Compositions for inhibiting checkpoint gene expression and uses thereof
a technology of expression inhibition and compound, which is applied in the direction of dna/rna fragmentation, biochemistry apparatus and processes, organic active ingredients, etc., can solve the problems that many previous cancer immunotherapies have likely been limited by these suppressive mechanisms, and achieve enhanced antitumor immunotherapy applications, suppress the immune response, and effectively inhibit or decrease pd1.
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Preparation of Oligonucleotide-Based Compounds
[0180]The oligonucleotide-based compounds of the invention were chemically synthesized using phosphoramidite chemistry on automated DNA / RNA synthesizer. TAC protected (Except U) 2′-O-TBDMS RNA monomers, A, G, C and U, were purchased from Sigma-Aldrich. 7-deaza-G, inosine and loxoribine monomers were purchased from ChemGenes Corporation. 0.25M 5-ethylthio-1H-tetrazole, PAC-anhydride Cap A and Cap B were purchased from Glen Research. 3% trichloroacetic acid (TCA) in dichloromethane (DCM) and 5% 3H-1,2-Benzodithiole-3-one-1,1-dioxide (Beaucage reagent) were made in house.
[0181]Oligonucleotide-based compounds of the invention were synthesized at 1-2 μM scale using a standard RNA synthesis protocol.
Cleavage and Base Deprotection
[0182]Oligonucleotide-based compounds of the invention were cleaved from solid support and the solution was further heated at 65° C. to removing protecting groups of exo cyclic-amines. The resulting solution was dried ...
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