High solid content stable-stored nanometer zinc oxide concentrated slurry and its preparation process

A nano-zinc oxide and preparation process technology, applied in the field of nano-materials, can solve the problems of low content of nano-zinc oxide, complex preparation methods, narrow application range, etc., and achieve the effect of simple ingredients, simple process, and wide applicability

Active Publication Date: 2007-11-14
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
View PDF6 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent 02121246.5 reports multifunctional nano-zinc oxide suspoemulsion and its preparation method. In this method, nano-zinc oxide is modified. The preparation method is relatively complicated, and the content of nano-zinc oxide is also low.
Chinese patent 02159055.9 refers to surface-modified nano-zinc oxide dispersions and their preparation methods and uses, which are SiO 2 、Al 2 o 3 , Fe 2 o 3 It is deposited on the surface of nano-zinc oxide, and then mixed with silane coupling agent, water-soluble polymer and water. This dispersion is specially used to prepare UV-resistant textiles, and its application range is narrow
In addition, the nano zinc oxide developed by US Patent 5,914,101 has a solid content of 40-75%, but the zinc oxide has to undergo a complicated modification process before being dispersed, and the process is relatively cumbersome

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024]Prepare 300g of water-based nano-zinc oxide concentrated slurry. Weigh 68g of water in a 500ml beaker, add 21g of dispersant Dispers735 W and 0.5g of defoamer Foamex K3, disperse for 5 minutes at 1000rpm in the high-speed disperser, and then add 40nm nano zinc oxide without stopping the high-speed disperser 210g, disperse with a high-speed disperser at 2000rpm for 15 minutes, and finally add the other half of the defoamer 0.5g, and disperse at a slow speed of 500rpm for 2 minutes, and the resulting nano-zinc oxide slurry is ground with a ball mill for 3 hours to make the average particle size less than 100 nanometers , making the concentrated slurry of nano-zinc oxide with a weight ratio of 70% of nano-zinc oxide. Wherein the dispersant accounts for 7.0% of the total amount of the slurry, and the defoamer accounts for 0.33% of the total amount of the slurry.

Embodiment 2

[0026] Adjust the amount of dispersant Dispers735W added. Wherein water is 73.5g, nano-zinc oxide powder is 210g, dispersant Dispers735 W is 15.0g, defoamer Foamex 8030 is 1.5g, the preparation method of nano-zinc oxide concentrated slurry is the same as that of Example 1. The concentrated slurry of nano-zinc oxide with a weight ratio of 70% is made. Wherein the dispersant accounts for 5.0% of the total amount of the slurry, and the defoamer accounts for 0.5% of the total amount of the slurry.

Embodiment 3

[0028] Adjust the amount of dispersant Dispers735 W added. Wherein water is 45.5g, nano-zinc oxide powder 210g, dispersant Dispers735W is 36g, defoamer Foamex K5 is 4.5g, the preparation method of nano-zinc oxide concentrated slurry is the same as embodiment 1. The concentrated slurry of nano-zinc oxide with a weight ratio of 70% is made. Wherein the dispersant accounts for 12% of the total amount of the slurry, and the defoamer accounts for 1.5% of the total amount of the slurry.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
viscosityaaaaaaaaaa
Login to view more

Abstract

The invention belongs to the area of nano material, refers to the concentrated plasma of nano zinc oxide that contains much solid and can be stored stably and its preparing process. The concentrated plasma contains 40-80% of nano zinc oxide the average size of which is less than 50nm, 1-15% of dispersing agent, 0.1-2% of defoaming agent, residual water, that is produced after the processes of homogeneous mixture, dispersion, abrasion and etc. The dispersing agent that is used is commercial dispersing agent suitable for water system, not containing some poison materials such as benzene, formaldehyde and etc, and passing American FDA certification, so that is innocuous for not only human and also environment absolutely. The inventive concentrated plasma of nano zinc oxide contains more solid, and has low viscosity, excellent dispersibility and stability, can hardly pollute environment, processes simply and has extensive applicability, so that can be used in many areas, such as ceramics, coating mixture, rubber, daily cosmetic product, magnetic material and electronic material.

Description

technical field [0001] The invention belongs to the field of nanomaterials, and specifically relates to a high-solid-content storage-stable nano-zinc oxide concentrated slurry and its preparation process. The nano-zinc oxide and a certain amount of dispersant, Foaming agent and water are mixed to obtain water-based nano-zinc oxide concentrate slurry with excellent performance in all aspects. Background technique [0002] Nano zinc oxide is a functional material with a wide range of uses. It has optical, magnetic, thermal and sensitive properties that conventional bulk materials do not have. The product has high activity and has anti-infrared, ultraviolet and anti-virus and sterilization functions. It is mainly used in the following Field: (1) Rubber industry: The rubber industry is the largest user of zinc oxide. Nano-zinc oxide is used to manufacture high-speed and wear-resistant rubber products, such as aircraft tires and radial tires for high-end cars. Long service life ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C09C1/04C09C3/10C09C3/12C09C3/04
Inventor 宋影伟刘福春韩恩厚
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products