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Antibacterial glass product and preparation method thereof

A technology for antibacterial glass and glass products, applied in the field of glass products, can solve the problems of high process cost, time-consuming and high cost, and achieve the effects of simple and easy operation, low cost and few raw materials in the preparation method

Active Publication Date: 2021-08-31
胡波
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] CN105523266B discloses adding silver nitrate in potassium nitrate and realizing the exchange of glass surface ions and silver ions through high-temperature melting. The temperature required for high-temperature melting is very high, resulting in high process costs
CN111499219A discloses adding silver nitrate in aqueous solution and spraying on the container surface, heating at high temperature to promote ion exchange, this process is complicated, and the dispersion liquid has fluidity, it is difficult to form a uniform surface functional layer, it is difficult to form an effective antibacterial layer and Generate sufficient enriched silver ions on the container surface
When the ion diffusion method is used to form a silver infiltration layer on the glass surface, the conventionally used process is more complicated and has many steps, especially when performing the thermal diffusion step, the required process temperature is high, time-consuming and costly. And the antibacterial effect of the obtained antibacterial glass products is not durable

Method used

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  • Antibacterial glass product and preparation method thereof
  • Antibacterial glass product and preparation method thereof

Examples

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preparation example Construction

[0039] This specific embodiment provides a kind of preparation method of antibacterial glass product, comprises the following steps:

[0040] S1: Prepare 500ppm (0.05wt%) silver nitrate aqueous solution and place it in a reaction kettle; clean the borosilicate glassware, soak the borosilicate glassware in the silver nitrate aqueous solution, the borosilicate glassware Both the inner and outer surfaces were immersed in the silver nitrate aqueous solution.

[0041] S2: Set the temperature in the reactor to 110°C-200°C. Correspondingly, the specific system pressure can be obtained by setting the temperature; make the silver nitrate aqueous solution into a subcritical state aqueous solution, and maintain the temperature for reaction for 60 minutes.

[0042] S3: After the reaction is completed, the temperature is lowered, and the borosilicate glass vessel doped with silver ions on the surface is taken out, ultrasonically cleaned, and vacuum-dried in an oven for 10-60 minutes.

[0...

Embodiment 1

[0045] Embodiment 1 prepares the silver nitrate aqueous solution of 500ppm, puts the silver nitrate aqueous solution in the reaction kettle; cleans the borosilicate glassware, soaks the borosilicate glassware in the silver nitrate aqueous solution, the inner surface of the glassware and The outer surfaces were all immersed in the silver nitrate aqueous solution. The temperature in the reactor was set at 110° C. to make the silver nitrate aqueous solution into a subcritical aqueous solution, and the temperature was maintained for 60 minutes to carry out the reaction. Cool down after the reaction, take out the borosilicate glass vessel doped with silver ions on the surface, clean it with ultrasonic waves, and dry it in a vacuum oven for 30 minutes.

Embodiment 2

[0046] The difference between Example 2 and Example 1 is that the temperature in the reactor is set to 125°C.

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Abstract

The invention discloses an antibacterial glass product and a preparation method thereof. The preparation method of the antibacterial glass product comprises the following steps: 1, in a reaction kettle, providing a silver salt aqueous solution and a glass product containing sodium ions, and covering at least part of the surface of the glass product with the silver salt aqueous solution; 2, setting the temperature and pressure in the reaction kettle to make the silver salt aqueous solution become a subcritical state aqueous solution, and carrying out a reaction; and 3, cooling after the reaction is finished, taking out the glass product doped with the silver ions on the surface, cleaning and drying. The preparation method of the antibacterial glass product provided by the invention is simple and easy to operate and short in time consumption, and the cost is greatly reduced. A silver ion antibacterial layer which is uniformly distributed can be obtained on the surface of the glass product without a high-temperature annealing step, and the obtained antibacterial glass product has a lasting antibacterial effect.

Description

technical field [0001] The invention belongs to the technical field of glass products, and in particular relates to an antibacterial glass product and a preparation method thereof. Background technique [0002] Glass products are often used to place food, and glass products for food are required to have certain antibacterial properties. Some of the existing antibacterial glass products are usually formed on the surface of the glass products to achieve their antibacterial properties, and one of the methods for forming the antibacterial layer is to form a silver ion layer on the surface of the glass products by ion diffusion. [0003] CN105523266B discloses adding silver nitrate into potassium nitrate and exchanging glass surface ions and silver ions through high-temperature melting. The temperature required for high-temperature melting is very high, resulting in high process costs. CN111499219A discloses adding silver nitrate in aqueous solution and spraying it on the surfac...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C21/00
CPCC03C21/005Y02A50/30
Inventor 胡波
Owner 胡波
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