Optical filter and display using the same
A technology of filters and appliances, applied in the fields of filters, optics, instruments, etc., can solve problems such as filters that have not yet been found
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[0170] Examples and comparative examples are given below to further specifically illustrate the present invention. These descriptions are not intended to limit the present invention. In the following, Ph represents a phenyl group, and Pc represents a phthalocyanine.
Synthetic example 1
[0171] Synthesis example 1: Synthesis of phthalocyanine dye (A)
[0172] In a 250ml four-necked flask, charge 20g (34 mmol) of 3-phenoxy-4,5-bis(2,5-dichlorophenoxy)-6-fluorophthalonitrile, 2g (13 mmol) of vanadium trichloride and 30 ml of n-octanol were stirred at 170°C while bubbling nitrogen, and kept for about 4 hours. Cool to normal temperature afterwards, add 15g (136 mmol) PhCH 2 NH 2 and 120ml of benzonitrile, and incubated at 90°C for about 5 hours. The reaction solution was cooled, and it was precipitated by the phthalonitrile method, and then vacuum-dried to obtain 180g VOPc (2,5-Cl 2 PhO) 8 (PhO) 4 (PhCH 2 NH) 4 . The maximum absorption wavelength when the phthalocyanine-based dye (A) was dispersed in a polyester-based resin (Bylon 200, manufactured by Toyobo Co., Ltd.) was 878 nm.
Synthetic example 2
[0173] Synthesis Example 2: Synthesis of Phthalocyanine Pigment (B)
[0174] Use 1g (10 millimoles) cupric chloride to replace vanadium trichloride, in addition the synthetic same with compound (A), obtain 180g CuPc (2,5-Cl 2 PhO) 8 (PhO) 4 (PhCH 2 NH) 4 . The maximum absorption wavelength when the phthalocyanine dye (D) was dispersed in a polyester resin (Bylon 200, manufactured by Toyobo Co., Ltd.) was 810 nm.
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