Intumescent flame-retardant coating for cables and preparation method of intumescent flame-retardant coating

A kind of flame retardant coating and expansion type technology, which is applied in the field of flame retardant coating for expansion type cables and its preparation, can solve the problems such as the decrease of the expansion ratio of the coating and the reduction of fire resistance performance, so as to improve the fire resistance limit, ensure the expansion ratio, and avoid The effect of the acid reaction

Inactive Publication Date: 2021-06-11
STATE GRID CORP OF CHINA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0017] We can see that with Fe 2 o 3 As the dosage increases, the foaming ratio of the paint will gradually decrease, because it will react with the acid source, which makes it difficult for the acid source to react with the carbonizing agent to dehydrate, so that the foaming ratio of the paint will decrease. The reason why the fire resistance limit rises first and then falls is because it can increase the strength of the foam layer while reducing the foaming ratio of the coating, ensuring the stable existence of the foam layer and ensuring the fire resistance effect. When ensuring the stable existence of the foam layer, the positive income When it is higher than the negative income brought by the decrease of the expansion ratio, the fire resistance limit increases. When the positive income of ensuring the stable existence of the foam layer is lower than the negative income brought about by the decrease of the expansion ratio, the fire resistance limit shows a downward trend, thus , the optimal solution is 6% addition, but this is the optimal solution under the limitation of the current technical solution
In fact, generally speaking, the existing intumescent fire retardant coatings still avoid the choice of Fe 2 o 3 Series of pigments and fillers, because with and without Fe 2 o 3 Compared with intumescent fireproof coatings with series of pigments and fillers, adding Fe 2 o 3 Series of pigments and fillers will indeed reduce its fire resistance to a certain extent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A flame retardant coating for intumescent cables, comprising the following raw materials: A component: base material: 25.0 parts by weight of silicon acrylic emulsion; B component: acid source: 27.5 parts by weight of ammonium polyphosphate; carbonizing agent: 16.5 parts by weight of pentaerythritol; Foaming agent: 16.5 parts by weight of melamine; additives: 5.0 parts by weight of expandable graphite, 8.0 parts by weight of phthalocyanine, 12.0 parts by weight of silane coupling agent modified Fe 2 o 3 ; C component: 6.0 parts by weight of curing agent.

[0034] Further, the silane coupling agent modified Fe 2 o 3 by Fe 2 o 3 , silane coupling agent, absolute ethanol, and deionized water, Fe 2 o 3 , silane coupling agent, absolute ethanol, and deionized water in a mass ratio of 16:1:2:1.

[0035] Further, the degree of polymerization of the ammonium polyphosphate is >1000.

[0036] Further, the purity of the melamine is ≥99%.

[0037] Further, the silane coupl...

Embodiment 2

[0047] A flame retardant coating for intumescent cables, comprising the following raw materials: A component: base material: 20.0 parts by weight of silicon acrylic emulsion; B component: acid source: 25.0 parts by weight of ammonium polyphosphate; carbonizing agent: 15.0 parts by weight of pentaerythritol; Foaming agent: 15.0 parts by weight of melamine; additives: 3.0 parts by weight of expandable graphite, 6.0 parts by weight of phthalocyanine, 16.0 parts by weight of silane coupling agent modified Fe 2 o 3 ; C component: 4.0 parts by weight of curing agent.

[0048] Further, the silane coupling agent modified Fe 2 o 3 by Fe 2 o 3 , silane coupling agent, absolute ethanol, and deionized water, Fe 2 o 3 , silane coupling agent, absolute ethanol, and deionized water in a mass ratio of 100:3:6:3.

[0049] Further, the degree of polymerization of the ammonium polyphosphate is >1000.

[0050] Further, the purity of the melamine is ≥99%.

[0051] Further, the silane coup...

Embodiment 3

[0061] A flame retardant coating for intumescent cables, comprising the following raw materials: A component: base material: 21.0 parts by weight of silicon acrylic emulsion; B component: acid source: 26.0 parts by weight of ammonium polyphosphate; carbonizing agent: 15.0 parts by weight of pentaerythritol; Foaming agent: 16.5 parts by weight of melamine; additives: 4.0 parts by weight of expandable graphite, 7.0 parts by weight of phthalocyanine, 13.0 parts by weight of silane coupling agent modified Fe 2 o 3 ; C component: 5.0 parts by weight of curing agent.

[0062] Further, the silane coupling agent modified Fe 2 o 3 by Fe 2 o 3 , silane coupling agent, absolute ethanol, and deionized water, Fe 2 o 3, silane coupling agent, absolute ethanol, and deionized water in a mass ratio of 45:2:4:2.

[0063] Further, the degree of polymerization of the ammonium polyphosphate is >1000.

[0064] Further, the purity of the melamine is ≥99%.

[0065] Further, the silane coupli...

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Abstract

The invention discloses an intumescent flame-retardant coating for cables and a preparation method of the intumescent flame-retardant coating. The intumescent flame-retardant coating for cables comprises the following raw materials: a component A including a base material, namely, 20.0-25.0 parts by weight of silicone acrylic emulsion; a component B including an acid source, namely, 25.0-27.5 parts by weight of ammonium polyphosphate, a carbonizing agent, namely, 15.0-16.5 parts by weight of pentaerythritol, a foaming agent, namely, 15.0-16.5 parts by weight of melamine, and auxiliaries, namely, 3.0-5.0 parts by weight of expandable graphite, 6.0-8.0 parts by weight of phthalocyanine and 12.0-16.0 parts by weight of silane coupling agent modified Fe2O3; and a component C including 4.0-6.0 parts by weight of a curing agent. The preparation method of theintumescent flame-retardant coating for cables comprises the steps of a, preparing silane coupling agent modified Fe2O3; b, uniformly mixing silane coupling agent modified Fe2O3, expandable graphite, phthalocyanine, ammonium polyphosphate, pentaerythritol and melamine to obtain a component B; c, adding the component B into the component A, uniformly stirring to obtain a component A and component B mixture, and sealing; d, sealing the component C; and e, mixing the mixture of the component A and the component B with the component C during use to obtain the intumescent flame-retardant coating for cables.

Description

technical field [0001] The invention belongs to the technical field of flame-retardant coatings for cables, and in particular relates to a flame-retardant coating for intumescent cables and a preparation method thereof. Background technique [0002] Cable trenches are underground pipelines used to lay and replace power or telecommunication cable facilities. Fires in cable trenches often cause huge economic losses and even casualties. [0003] There are two reasons for cable trench fire accidents. One is the fire caused by the cable itself. ditch fire, external factors include construction sparks, poor ventilation, etc. Generally speaking, after the cable laying in the cable trench is completed, we focus on prevention of external factors, and it is difficult for us to avoid the fire caused by the cable itself by controlling the external factors. Therefore, it is necessary to strengthen the protection of the cable itself. fire resistance. [0004] Cable fireproof coating is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/04C09D5/18C09D7/61C09D7/62C09D7/63
CPCC09D143/04C09D5/185C09D7/61C09D7/62C09D7/63C08K2003/323C08K2003/2272C08K13/06C08K3/32C08K5/053C08K5/34922C08K3/04C08K9/06C08K3/22C08K5/3467
Inventor 王磊曹翀李孟超郑罡南钰
Owner STATE GRID CORP OF CHINA
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