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Switchable adhesive and objects utilizing the same

Inactive Publication Date: 2011-02-17
INTERFACE INT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0019]A carpet material with at least one of its components made easier for recycle by use of an adhesive which can be selectively altered to change the adhesion strength to allow component carpet layers to be separated.

Problems solved by technology

Carpets or carpet tiles are the floor covering of choice in many households and businesses in the world but unfortunately carpet or carpet tiles have a limited lifespan and must eventually be replaced, with the resultant used carpet waste generally being sent to landfill.
These vast quantities of carpet waste have a negative impact on the environment, and the recycling of materials, like nylon and bitumen, comprised in the carpet is currently limited.
The quantity of used carpet or carpet tiles discarded thus amounts to significant economical losses in potentially reusable materials.
Recycling carpet or carpet tiles, however, is difficult because the components that are used to build up carpet or carpet tiles are chemically and physically diverse.
Unfortunately, recycling of the components of carpets or carpet tiles are hindered due to the residual presence of adhesive, for example SBR latex, when the layers have been mechanically separated under great tensile stresses.
In other words, adhesive might still be present both in the yarn of the carpet face layer and in / on the backing layer, thereby providing contaminated materials not suitable for proper reuse.
This method will however not solve the problem of residual presence of the adhesive attached to for example the yarn or the backing.
This method has however the drawback that high amounts of energy have to be spent in a process using vast amounts of chemicals, while in addition the problem of residual presence of the adhesive in / on the yarn / fabric is not solved satisfactory.
Although various modified (latex-based) adhesives for carpet tiles have been described, in general these are not easily separated or removed from carpet fibres.
However, none provide a satisfactory solution to the problem discussed above with respect to efficient recycling of objects such as carpet or carpet tiles, and none provide a satisfactory adhesive that can be suitably used in a carpet or carpet tiles that can be recycled.

Method used

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  • Switchable adhesive and objects utilizing the same
  • Switchable adhesive and objects utilizing the same
  • Switchable adhesive and objects utilizing the same

Examples

Experimental program
Comparison scheme
Effect test

example 1

1.1 Gelatinization

[0135]Cornstarch 75 g (27% w / w amylose, 73% w / w amylopectin) 0.463 mol was added to 1.5 L of distilled water in a 2 L round-bottom flask. The mixture was then gelatinized in an oil bath at 110° C. with continuous stirring for 3 hours. As the person skilled in the art will understand gelatinization conditions will depend on the starch type. High amylose (70% amylose) cornstarch for example will preferably be performed at a higher temperature (˜140° C.).

1.2 Retrogradation

[0136]Gelatinized cornstarch prepared in 1.1 was poured into 4×500 ml powder glass jars. While still hot, lids were attached forming a barrier against microbial activity. Samples were then labelled and placed in a fridge at 5° C. for 3 weeks. As the person skilled in the art will understand, also retrogradation stage depends on the starch type. High amylose (e.g. 70% amylose) cornstarch for example will retrograde sufficiently after only one or two days, as already described above.

1.3 Solvent Exchang...

example 2

2.1 Determination of Surface Area of Starch.

[0143]Nitrogen adsorption / desorption measurements of the starches was undertaken on a Micromeritics ASAP 2010 instrument at 77K with approximately 0.1 g of material. Prior to analysis, all samples were out-gassed for a minimum of 3 hours at 65° C. and corrected for mass differences after the experiment. Surface areas were calculated using the BET equation.

2.2 Determination of Starch Esterification—Titration Method.

[0144]Titration is the methodology that is most accepted in the field. The repeating unit of starch (α-D-glucopyranose) has three hydroxyl groups; therefore the maximum degree of substitution (D.S.) for starch is usually quoted as being three. However, the D.S. could exceed three as end units can have four ester-groups, for example acetyl groups, attached. The titration method employed to determine the DS of the esterified (expanded) starch was based on the procedure employed by Wurzburg (Wurzburg, O., (Ed. Whistler, R.), Methods...

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Abstract

A carpet material with at least one of its components made easier for recycle by use of an adhesive which can be selectively altered to change the adhesion strength to allow component carpet layers to be separated.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application claims priority to United Kingdom No. 0914377.7 filed Aug. 17, 2009, herein incorporated by reference in its entirety.BACKGROUND OF THE INVENTION[0002]The current invention relates to a means whereby an object can be rendered more readily adaptable from a first form suitable for a first use to a second form suitable for a second use, and to an adhesive, in particular, but not necessarily exclusively, a hot aqueous solvent switchable adhesive comprising or essentially consisting of a plasticized esterified expanded starch obtained by at least expanding starch to provide an expanded starch, esterification of the expanded starch to provide an esterified expanded starch, and plasticization of the esterified expanded starch to provide a plasticized esterified expanded starch. In particular, the current invention relates to a method of using such hot aqueous solvent switchable adhesive as the agent for allowing the adaptability...

Claims

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Application Information

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IPC IPC(8): D04H11/00C09J103/06B32B37/12B32B43/00
CPCC08B31/04C09J103/06D06N2213/068D06N7/0071D06N2209/067C08K5/0016Y10T428/23979B32B37/12B32B37/1284B32B37/18B32B38/00B32B38/10B32B2471/02C09J5/00C09J11/06C09J2403/00
Inventor MANTLE, JOHN ROBERTCLARK, JAMES HANLEYSHUTTLEWORTH, PETER SAMUEL
Owner INTERFACE INT