Magnetoelectric storage element of ferroelectric/ferromagnetic composite film based on PMN-PT and preparation method thereof

A ferromagnetic thin film and magnetoelectric storage technology, applied in the fields of magnetic field controlled resistors, manufacturing/processing of electromagnetic devices, material selection, etc., can solve problems such as limited storage density, limited memory application, and destructive reading process , to achieve low power consumption, good ferroelectric effect

Pending Publication Date: 2022-04-05
TIANJIN UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But it has two disadvantages: the reading process is destructive, and the storage density is limited
These two storage methods greatly limit its application as a memory

Method used

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  • Magnetoelectric storage element of ferroelectric/ferromagnetic composite film based on PMN-PT and preparation method thereof
  • Magnetoelectric storage element of ferroelectric/ferromagnetic composite film based on PMN-PT and preparation method thereof
  • Magnetoelectric storage element of ferroelectric/ferromagnetic composite film based on PMN-PT and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] The steps of preparing 30nm ferromagnetic film by ion beam sputtering are as follows:

[0043] 1) Clean the PMN-PT substrate with deionized water and dry it, put the substrate into the glue homogenizer, and spin-coat the photoresist solution on the surface of the substrate; set the first stage and accelerate the rotating tray to 800r / min to keep 10s; then the second stage accelerates the rotating tray to 3800r / min for 60s. Evaporate excess water to dryness on a hot plate, align the mask plate with the photolithography machine, and set the exposure time to 6s for photolithography. Mix the developer solution with water at a ratio of 1:10. Then put the exposed PMN-PT single crystal substrate into a developing solution, set a developing time of 15s, then put it into clean water for cleaning, and then bake the substrate at a temperature of 100°C.

[0044] 2) The PMN-PT single crystal piezoelectric substrate and Fe 65 co 35 The alloy target is placed in the sputtering cha...

Embodiment 2

[0048] The steps of preparing 20nm ferromagnetic film by ion beam sputtering are as follows:

[0049] 1) Clean the PMN-PT substrate with deionized water and dry it, put the substrate into the glue homogenizer, and spin-coat the photoresist solution on the surface of the substrate; set the first stage and accelerate the rotating tray to 800r / min to keep 10s; then the second stage accelerates the rotating tray to 3800r / min for 60s. Evaporate excess water to dryness on a hot plate, align the mask plate with the photolithography machine, and set the exposure time to 6s for photolithography. Mix the developer solution with water at a ratio of 1:10. Then put the exposed PMN-PT single crystal substrate into a developing solution, set a developing time of 15s, then put it into clean water for cleaning, and then bake the substrate at a temperature of 100°C.

[0050] 2) The PMN-PT single crystal piezoelectric substrate and Fe 65 co 35 The alloy target is placed in the sputtering cha...

Embodiment 3

[0053] The steps of preparing 40nm ferromagnetic film by ion beam sputtering are as follows:

[0054] 1) Clean the PMN-PT substrate with deionized water and dry it, put the substrate into the glue homogenizer, and spin-coat the photoresist solution on the surface of the substrate; set the first stage and accelerate the rotating tray to 800r / min to keep 10s; then the second stage accelerates the rotating tray to 3800r / min for 60s. Evaporate excess water to dryness on a hot plate, align the mask plate with the photolithography machine, and set the exposure time to 6s for photolithography. Mix the developer solution with water at a ratio of 1:10. Then put the exposed PMN-PT single crystal substrate into a developing solution, set a developing time of 15s, then put it into clean water for cleaning, and then bake the substrate at a temperature of 100°C.

[0055] 2) The PMN-PT single crystal piezoelectric substrate and Fe 65 co 35 The alloy target is placed in the sputtering cha...

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Abstract

The invention discloses a magnetoelectric storage element of a ferroelectric / ferromagnetic composite film based on PMN-PT and a preparation method of the magnetoelectric storage element, and belongs to the technical field of semiconductor integrated circuits, and the preparation of a small-size FeCo ferromagnetic film comprises the following steps of: masking a specific pattern on a PMN-PT single crystal substrate by utilizing ion beam deposition in combination with a photoetching process; and the PMN-PT single crystal piezoelectric substrate and the Fe65Co35 alloy target material are placed in a sputtering chamber, and the ferromagnetic thin film is prepared through ion beam sputtering. Compared with a traditional nonvolatile memory, the magnetoelectric memory element obtained by the invention has the advantages of low power consumption and high read-write speed, and has important significance for meeting the actual requirements of future memory devices. The layered composite film device is prepared by ion beam sputtering, and the process is simple and compatible with a semiconductor process.

Description

technical field [0001] The invention particularly relates to a magnetoelectric storage element based on a PMN-PT ferroelectric / ferromagnetic composite thin film and a preparation method thereof. Background technique [0002] With the rapid development of information technology in today's society, storage technology is required to provide memory with larger capacity, faster speed, smaller volume, longer service life and lower power consumption. Traditional information storage methods include ferroelectric random access memory (FeRAM) and magnetic memory (MRAM). Ferroelectric random access memory uses the spontaneous polarization of ferroelectrics to store information. It has the advantages of high durability, fast read and write speed, low power consumption, and reliable multi-level polarization states. It is a mature and promising non-volatile memory. volatile memory. But it has two disadvantages: the reading process is destructive, and the storage density is limited. Mag...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): H01L43/08H01L43/10H01L43/12C23C14/04C23C14/18C23C14/46H10N50/10H10N50/01
Inventor韩叶梅马美冰尹鑫曹海兴孙正王芳张楷亮
OwnerTIANJIN UNIVERSITY OF TECHNOLOGY