Electrophotographic photoreceptor, process cartridge and image-forming apparatus
A technology for electrophotography and imaging equipment, which is applied in the field of process boxes, imaging equipment, and electrophotographic photoreceptors, and can solve problems such as deterioration of electrical characteristics, attenuation of charged potential, and increase in residual potential of photoreceptors.
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Embodiment 1
[0356] A cylindrical aluminum base material of 30 mmΦ was ground with a centerless grinding apparatus so that the ten-point average surface roughness Rz=0.55 μm. The cylindrical aluminum substrate thus treated by centerless grinding was washed in the following order: it was degreased, etched with a 2% by weight aqueous sodium hydroxide solution for 1 minute, neutralized, and washed with pure water. Then, the aluminum substrate was anodized with 10% by weight sulfuric acid solution (current density: 1.0 A / dm 2 ) to form an anodized film on its surface. After washing with water, it was immersed in a 1% by weight nickel acetate solution at 80° C. for 20 minutes to seal the anodized film. Furthermore, it was washed with pure water and dried. This process provides the aluminum substrate with an approximately 6.5 μm thick anodized film formed on its surface.
[0357] Next, 1 part by weight of gallium phthalocyanine chloride having strong diffraction peaks at Bragg angles (2θ±0.2°...
Embodiment 2
[0362] A honed 30 mmΦ cylindrical aluminum substrate was prepared. Next, 100 parts by weight of a zirconium compound (Orgatix ZC540, produced by Matsumoto Chemical Industry Co., Ltd.), 10 parts by weight of a silane compound (Al100, produced by Nippon Unicar Co., Ltd.), 400 parts by weight of isopropyl alcohol and 200 parts by weight Parts of butanol were mixed to prepare a coating liquid for undercoat layer formation. The coating liquid was coated on an aluminum substrate by dipping the substrate in the coating liquid, and heat-dried at 150° C. for 10 minutes to form an undercoat layer with a thickness of about 0.1 μm on the surface of the substrate.
[0363] Next, 1 part by weight of a hydroxyl group having strong diffraction peaks at Bragg angles (2θ±0.2°) of 7.5°, 9.9°, 12.5°, 16.3°, 18.6°, 25.1° and 28.3° in its X-ray diffraction spectrum Gallium phthalocyanine (HPC-1), 1 part by weight of polyvinyl butyral (S-LEC BM-S produced by Sekisui Chemical Co., Ltd.) and 100 part...
Embodiment 3
[0369] With 100 parts by weight of zinc oxide (the test product produced by TAYCA CORPORATION, the specific surface area is 16m 2 / g, the average particle size is 70nm) and 500 parts by weight of toluene were stirred and mixed, and 1.5 parts by weight of a silane coupling agent (KBM603 produced by Shin-Etsu Chemical Co., Ltd.) was added to the solution and stirred for 2 hours. Then, toluene was removed under reduced pressure, and it was baked at 150° C. for 2 hours. 60 parts by weight of surface-treated zinc oxide, 15 parts by weight of blocked isocyanate (Sumitur 3175 produced by SumitomoBayer Urethane) and 15 parts by weight of butyral resin (S-LEC BM-1 produced by Sekisui Chemical Co., Ltd.) ) is dissolved in 85 parts by weight of methyl ethyl ketone. 38 parts by weight of the resulting solution were mixed with 25 parts by weight of methyl ethyl ketone, and dispersed together with 1 mmΦ glass beads therein in a sand mill for 2 hours to prepare a dispersion liquid. To the ...
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