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Catalyst capable of reducing nitric oxides and eliminating soot particle simultaneously and application thereof

A technology of soot particles and nitrogen oxides, applied in the direction of metal/metal oxide/metal hydroxide catalyst, physical/chemical process catalyst, chemical/physical process, etc., can solve the corrosion reaction pipeline, incomplete secondary, Easy to leak reaction and other problems, to achieve good anti-poisoning performance, good anti-sulfur dioxide, good application effect

Inactive Publication Date: 2008-06-04
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The elimination of nitrogen oxides is mainly carried out by the catalytic reduction method, mainly using ammonia as the reducing agent; ammonia selective catalytic reduction of nitrogen oxides in an oxidizing atmosphere is now recognized as the most effective method for eliminating nitrogen oxides from industrial waste gas, in Japan And some industrialized countries have already industrialized; but the ammonia needs to be metered and controlled in the process, which is easy to leak or react incompletely, causing secondary pollution; during the reaction, the sulfur-containing substances are oxidized and finally generate NH 4 HSO 4 , (NH 4 ) 2 S 2 o 7 , block and corrode the reaction pipeline, and deactivate the catalyst

Method used

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  • Catalyst capable of reducing nitric oxides and eliminating soot particle simultaneously and application thereof
  • Catalyst capable of reducing nitric oxides and eliminating soot particle simultaneously and application thereof
  • Catalyst capable of reducing nitric oxides and eliminating soot particle simultaneously and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Example 1Cu / C-CeO 2 Catalyst preparation

[0022] Here, Cu / C-CeO with a copper content of 5% (weight percentage) and a weight ratio of activated carbon to cerium oxide of 1:10 2 The preparation process of the catalyst used in the present invention is generally described by way of example. Activated carbon is commercially available coconut shell activated carbon, CeO 2 It is obtained by decomposition of cerium nitrate.

[0023] (1) The activated carbon used was washed with concentrated nitric acid at 70°C for 1 hour, then washed with water until neutral, and finally dried at 110°C for 12 hours for later use;

[0024] (2) The catalyst carrier CeO 2 3.000 gram and above-mentioned 0.3000 gram of activated carbon mechanically stirred and mixed 10 minutes, catalyst active component Cu was impregnated on the carrier with equal volume impregnation method, and the impregnation time was 5 hours, and the precursor of Cu was the nitrate of Cu, then Heat and stir in a water ba...

Embodiment 2

[0026] Example 2Cu / C-CeO 2 Catalyst preparation

[0027] The difference from Example 1 is that

[0028] (2) The catalyst carrier CeO 23.000 gram and above-mentioned 0.3000 gram of activated carbon that have been treated were mechanically stirred and mixed for 10 minutes, and the catalyst active component Cu was impregnated on the carrier with an equal volume impregnation method, and the impregnation time was 3 hours, and the precursor of Cu was the nitrate of Cu, and then Heat and stir in a water bath at 80°C for 3 hours, then dry at 100°C for 10 hours;

[0029] (3) Finally, calcining in a nitrogen atmosphere at 450° C. for 1 hour, and finally pressing the catalyst into tablets and pulverizing it, and then sieving to obtain 60-80 mesh particles for future use.

Embodiment 3

[0030] Embodiment 3Cu / C-CeO 2 Catalyst preparation

[0031] The difference from Example 1 is that

[0032] (2) The catalyst carrier CeO 2 3.000 gram and above-mentioned 0.3000 gram of activated carbon that have been treated were mechanically stirred and mixed for 10 minutes, and the catalyst active component Cu was impregnated on the carrier with an equal volume impregnation method, and the impregnation time was 6 hours, and the precursor of Cu was the nitrate of Cu, and then Heat and stir in a water bath at 75°C for 1 hour, then dry at 105°C for 9 hours;

[0033] (3) Finally, roast at 550° C. in a nitrogen atmosphere for 2 hours, and finally press the catalyst into tablets and pulverize it, and then sieve it to obtain granules of 60 to 80 meshes for use.

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PUM

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Abstract

The invention discloses an accelerant and application of removing air contaminant NOx and carbon-smoke granule, which is characterized by the following: the accelerant uses copper for active component; the copper spreader carrier is on activated carbon or the compound of carbon-smoke granule and cerium oxide; the mass ratio of activated carbon or carbon-smoke granule and cerium oxide is 0.1-1; the weight percentage content of compound spreader carrier copper is 5-10. The invention adopts Cu / C-CeO2 accelerant to removing nitrogen oxide and carbon-smoke granule, which can come into effect of removing the two contaminants.

Description

technical field [0001] The invention relates to the removal of air pollutants NOx and soot particles, in particular to a catalyst for simultaneously reducing nitrogen oxides and eliminating soot particles and its application. Background technique [0002] Environmental pollution has always been a major problem in modern society. From the "London smog" and "photochemical smog" pollution at the beginning of the 20th century, to the acid rain that still exists today, the greenhouse effect and the ozone layer hole effect, every adoption of new technology, invention of new materials and use of new energy will bring New environmental pollution problems. With the use of fossil fuels such as oil and coal, as well as the use of engines fueled by gasoline and diesel, the problem of environmental pollution has never been as serious as it is today. [0003] Engines fueled by gasoline and diesel will release a variety of harmful components during operation, mainly carbon monoxide (CO),...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/60B01D53/86B01J23/70B01J23/83
CPCY02A50/20
Inventor 刘志张涛王晓东徐长海孙军
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI