[0027] Next, the technical solutions in the present application embodiment will be described in the following examples, and the embodiments described herein are described herein, not all of the embodiments of the present disclosure. Based on the embodiments in the present application, all other embodiments obtained without creative labor are not made in the pre-creative labor premises.
[0028] The term "first", "second", "second", or the like in the specification of the present application and the like are used to distinguish a similar object, and is not intended to describe a particular order or ahead order. It should be understood that the data such as use can be interchanged in appropriate, so that the embodiments of the present application can be implemented in the order other than those illustrated or described herein, and "first", "second", etc. Objects are usually a class, and the number of objects is not limited, such as one of the first object, or multiple. In addition, the specification and the claim "and / or" represent at least one of the connected objects, characters "/", generally indicating that the front and rear association object is a "or" relationship.
[0029] Next, a circulating fixed bed provided by the present application embodiment will be described in detail by specific embodiments and their application scenarios.
[0030] See Figure 1-5 The embodiment of the present application provides a circulating fixed bed for circulating the production of carbon material, including a temperature control body 10, at least one temperature control segment reactor 20, controller 30, the reactor 20 at least partially in the temperature. Inside the control body 10, the temperature control body 10 controls the temperature of each temperature control segment reactor 20;
[0031] The reactor 20 includes a rotating body 21, an AB tube 22, and the AB tube 22 comprises a tube 221, a B tube 222, and the A tube 221 is set to each other and relatively moving;
[0032] The controller 30 controls the material into the AB tube 22 to react to form a carbon material, which controls the rotating body 21 to rotate the A tube 221 relative to the B tube 222 to rotate to feed and extract. The A tube 221 is reused at different angles with respect to the B tube 222 weeks to achieve cyclic production carbon material.
[0033] In the present application embodiment, at least one temperature control segment reactor 20 is employed for a variety of mixed gases, the temperature value of the various gases can be adjusted to solve, save materials, for a single gas source, can achieve sufficient preheating acceleration Reaction time; use AB tube 22 mutual movement, control the feed and discharge cycle, make it scale and industrialization, shorten the production cycle, intelligent, high yield; use exhaust gas temperature auxiliary heating reactor to enable energy secondary Using more efficient and environmentally friendly, energy saves energy; at the same time, the rotation can also be pushed with exhaust gas, the overall structure is simple, reliable, efficient, not only adequately reacted, fully utilized, but also realizes the recyclability of the fixed bed, while control AB tube The rotation of 22 can also achieve more adequacy, and the material heat transfer is more uniform, and more materials can be added, and the quality of the carbon material is better and more uniform. This application can solve problems that cannot save energy and high yield in the prior art.
[0034] It should be noted that in the embodiment of the present invention, the at least one temperature control section reactor 20 means that a temperature control segment reactor 20 may also include a plurality of temperature control segments 20, including a temperature control. The segment reactor 20 is that the controller 30 can only adjust one temperature, while the plurality of temperature control segments 20 can control a variety of different temperatures.
[0035] It should be noted that in the embodiments of the present invention, each control, communication between the plurality of temperature control segments, to ensure connectivity of the air source.
[0036] It should be noted that in the embodiment of the present invention, when the reactor 20 is a temperature control section, a plurality of fixed beds can be used to implement a heat transfer zone control.
[0037] It should be noted that in the embodiment of the present invention, the A tube 221 and the B tube 222 are relative motion, and the two can be set, and the A tube can be outside, and can be rotated outside, or Inner side rotation.
[0038] It should be noted that in the embodiment of the present invention, the material is not limited to the gas source, or a liquid or solid particle, a gas source, for example: alkane, hydrocarbon, or a carbon dioxide, etc., the liquid can be ethanol, B Diol, aqueous solution, etc., the solid particles may be an oxide, a compound, a mixture, or the like, or the like, or the like, or the like.
[0039] It should be noted that in the embodiment of the present invention, the position of the feed port is not limited, and is usually from both ends from the AB tube 22, and solid or liquid or solids containing a gas source can be The pipe sidewall increases the position to facilitate access.
[0040] It should be noted that in the embodiment of the present invention, the generated carbon material is sent out by an in-force, and the size of the inlet is not limited, and the carbon material sent into the collector 23 is collected.
[0041] Wherein, the collector 23 is controlled by the controller 30 to communicate with the AB pipe.
[0042] It should be noted that in the embodiment of the present invention, it is repeatedly referred to the repeated reaction cycle in the embodiment, and after the reaction is completed, the feed is achieved, and the newly reactive material is filled, the temperature remains unchanged, continuous reactions, no temperature rise cooling Waiting for operation.
[0043] Among them, the A tube 221 is rotated relative to the B tube 222, and during the reaction, the A tube 221 can be slowly rotated to ensure a sufficient reaction of the material such as the catalyst in the A tube 221, so that the catalyst of the bottom surface also functions, so that the reactor More catalysts can be added to produce greater yield, and the heat transfer of each of the catalyst particles is more uniform, and the quality of the carbon material grown is higher, and it is even more uniform.
[0044] It should be noted that in the embodiment of the present invention, the A tube 221 can also be rotated from the B tube 222 during the reaction, and the A tube 221 and the B tube 222 are relatively rotated after the reaction is completed to achieve the change of the new material.
[0045]It should be noted that in the embodiment of the present invention, the A tube 221 can also be rotated in a positive and reverse direction cycle relative to the B tube 222 to move the particles or liquid to the liquid.
[0046] It should be noted that in the embodiment of the present invention, the A tube 221 and the B tube 222 may be a C shape, and when both rotate to the diameter alignment, the carbon material is sent, and the material reaction is sent to the material.
[0047] It should be noted that in the embodiment of the present invention, the A tubes 221 and the B tube 222 may also be panel-shaped and bucket, and the A tube 221 is divided into two parts, wherein a portion is used as the reaction area, and the other is used. In the feed and extract, the plate-like structure is rotated to achieve cycle production.
[0048] Preferably, the exhaust gas of the AB tube 22 is in communication with the temperature control body 10 for auxiliary heating for the reactor 20.
[0049] It should be noted that in the embodiment of the present invention, the exhaust gas-assisted heating is to collect or separate after the exhaust gas is saved, and the exhaust gas can be collected or separated.
[0050] Preferably, the AB tube 22 comprises at least one set of entrance ports to enter and exit the material.
[0051] It should be noted that in the embodiment of the present invention, the meaning of at least one set means that there is an inlet and outlet in both ends of the AB tube 22. To increase other solids or liquids, it is necessary to increase the import, and the carbon generated Materials need to be taken, need to increase the export, of course, the newly added imported and exports can be the same.
[0052] Preferably, the temperature control body 10 comprises a primary heating source and auxiliary heating source, the auxiliary heating source being heated.
[0053] It should be noted that in the embodiment of the present invention, the main heating source can employ universal technology on the current market, such as heating wire, electromagnetic, or the like, and the auxiliary heating can be heated with exhaust gas. In order to better control the desired temperature, it is necessary to add a temperature sensor to monitor the current temperature in real time. On the basis of the auxiliary heating, the main heating source replenishes heating, which is automatically stopped, real-time control, and maintains temperature when the set temperature is replenished.
[0054] Preferably, the material comprises at least carbon-containing substances, catalysts, the carbon-containing substance comprising ethanol, methane, ethylene glycol, propylene, the catalyst comprising iron oxide, iron nitrate, nickel,;
[0055] The carbon material comprises carbon nanotubes, graphene, graphite.
