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Method for weight-increasing and antimicrobial treatment of silk fiber

A technology of real silk and fibers, applied in the field of weight-enhancing modification and finishing of real silk fibers, can solve the problems of environmental pollution, waste of sericin resources, poor antibacterial properties of silk fibers, etc. Effect

Active Publication Date: 2011-11-23
嵊州市好运来印染有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] If the degumming wastewater produced by refining silk fibers to remove sericin is directly discharged, it will not only cause great pollution to the environment, but also waste the sericin resources in it. Generally, a relatively high concentration of chemical reagents is required to achieve a better effect, and high concentrations of chemical reagents increase the difficulty of subsequent sewage treatment. Therefore, there are great shortcomings in the method of using chemical reagents to fix sericin. Currently, silk fibers are still mainly used for weight gain. The first type of processing method, but in terms of both achieving the purpose of silk weight gain and recycling degumming wastewater, there is no effective solution at present, and the currently commonly used silk weight gain methods are only dedicated to weight gain research, so that after weight gain The antibacterial properties of silk fibers are generally poor, which limits the use of silk fabrics

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Method for weight-increasing and antimicrobial treatment of silk fiber

Examples

Experimental program
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Effect test

Embodiment 1

[0013] See attached figure 1 shown. A method for weight gain and antibacterial treatment of real silk fibers, comprising the following steps: preparing raw silk cheese yarn material—degumming treatment with silk refining agent—washing treatment—weight gain treatment—soaping—dyeing—fixing color Or soaping - antibacterial treatment - finishing, drying - weight gain (modified) products.

[0014] In the step of preparing the raw silk package material, silk fiber is used as an example, and 100Kg of pure silk fiber is weighed as the material to be processed.

[0015] In the degumming treatment step, the silk refining agent is used to remove the sericin protein according to the conventional process, and then one wash with hot water at 100°C, one wash with warm water at 70°C, and one wash with cold water at room temperature.

[0016] In the weight-increasing treatment step, the grafting liquid is prepared first: the grafting monomer adopts a derivative of methacrylate, such as methy...

Embodiment 2

[0025] See attached figure 1 shown. A method for weight gain and antibacterial treatment of real silk fibers, the steps of which are the same as in Example 1.

[0026] The steps of preparing raw silk cheese yarn material and degumming are the same as in Example 1.

[0027] In the weight-increasing treatment step, the grafting liquid is prepared first: the grafting monomer adopts a derivative of methacrylate, such as methyl methacrylate, ethyl methacrylate, propyl methacrylate or methacrylic acid One or more mixtures of butyl esters, the addition amount is 66% of the fabric weight; ammonium persulfate is used as the initiator; the nonionic surfactant is flat plus O, and the addition amount is 0.8g / l; dispersion Agent WA, the addition amount is 1g / l; Soft water is used as the solvent, and the bath ratio is 1:15; The pH value of the grafting liquid is adjusted to 3-4 with a mixture of formic acid and acetic acid. The weight-increasing treatment step is carried out in a closed ...

Embodiment 3

[0032] See attached figure 1 shown. A method for weight gain and antibacterial modification of real silk fibers, the steps of which are the same as in Example 1.

[0033] The steps of preparing raw silk cheese yarn material and degumming are the same as in Example 1.

[0034] In the weight-increasing treatment step, the grafting liquid is prepared first: the grafting monomer adopts a derivative of methacrylate, such as methyl methacrylate, ethyl methacrylate, propyl methacrylate or methacrylic acid One or more mixtures of butyl esters, the addition of which is 66% of the fabric weight; and adding degumming wastewater accounting for 10%, 20%, and 30% of the fabric weight respectively; using ammonium persulfate as the initiator; The non-ionic surfactant is Pingping plus O, and the addition amount is 0.8g / l; the dispersant WA, the addition amount is 1g / l; the solvent is soft water, and the bath ratio is 1:15; the grafting is adjusted with a mixture of formic acid and acetic aci...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a method for weight-increasing and antimicrobial treatment of silk fiber, comprising: the preparing of silk fiber, degumming, washing, weight increasing treatment, soaping, dyeing, antibacterial treatment and after-finishing, wherein the weight-increasing treatment is performed at high temperature and pressure, the high temperature is 85 to 90 DEG C, in the weight increasing treatment, a grafting solution is firstly prepared and contains methacrylate ester derivatives as grafting monomer, a initiator, a non-ion or anionic surfactant and degumming waste water. In the invention, the drained degumming waste water can be recycled, thus saving the resource, reducing the pollution, improving the efficiency, and according with the requirement of circular, economical and clean production. In the invention, the weight increasing treatment for the silk fiber is performed, at the same time, the antimicrobial treatment is also completed, thus the treated silk fiber has theideal weight-increasing effect and a certain of antimicrobial performance.

Description

technical field [0001] The invention relates to weight gain modification and finishing of real silk fibers, in particular to a method for weight gain and antibacterial treatment of real silk fibers. Background technique [0002] The raw material of real silk is silk. Silk fiber is mainly composed of two proteins, silk fibroin and sericin. The dyeing process of real silk fiber adopts the processing method of removing sericin first, but after the sericin on the surface of the silk fiber is removed through refining, The weight of silk fiber is reduced and the fiber becomes thinner, so that the silk fabric has defects such as poor abrasion resistance, poor wrinkle recovery, and poor washability. Durability, wrinkle resistance, firmness and body. [0003] At present, the processing methods of weight-increasing silk fibers mainly include the following two types: one is to carry out chemical grafting on silk fibers, so as to increase the weight of fibers and improve the wearabilit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M14/06D06M11/46D06M101/10
Inventor 胡士良李振国
Owner 嵊州市好运来印染有限公司
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