Heat-peelable pressure-sensitive adhesive sheet and method of recovering adherend
A technology of thermal peeling and adhesive sheet, which is applied in the direction of adhesive heating bonding method, polymer adhesive additive, film/sheet adhesive, etc., and can solve the problem of contact between the adhesive layer and the adherend Problems such as insufficient area reduction, inability to peel, and time-consuming peeling
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Embodiment 1
[0052] Be coated with 100 parts by weight of acrylic acid polymer A (acrylic acid polymer A) on the polyimide film base material (trade name " Capton H100 " of Du Pont chemical manufacture (du Pont Chemical, Du Pont-Toray), Tg300 ℃ or more) that thickness is 25 μ m. 2-ethylhexyl ester / ethyl acrylate / acrylic acid-2-hydroxyethyl ester (weight ratio: 50 / 50 / 4) copolymer), 3 parts by weight of isocyanate cross-linking agent (trade name " coronet-toL (colonateL )", a toluene solution of Nippon Polyurethane Industry Co., Ltd.) and dried to form an intermediate layer with a thickness of 25 μm.
[0053] In addition, a polyester film containing 100 parts by weight of the above-mentioned acrylic polymer A and 40 parts by weight of heat-expandable microspheres A (trade name "MazumotoMicrosoft F-301D (Matsumoto microspheres F- 301D)", Matsumoto Yushi-Seiyaku Co., Ltd. (Matsumoto Yushi-Seiyaku Co., Ltd.); expansion start temperature 90 ° C, median particle size (median size) 11.5 μm, maximu...
Embodiment 2
[0055] Except for using a polyethylene terephthalate base material (Tg68° C.) with a thickness of 38 μm instead of a polyamide base material with a thickness of 25 μm, the same operation was carried out as in Example 1 to obtain a total thickness of 93 μm. Heat-peelable adhesive sheet B.
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