Atomic grade p-n node monocrystal rectifier and its application
An atomic-level, rectifier technology, applied in transistors, semiconductor devices, diodes, etc., can solve problems such as low thermal stability and difficult application of nanometer operations
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Embodiment 1
[0025] Example 1 La 0.66 Ca 0.29 K 0.05 MnO 3 Single crystal preparation and characterization
[0026] 0.4M La(NO 3 ) 3 solution, 0.4M Ca(NO 3 ) 2 Solution, 0.12M KMnO 4 Solution, 0.56MMnCl 2 The solutions were mixed and KOH was added to form a reaction mixture. Stir the reaction mixture evenly and put it into a reaction kettle with a filling degree of 75%. After tightening it, put it in an oven at 260°C for crystallization for 3 days to obtain the composition La 0.66 Ca 0.29 K 0.05 MnO 3 single crystal. La 0.66 Ca 0.29 K 0.05 MnO 3 The average valence state of manganese is measured by iodometric method, and the experimental average valence state is 3.36, which is close to the theoretical value of 3.39. Using different amounts of KOH, a series of compounds La with K content varying from 0.01 to 0.14 can be obtained 1-x-y Ca x K y MnO 3 .
[0027] Given below is La 0.66 Ca 0.29 K 0.05 MnO 3 X-ray single crystal structure data.
[0028] Molecular for...
Embodiment 2 3
[0030] Example 2 Triple Valence Manganese Oxide Single Crystal Sample Work Function and I-V Curve Characteristics
[0031] The work function was measured with a Kelvin probe (produced in the UK, KP Technology Ltd) at room temperature and atmospheric conditions. The Kelvin probe is a vibrating capacitive device used to measure the work function between the sample and the vibrating needle (the work function of gold in the experiment is 5.1 eV). The sample powder was sprinkled horizontally on a clean aluminum sheet. In the test of current image tunneling spectrometer, 5×10 -5 Under the pressure of pa, 99.99% of the gold is thermally evaporated onto the treated silicon wafer to obtain a gold film. The single crystal sample was sprinkled on the gold film of the AFM stand (the schematic diagram is shown in Figure 5). The contact force between the gold probe and the gold film is kept at 2Nm -1 . The bias voltage used to measure the voltammetry curve between the gold film and the...
Embodiment 3
[0033] Example 3 Atomic level p-n junction single crystal diode
[0034] The single crystal rectifier as a stand-alone device has the application mode and accuracy in detector tube, rectifier tube, switching diode, low voltage diode and varactor diode, and its performance in fast photoelectric conversion. Atomic-scale three-dimensional p-n junction effects in quantum computer chips.
[0035] single crystal diode. Connect electrodes on both sides of the single crystal sample to obtain an atomic-level p-n junction single crystal diode, as shown in Figure 7. In FIG. 7, n and p represent the n-terminal and p-terminal shown in FIG. 3, respectively. m represents the number of knots.
[0036] Single Crystal Thin Film Diodes. The single crystal film refers to the SrTiO 3 , SiO 2 , Ta 2 o 5 As the substrate, a triple valence state manganese oxide single crystal film was prepared on such a substrate by applying a hydrothermal synthesis method, and the preparation method was the ...
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