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Curing agent for efficiently repairing arsenic-polluted soil and application thereof

An arsenic pollution and curing agent technology, applied in the restoration of polluted soil and other directions, can solve problems such as soil environmental balance damage, and achieve the effect of facilitating subsequent utilization, good effect and simple operation.

Active Publication Date: 2021-07-16
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when too much iron-containing material is added, it will cause damage to the balance of the soil environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Provides a high-efficiency curing agent for repairing arsenic-contaminated soil, including 20mL of ammonia water, 80g of ferrous sulfate and 40g of sepiolite; wherein the concentration of ammonia water is 25-28%, and the particle size of sepiolite is 100 mesh.

[0020] The application of the above-mentioned curing agent for repairing arsenic-contaminated soil in arsenic-contaminated soil is specifically:

[0021] Stir the arsenic-contaminated soil (the content of arsenic is 500mg / kg) to loosen it, and then add ammonia water, ferrous sulfate and sepiolite in the curing agent to the soil respectively, wherein the amount of curing agent added is: the concentration of ammonia water 20mL / kg soil, ferrous sulfate 80g / kg soil, sepiolite 40g / kg soil, and stir the soil to make it mix with the curing agent, then adjust the soil moisture content to maintain 35%, and the measured soil pH is 8.3, Use 3% dilute hydrochloric acid to adjust soil pH to keep it in the range of 6-7, and c...

Embodiment 2

[0024] Provides a high-efficiency curing agent for repairing arsenic-contaminated soil, including 15mL of ammonia water, 70g of ferrous sulfate, and 35g of sepiolite; wherein the concentration of ammonia water is 25-28%, and the particle size of sepiolite is 100 mesh.

[0025] The application of the above-mentioned curing agent for repairing arsenic-contaminated soil in arsenic-contaminated soil is specifically:

[0026] Stir the arsenic-contaminated soil (the content of arsenic is 500mg / kg) to loosen it, and then add ammonia water, ferrous sulfate and sepiolite in the curing agent to the soil respectively, wherein the amount of curing agent added is: the concentration of ammonia water 15mL / kg soil, ferrous sulfate 70g / kg soil, sepiolite 35g / kg soil, and stir the soil to make it mix with the curing agent, then adjust the soil moisture content to maintain 35%, the pH of the measured soil is 8.2, Use 3% dilute hydrochloric acid solution to adjust soil pH to keep it in the range ...

Embodiment 3

[0029] A curing agent for efficiently repairing arsenic-contaminated soil is provided, including 25mL of ammonia water, 75g of ferrous sulfate, and 45g of sepiolite; wherein the concentration of ammonia water is 25-28%, and the particle size of sepiolite is 100 mesh.

[0030] The application of the above-mentioned curing agent for repairing arsenic-contaminated soil in arsenic-contaminated soil is specifically:

[0031] Stir the arsenic-contaminated soil (the content of arsenic is 500mg / kg) to loosen it, and then add ammonia water, ferrous sulfate and sepiolite in the curing agent to the soil respectively, wherein the amount of curing agent added is: the concentration of ammonia water 25mL / kg soil, ferrous sulfate 75g / kg soil, sepiolite 45g / kg soil, and stir the soil to make it mix with the curing agent, then adjust the soil moisture content to maintain 35%, the pH of the measured soil is 8.9, Use 3% dilute hydrochloric acid solution to adjust soil pH to keep it in the range o...

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Abstract

The invention discloses a curing agent for efficiently repairing arsenic-polluted soil and application thereof. The curing agent comprises ammonia water, ferrous sulfate and sepiolite, wherein the volume mass ratio of the ammonia water to the ferrous sulfate to the sepiolite is (15-25) mL: (70-85) g: (35-45) g. The curing agent is simple in component, the raw materials are cheap and easy to obtain, when the curing agent is used for repairing the arsenic-polluted soil, high-toxicity arsenic III can be basically and completely oxidized into arsenic V, arsenic V generates arsenic iron ore and iron arsenate to be co-precipitated or adsorbed and fixed, and therefore the arsenic toxicity and mobility of the soil are reduced, and efficient repairing of the arsenic-polluted soil is achieved.

Description

technical field [0001] The invention belongs to the technical field of heavy metal-contaminated soil treatment, and in particular relates to a curing agent for efficiently repairing arsenic-contaminated soil and an application thereof. Background technique [0002] Soil pollution is a very important environmental pollution problem in our country today, and it is urgent to solve this problem. In the remediation of arsenic pollution in soil, the most commonly used curing agents are environmental mineral materials and iron-containing materials, but environmental mineral materials (such as sepiolite) have limited remediation effects on arsenic-contaminated soil, and generally need to be modified to achieve Better repair effect. Iron-containing agents are a kind of very ideal arsenic-contaminated soil remediation materials, but in the process of remediating arsenic-contaminated soil, the amount of iron-containing materials will also affect the effect of arsenic fixation. General...

Claims

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Application Information

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IPC IPC(8): B09C1/08
CPCB09C1/08
Inventor 黄永炳谢依廷肖谣汤冬梅李智鹏李颜政
Owner WUHAN UNIV OF TECH