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Gold or silver particles with paramagnetism, and composition containing thereof

A paramagnetic, silver powder technology, used in the field of cosmetics, depilatory, or toothpaste compositions, can solve the problems of limited application fields, poor dispersibility of gold or silver powder, etc.

Inactive Publication Date: 2010-12-29
NPC CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the high cohesion between the particles, the dispersibility of gold or silver powder is also poor, which limits its application field

Method used

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  • Gold or silver particles with paramagnetism, and composition containing thereof
  • Gold or silver particles with paramagnetism, and composition containing thereof
  • Gold or silver particles with paramagnetism, and composition containing thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example 1

[0070] By using an inductively coupled plasma torch, a 13.56MHz 10kW class RF power amplifier (7kW or greater if a single type RF power amplifier; 5kW or greater per amplifier for a dual type), and a helical antenna RF power application components, in 10 -3 38000-45000K (T max =84000K) argon plasma. When the temperature exceeds 30000K (which is a suitable temperature for the actual reaction), and the argon plasma density exceeds 4×10 11 g / cm 3 , the vacuum should be adjusted to about 1 Torr by increasing the input of argon (99.999% pure, which is the reaction gas). The length of the reaction flame (in which the generated plasma is formed) is adjusted to 600-700 mm, and reacted with the silver raw material powder. After the raw material powder is completely changed into the atomic or metal plasma gaseous state, it is cooled by rapid heat exchange in 20-30°C water for 2-5 seconds under vacuum conditions, and a spherical paramagnetic Ag white form with a size of 1-40 μm is ob...

preparation example 2

[0072] The length of the reaction flame (in which the plasma is formed) is adjusted to 300-400 mm. After the metal plasma became gaseous, under the same preparation conditions as in Preparation Example 1, except that the cooling was carried out in liquid nitrogen at -50 to -100° C. for 0.5-1 seconds under vacuum conditions, a compound having a thickness of 50 nm- 3μm-sized spherical paramagnetic gray silver powder (Ag gray type). Such as Figure 5 As shown (which is a TEM photograph of the obtained gray silver powder), no oxide layer exists on the surface of the silver powder.

preparation example 3

[0074] The reaction flame length (in which the plasma is formed) was adjusted to 250-300 mm by manual RF application elements using two trapezoidal antennas in the reaction tube. After the raw material powder becomes metal plasma gaseous state, under the same preparation conditions as in Preparation Example 1, except that the cooling is carried out under vacuum conditions in liquid nitrogen lower than -100° C. for 0.1-0.3 seconds, a mixture with 1 - 50nm size spherical paramagnetic black silver powder (Ag black type). Such as Figure 6 As shown, which is a TEM photograph of the obtained black silver powder, no oxide layer exists on the surface of the silver powder. Also, the powder particles do not show cohesion, but can be well dispersed in distilled water, ethanol, methanol, etc.

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Abstract

The present invention is related to gold or silver powder characterized by having paramagnetism. In more detail, contrary to the conventional gold or silver powder known to be a diamagnetic material having magnetism in the opposite direction to that of the magnetic field in the external magnetic field, the gold or silver powder according to the present invention is characterized by being a paramagnetic gold or silver powder having magnetism in the same direction as that of the external magnetic field, i.e., in the positive direction, in all temperature ranges, which is further characterized by having saturated magnetic moment with the external magnetic field, H, of 2,000 to 8,000 Oe. The paramagnetic gold or silver powder according to the present invention is also characterized by that inclination dM / dH of the mass magnetism curve is positive at an absolute temperature of 20K with the external magnetic field, H, of greater than 1,000 Oe. The paramagnetic gold or silver powder according to the present invention shows an extremely small coercive force, has no surface oxidation layers, is stable at a room temperature, has no cohesive property, and is highly dispersible. Owing to these characteristics, the gold or silver powder according to the present invention may be used for various material areas.

Description

technical field [0001] The present invention relates to gold or silver particles having paramagnetic characteristics, and depilatory, cosmetic, or toothpaste compositions containing such particles. Background technique [0002] Since the beginning in Russia in the 1940s, research on nanopowder has made progress in Western Europe, the United States, and Japan. Since the late 1980s, research on nanopowders has been formally carried out in the fields of metals and ceramics. In nanopowder research, first of all, in order to take advantage of the advantages of particle size miniaturization such as purity, molding, mixing, fineness, etc., many methods for realizing particle miniaturization have been developed, and it has been reported that nanometer-sized particles exhibit many unusual nature. [0003] Effects exhibited according to particle nanometer size include: heat conduction with increasing specific surface area; absorption; adsorption; surface effects such as catalytic pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A61K8/19A61Q9/04A61Q11/00A61Q19/00
CPCH01F1/0036B22F1/00B22F9/14B82Y40/00
Inventor 金永南
Owner NPC CO LTD