of recycling and pretreatment of waste lithium ion batteries, and in particular relates to a safe discharge method for waste lithium ion batteries. Background technique [0002] Lithium-ion batteries have the advantages of high energy density, no memory effect and excellent electrical performance, and have been widely used in electronic products, new energy vehicles, energy storage and other fields. By the end of 2019, my country had promoted a total of 3.81 million new energy vehicles. The service life of lithium-ion batteries is generally 3 to 8 years. At present, lithium-ion batteries are gradually entering the large-scale decommissioning period, and the recycling and disposal of lithium-ion batteries is imminent. [0003] At present, the recycling methods of waste lithium-ion batteries in my country are mainly dismantling, crushing, sorting, and element extraction processes to realize the recycling and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/44H01M10/54
CPCH01M10/445H01M10/443H01M10/54Y02W30/84B09B2101/16B09B3/32
Inventor 陈妹妹
Owner 深圳市杰成镍钴新能源科技有限公司
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