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Preparation method of rare earth composite material

A composite material and rare earth technology, applied in the field of metal materials, can solve the problems of insufficient mechanical properties, difficult structural parts, poor energy release effect, etc., and achieve the effect of good energy release effect.

Pending Publication Date: 2022-06-03
厦门欧斯拓科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, metal energy-releasing materials mainly use highly active elements such as Zr and Al as the main energy-releasing elements, which achieve combustion effects in environments with high air or oxygen content, but usually release energy in low-pressure anoxic and underwater environments. Poor, and its mechanical properties are insufficient, it is difficult to be used in structural parts

Method used

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  • Preparation method of rare earth composite material
  • Preparation method of rare earth composite material
  • Preparation method of rare earth composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The preparation method of the rare earth composite material of the present embodiment includes the following steps:

[0044] Raw material mixing: M powder with a particle size D50 of 6.0 μm and 58# paraffin are put into the mixer according to the ratio of 99:1 to 98:2 for mixing, and the mixing time is 24h.

[0045] Compression molding: put the mixed powder into a rubber sleeve, and press and shape in an isostatic press according to the compression pressures of Examples 1.1-1.8 and Comparative Examples 1.1-1.2 in Table 1, and hold the pressure for 30s.

[0046] Degreasing: Place the formed body in trichloroethylene solvent at 50°C to remove part of the 58# paraffin, and then perform thermal degreasing at 500°C.

[0047] Sintering treatment: put the compact into a vacuum furnace, fill the furnace with hydrogen and heat it up to 2100°C, sinter for 10 hours, and obtain M skeleton after cooling in the furnace.

[0048] Infiltration treatment: put the rare earth element int...

Embodiment 2

[0065] The preparation method of the rare earth and tungsten composite material of the present embodiment includes the following steps:

[0066] Raw material configuration and mixing: Put tungsten powder with a particle size D50 of 7.0μm and 58# paraffin into the mixer according to the ratio of 99:1 to 98:2, and the mixing time is 36h.

[0067] Compression molding: Put the mixed powder into a rubber sleeve, and press and shape in an isostatic press according to the compression pressures of Examples 2.1-2.8 and Comparative Examples 2.1-2.2 in Table 4, and the pressure holding time is 25s.

[0068] Degreasing: Place the formed body in trichloroethylene solvent at 70°C to remove part of the 58# paraffin, and then perform thermal degreasing at 450°C.

[0069] Sintering and dehydrogenation: put the compact into a vacuum furnace, fill the furnace with hydrogen and heat it up to 2100 ° C, sinter for 10 hours, and obtain a tungsten skeleton after cooling in the furnace.

[0070] Infi...

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Abstract

The invention discloses a preparation method of a rare earth composite material, the chemical formula of the rare earth composite material is R-H-M, R-H exists in the form of a rare earth hydride, R is selected from at least one of lanthanide rare earth elements and Y elements, M is selected from at least one of W or Mo, and M is selected from at least one of Y and Y elements. The preparation method comprises the following steps: mixing M powder and a forming agent in a mixer; carrying out compression molding on the mixed M powder; degreasing and sintering the formed green body, and cooling along with a furnace to obtain an M framework with the porosity of 10-40%; immersing the M skeleton into a molten liquid of R for infiltration treatment, and separating the M skeleton after infiltration treatment from redundant R; and cooling the obtained M framework, and carrying out heat treatment in a hydrogen atmosphere to prepare the rare earth composite material. The rare earth composite material disclosed by the invention has high energy release and can realize efficient energy release in an oxygen-free environment, and the application environment of a metal energy release material is remarkably improved.

Description

technical field [0001] The invention relates to metal materials, in particular to a preparation method of rare earth composite materials. Background technique [0002] For the currently known metal energy release materials, the energy release mechanism is that an element that is easier to react with oxygen reacts with oxygen, releasing a large amount of heat; the second is the reaction between metal and metal or between metal and intermediate products. At present, metal energy release materials mainly use Zr, Al and other highly active elements as the main energy release elements, and achieve combustion effect in an environment with high air or oxygen content, but usually in low-pressure oxygen-deficient, underwater and other environments. poor, and its mechanical properties are insufficient, making it difficult to use in structural components. How to prepare an energy-releasing metal that can achieve high-efficiency energy release in an oxygen-free environment, has strong ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22D23/04B22F3/02B22F3/11B22F3/26C22C1/04C22C27/04C22F1/02C22F1/18B22F3/24
CPCC22C1/045C22C27/04B22F3/02B22F3/1007B22F3/1021B22F3/11B22D23/04B22F3/26C22F1/02C22F1/18B22F3/24B22F2003/248
Inventor 吕延伟郑建平吴建鹏张畅王子秋
Owner 厦门欧斯拓科技有限公司