Method for preparing plumbum containing radiation protection organic glass
A plexiglass and anti-radiation technology, applied in shielding, nuclear engineering, reactors, etc., can solve the problems of limited application fields, opacity, and fragile preparation process of inorganic lead glass, and achieve the effect of simple process and superior performance
Inactive Publication Date: 2010-12-01
JIANGNAN UNIV
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Problems solved by technology
For many years, relevant industrial departments, medical and scientific research institutions have used lead plates and inorganic lead glass as radiation protection materials, but the lead plates are bulky and opaque, and their application in many fields is limited; while the inorganic lead glass is fragile and the preparation process is complicated. It is expensive and it is difficult to make large-area industrial application materials, so its application fields are also limited
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Abstract
The invention relates to a method for preparing lead-bearing radiation-proof organic glass, belonging to the functional high molecular material polymerization technical field. The method synthesizes organic carboxylic acid lead salt through organic synthesis and modification of inorganic lead salt, adds the organic carboxylic acid lead salt into water-in-oil type microemulsion which consists of methyl methacrylate (MMA), a surfactant, an auxiliary surfactant, water and so on, initiates under the condition of a thermal initiator and polymerizes an organic glass sheet. Moreover, the performanceof the organic glass sheet is tested, and the result reveals that the impact strength, the tensile strength, the light transmittance, the refractive index, the glass transition temperature and the radiation-proof property of the organic glass prepared by polymerization of the microemulsion are all superior to those of common organic glass. The invention provides a novel method for synthesizing functional high molecular materials. The method has a simple and convenient technique; the synthesized sheet has superior performance, can make up for the defects of an inorganic radiation-proof glass sheet, and is hopeful to become practical novel radiation-proof materials.
Description
A kind of preparation method of lead-containing anti-radiation organic glass technical field The invention discloses a preparation method of lead-containing anti-radiation organic glass, which belongs to the technical field of polymerization of functional polymer materials. The invention relates to a new method for preparing organic lead salt and synthesizing functional polymer materials. The invention relates to the preparation of a metal salt-containing anti-radiation organic glass by means of microemulsion polymerization. Background technique With the rapid development of industrial and agricultural production, national defense scientific research, radiation medicine and atomic energy industry, the use of various rays is becoming more and more extensive. When people are using radiation, they are also exposed to the hazards of radiation. Radiation can be protected. The basic principle of radiation protection is to minimize or avoid the exposure of rays entering the h...
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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/06C08K5/098C08F220/14G21F1/10C08F2/44C08F2/24
Inventor 蒋平平陈建波林学敏
Owner JIANGNAN UNIV
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