Compound containing 1, 3-diketone ligand, application of compound and organic electroluminescent device

A compound and ligand technology, applied in the field of organic electroluminescent devices, can solve the problems of large efficiency roll-off and low luminous efficiency, and achieve the effects of improving lifespan, luminous efficiency and thermal stability

Pending Publication Date: 2022-05-13
BEIJING GREEN GUARDEE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to overcome the problems of large efficiency roll-off and low luminous efficiency in existing organic electroluminescent devices

Method used

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  • Compound containing 1, 3-diketone ligand, application of compound and organic electroluminescent device
  • Compound containing 1, 3-diketone ligand, application of compound and organic electroluminescent device
  • Compound containing 1, 3-diketone ligand, application of compound and organic electroluminescent device

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1-3

[0073] According to particularly preferred embodiments 1-3 , in Ir(L A )(L B ) 2 In the structure shown,

[0074] In formula (IA), R 1 , R 2 , R 3 , R 4 each independently selected from H, C 1 -C 7 Alkyl, C 6 -C 10 Aryl; or R 1 with R 2 combination of and R 3 with R 4 At least one of the combinations of the combinations is ring-closed to form a 4-6 membered saturation;

[0075] In formula (IB), X is C or N,

[0076] Q ring is selected from substituted or unsubstituted benzene ring, substituted or unsubstituted quinoline ring, substituted or unsubstituted isoquinoline ring, substituted or unsubstituted naphthalene ring, substituted or unsubstituted phenanthrene ring, substituted or unsubstituted Substituted benzothiophene ring, substituted or unsubstituted benzofuran ring, substituted or unsubstituted indole ring, substituted or unsubstituted benzothiazole ring, substituted or unsubstituted benzoxazole ring, substituted or unsubstituted Substituted benzimidazo...

specific Embodiment approach 1-4

[0081] According to particularly preferred embodiments 1-4 , in Ir(L A )(L B ) 2 In the structure shown,

[0082] In formula (IA), R 1 , R 2 , R 3 , R 4 each independently selected from H, methyl, ethyl, C 3 straight chain alkyl, C 3 branched chain alkyl, C 3 Cycloalkyl, C 4 straight chain alkyl, C 4 branched chain alkyl, C 4 Cycloalkyl, C 5 straight chain alkyl, C 5 branched chain alkyl, C 5 Cycloalkyl, C 6 straight chain alkyl, C 6 branched chain alkyl, C 6 Cycloalkyl, C 7 straight chain alkyl, C 7 branched chain alkyl, C 7 Cycloalkyl, phenyl; or R 1 with R 2 combination of and R 3 with R 4 At least one combination of the combinations is ring-closed to form a 4-6 membered saturated ring;

[0083] In formula (IB), X is C or N,

[0084] Q ring is selected from substituted or unsubstituted benzene ring, substituted or unsubstituted quinoline ring, substituted or unsubstituted isoquinoline ring, substituted or unsubstituted naphthalene ring, substituted ...

specific Embodiment approach 1-6

[0097] According to particularly preferred embodiments 1-6 , in Ir(L A )(L B ) 2 In the structure shown,

[0098] L A selected from the structures shown in claim 6; and

[0099] L B Selected from the structures shown in claim 7.

[0100] According to preferred embodiments 1-7 , Ir(L A )(L B ) 2 The structure shown is selected from the structures shown in claim 8.

[0101] The present invention has no special limitation on the preparation method of the compound containing 1,3-diketone ligand described in the aforementioned first aspect, and those skilled in the art can determine the appropriate reaction route according to the structural formula combined with known methods in the field of organic synthesis . The following sections of the present invention exemplarily provide several methods for preparing the compounds containing 1,3-diketone ligands described in the first aspect, which should not be understood by those skilled in the art to limit the present invent...

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Abstract

The invention relates to the field of organic electroluminescent devices, and discloses a compound containing a 1, 3-diketone ligand, application of the compound and an organic electroluminescent device. The compound has a structure as shown in Ir (LA) (LB) 2, LA has a structure as shown in a formula (IA), and LB is a structure as shown in a formula (IB), a structure as shown in LB310, a structure as shown in LB311, a structure as shown in LB312, a structure as shown in LB313 or a structure as shown in LB314. The compound containing the 1, 3-diketone ligand provided by the invention has the advantages of small synthesis difficulty and easy purification, has excellent luminescence performance when being used as an organic electrophosphorescent material, can prolong the service life of a device, can increase the solubility of the phosphorescent material, and can reduce the probability of triplet state-triplet state quenching.

Description

technical field [0001] The invention relates to the field of organic electroluminescent devices, in particular to a compound containing 1,3-diketone ligand and application thereof, and an organic electroluminescent device. Background technique [0002] Compared with traditional liquid crystal technology, organic electroluminescent technology does not require backlight illumination and color filters, and pixels can emit light by themselves on a color display panel. Moreover, it has ultra-high contrast, ultra-wide viewing angle, and curved surface. , thin and other characteristics. [0003] In 1987, Dr. Deng Qingyun of Kodak Company reported two organic semiconductor materials based on 8-hydroxyquinoline aluminum with high fluorescence efficiency and good electron transport properties and aromatic diamine with good hole transport properties, prepared by thermal evaporation. Double-layer OLED device, the external quantum efficiency of the device reaches 1% for the first time, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F15/00C09K11/06H01L51/54
CPCC07F15/0033C09K11/06C09K2211/185H10K85/342
Inventor 吕瑶冯美娟
Owner BEIJING GREEN GUARDEE TECH
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