Preparation metod of modified ultroviolet light solidified wooden articles paint by in-situ method

A technology for curing coatings and ultraviolet light, which is applied in the direction of polyester coatings, epoxy resin coatings, polyurea/polyurethane coatings, etc., can solve the problems of easy aggregation of nano-materials, influence on ultraviolet light absorption, complex process conditions, etc., and achieve simple process Ease of operation, avoiding the difficulty of dispersion, and the effect of scientific technical route

Active Publication Date: 2007-10-03
溧阳常大技术转移中心有限公司
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Problems solved by technology

[0004] However, as inorganic powder nanomaterials, although the surface has been modified to a certain extent, its surface still contains a large number of hydrophilic groups, has a large specific surface energy and surface activity, and is very difficult to add to organic coating systems. Mutual self-aggregation easily occurs to form aggregates and agglomerates, which affects the performance of the coating to a certain extent. CN200510050745.X reports using the sol-gel method to add hydrochloric acid and absolute ethanol to the UV-curable coating. Stir well to make the system uniform, then add organosilicon monomer to hydrolyze the organosilicon monomer under acidic conditions to obtain high hardness

Method used

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  • Preparation metod of modified ultroviolet light solidified wooden articles paint by in-situ method
  • Preparation metod of modified ultroviolet light solidified wooden articles paint by in-situ method
  • Preparation metod of modified ultroviolet light solidified wooden articles paint by in-situ method

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Embodiment 16

[0021] The coating described in embodiment 16, after adopting modes such as roller coating, spray coating, flow coating etc. to be applied on wood surface, gained coating film performance is better, and accompanying drawing 2 is the SEM figure of coating film, can find out from the figure: nanoparticle The distribution of UV coating is relatively uniform, and the particle size is also relatively uniform, generally distributed in the range of 60-80nm. In the figure, nano-SiO 2 There are obvious organic layer intervals between the sol particles, indicating that the in-situ modified UV coating has effectively solved the problem of nanoparticle agglomeration.

[0022] The different embodiments of table 1 and each component content of comparative example, relevant performance parameter

[0023]

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Abstract

This invention relates to preparation method of in situ modified ultraviolet light curing carpentry dope. It selects one or more kinds of acrylate resin kind reactive diluents that has lower viscosity as in situ reactive basal body, adopts silicic acid ester as precursor, takes silane coupling agent with amino amino as catalyzer and surface conditioning agent, one-step complete preparation and surface treatment of nanometer materials, gain ultraviolet light curing dope. This film coating is transparence, rigidity reach 6H, adhesion reach 98%, wearability 1.7 mg . nanometer particle distribute uniformity in dope, particle size is between 60 to 80 nm, efficiently solve problem of nanometer particle agglomeration, advance wearability and rigidity and so on performance of film coating.

Description

technical field [0001] The invention relates to a preparation method of a nano-modified ultraviolet coating, in particular to a preparation method of an ultraviolet-cured wood coating modified by an in-situ method. technical background [0002] In recent years, UV-curable coatings have achieved rapid development at home and abroad. UV-curable coatings are favored by the market due to their advantages of no pollution, high efficiency, and energy saving. UV-curable coatings are widely used in many fields such as wood, ink, adhesives, printing plates, electronics industry, etc. At present, domestic UV-curable coatings are widely used in wood, but the existing technology cannot fully meet the needs of the market, such as coating The wear resistance and hardness of the film cannot meet the market's requirements for coatings for substrates such as floors. Scientists and technicians are constantly exploring the modification of UV-curable coatings. [0003] For the modification of...

Claims

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Application Information

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IPC IPC(8): C09D4/02C09D163/10C09D175/14C09D167/06B05D7/06
Inventor 陈海群何光裕孙小强黄勇巫峡曹云峰殳黎
Owner 溧阳常大技术转移中心有限公司
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