Multicomponent composite flocculating setting agent and use in arsenic contamination water treatment

A multi-component composite, sedimentation agent technology, applied in the fields of flocculation/sedimentation water/sewage treatment, water/sewage treatment, water/sludge/sewage treatment, etc. problem, to achieve the effect of good arsenic removal

Active Publication Date: 2009-08-12
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, for rivers polluted by arsenic, the length of the river is often in the range of tens to hundreds of kilometers, which is too wide to add arsenic-removing sedimentation agent; The settling time allowed for arsenic pollution treatment is often relatively short, often requiring several hours to tens of hours to complete the settling of arsenic
Therefore, if a multi-element compound metal oxide sedimentation agent for arsenic removal (CN200810266740: 1) is used, the sedimentation agent that has absorbed arsenic in the above-mentioned short time range is difficult to fully settle and the effect of removing arsenic is limited, and if the sedimentation agent with larger particles is formed, the sedimentation is accelerated rate is difficult to ensure the effect of adsorption and removal of arsenic
Therefore, it is difficult to effectively solve the problem of arsenic-polluted water body treatment projects in rivers by using the above-mentioned multi-component composite metal oxide arsenic-removing sedimentation agent for still water bodies such as lakes and reservoirs and its engineering technical solutions

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0075] Preparation of multi-component composite flocculation-sedimentation agent: Add ferric chloride, aluminum trichloride, and potassium permanganate into a dissolving tank filled with water and stir to dissolve fully, so that the concentrations of aluminum salts and iron salts in the water are both 2g / L, the concentration of potassium permanganate is 0.02g / L.

[0076] The multi-component composite metal oxide arsenic-removing sedimentation agent is a mixed aqueous solution composed of an aqueous solution of ferric chloride, an aqueous solution of aluminum trichloride, and an aqueous solution of ferrous sulfate (ferric chloride, aluminum trichloride, and ferrous sulfate are mixed The concentration in the aqueous solution is 2g / L) and the potassium permanganate aqueous solution (the concentration of potassium permanganate is 1g / L) is mixed and stirred for 10 minutes to prepare; the composite group of multi-component composite metal oxide arsenic-removing sedimentation agent ...

Embodiment 2

[0079] Preparation of multi-component composite flocculation-sedimentation agent: Add aluminum trichloride, ferric nitrate and alum to a dissolving tank filled with water and fully stir and dissolve, so that the concentration of aluminum salt in the water is 20g / L, and the concentration of iron salt is 0.2g / L , the concentration of potassium permanganate is 0.05g / L.

[0080] Applied to the purification of arsenic-polluted reservoirs: the concentration of arsenic in arsenic-polluted water is 0.10mg / L. The multi-component composite flocculation-settling agent is evenly sprayed and settled on the water surface, and the total concentration of ferric chloride and aluminum trichloride in the multi-component composite flocculation-settling agent formed in the treated water is 2mg / L, and the concentration of ferric chloride and trichloride is 2mg / L. The molar ratio of aluminum chloride is 0.82%:1; potassium permanganate is 2.5% of the total weight of ferric chloride and aluminum trich...

Embodiment 3

[0082] Preparation of multi-component composite flocculation and sedimentation agent: Add aluminum trichloride, alum, polyaluminum sulfate, polyaluminum chloride, aluminum sulfate, aluminum nitrate, polyferric sulfate, polyaluminum ferric sulfate, potassium permanganate, and polyacrylamide into the Fully stir and dissolve in a dissolving tank filled with water, so that the concentration of aluminum salt in the water is 3000g / L, the concentration of iron salt is 1000g / L, the concentration of potassium permanganate is 10g / L, and the concentration of polyacrylamide is 0.2g / L.

[0083] The multi-component composite metal oxide arsenic-removing sedimentation agent is a mixed aqueous solution composed of an aqueous solution of aluminum trichloride and an aqueous solution of ferrous sulfate (the concentrations of aluminum trichloride and ferrous sulfate in the mixed aqueous solution are both 2g / L) and composed of The mixed aqueous solution (the concentration of ferric chloride in the ...

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Abstract

The invention belongs to the technical field of river water body pollution control and in particular relates to a multiple-element compound flocculating settling agent and the application of the multiple-element compounded flocculating settling agent in arsenic pollution water body treatment. The multiple-element compounded flocculating settling agent is prepared by compounding malysite, aluminium salt, hypermanganate, polyacrylamide and aqueous solution. The multiple-element compounded flocculating settling agent can be applied in the arsenic pollution water body treatment to remove arsenic in the arsenic pollutant water body. The concentration of the arsenic in the treated water can meet or is superior to the specified requirement of three types of water on the arsenic concentration in the national earth surface water environment quality standard (less than 0.05 mg/L). The invention also can be used for removing heavy metals such as copper, chromium, cadmium, lead and the like in water by sedimentation. The multiple-element compounded flocculating settling agent can be used together with a multiple-element compounded metal oxide arsenic removal setting agent in static or flowing arsenic pollution water body treatment for removing the arsenic in the water body polluted by arsenic.

Description

technical field [0001] The invention belongs to the technical field of river water pollution treatment, and in particular relates to a multi-component composite flocculation-sedimentation agent and the application of the multi-component composite flocculation-settling agent in the treatment of arsenic-polluted water bodies. Background technique [0002] The arsenic-containing wastewater produced in industrial production processes such as chemical industry, metallurgy, iron and steel, energy and minerals is an important source of water pollution. The safety of drinking water sources and water quality along the coast poses a major hidden danger to drinking water. Especially for arsenic pollution incidents caused by the discharge of some high-load arsenic-containing wastewater in a short period of time, it is more likely to have a serious impact on downstream people's lives, fishery production, and social stability due to its high pollution load and high pollution intensity. ....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/52C02F1/58
Inventor 曲久辉刘锐平王洪杰刘会娟兰华春
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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