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Aqueous solution and method of prolonging life of residual chlorine in aqueous solution

An aqueous solution and perchloric acid technology, applied in the field of aqueous solution, can solve the problem of shortening the life of hypochlorous acid

Active Publication Date: 2014-07-23
イーデオ +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, the life of hypochlorous acid is gradually shortened

Method used

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  • Aqueous solution and method of prolonging life of residual chlorine in aqueous solution
  • Aqueous solution and method of prolonging life of residual chlorine in aqueous solution
  • Aqueous solution and method of prolonging life of residual chlorine in aqueous solution

Examples

Experimental program
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Effect test

Embodiment 1

[0103] make KClO 3 Dissolved in pure water.

[0104] in the KClO 3 Citric acid was added to the aqueous solution. Thus, the pH was adjusted to about 4.

[0105] Determine the KClO of this pH4 3 The residual chlorine concentration of the aqueous solution.

[0106] In addition, KClO at pH 4 above 3 Add H to the aqueous solution 2 O 2 The aqueous solution was used to measure the residual chlorine concentration.

[0107] The results of this measurement (measured by the KI method) are shown in Table-1 below.

[0108] [Table 1]

[0109] Table 1

[0110] Elapsed time Concentration (ppm)

[0111] Potassium Chlorate 125 125 125 125 125 125

[0112] Hydrogen Perchloride 0 30 60 120 240 480

[0113] Residual chlorine 0 days 0 5 25 30 30 125

[0114] 7 days 0 200 250 300 300 350

[0115] 14 days 0 200 250 300 300 350

[0116] 30 days 0 200 250 300 300 350

[0117] It can be seen from this Table-1 that by containing H 2 O 2 , even ...

Embodiment 2

[0120] make KClO 3 Dissolved in pure water.

[0121] in the KClO 3 Citric acid was added to the aqueous solution. Thus, the pH was adjusted to about 4.

[0122] in the KClO 3 NaClO was further added to the aqueous solution.

[0123] Then, the residual chlorine concentration was measured. The results were not significantly different from the case of the NaClO aqueous solution.

[0124] Then, use figure 1 The anodic electrolyzed water produced in the illustrated two-chamber type electrolytic cell replaces the above-mentioned pure water. The two-chamber electrolytic cell is as follows: a platinum electrode made of an 80-mesh mesh (the size of the electrode is 80mm × 60mm) is used as the anode electrode, a titanium electrode (the size of the electrode is 80mm × 60mm) is used as the cathode electrode, and a fluorine-based cation exchange membrane is used as the A membrane separating the anodic and cathodic compartments. Then, pure water is supplied to the cathode chamber a...

Embodiment 3

[0129] Dissolve 40ppm NaClO and 100ppm KClO in the anode electrolyzed water of Example 2 2 . Further addition of citric acid adjusted the pH to about 6.

[0130] Determination of the content of NaClO and KCIO 2 The residual chlorine concentration of the aqueous solution (measured by the KI method), the results are shown in Figure 8 .

[0131] by the Figure 8 It can be seen that the long-term high retention of NaClO and KClO 2 the residual chlorine concentration of the aqueous solution.

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Abstract

The present invention provides an aqueous solution having a high long-term residual chlorine concentration and excellent disinfection (bactericidal) ability. The aqueous solution is an aqueous solution containing at least one active oxygen selected from the group of hydrohalic acid and its salts, and the hydrohalic acid is selected from the group of hypochlorous acid, chlorous acid, chloric acid and perchloric acid At least one selected, the total amount of substances selected from the hydrohalic acid and its salts contained in the aqueous solution is 10-50000ppm, and the total amount of active oxygen contained in the aqueous solution is 0.1-1000ppm .

Description

technical field [0001] The present invention relates to aqueous solutions. In particular, it relates to a technique for prolonging the life of residual chlorine, which is an indicator of the ability (sterilization power, sterilization power, or oxidizing power) of a disinfectant or washing liquid. Background technique [0002] Hypohalites (especially hypochlorite (ClO - )) aqueous solution is used in disinfection (sterilization) and the like. The oxidative power (disinfection power: germicidal power) of the hypochlorite was evaluated by the concentration of residual hypochlorous acid. The hypochlorous acid concentration was evaluated by the residual chlorine concentration. In addition, the residual chlorine concentration is measured by the iodine method or the DPD (diethyl-p-phenylenediamine) method. [0003] Residual chlorine obtained from hypochlorous acid has a shorter lifespan. The lifetime of this residual chlorine is pH-dependent. In addition, when acidity is for...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A01N59/08
CPCC01B11/12C02F2001/46161A61L2/18C01B11/08C02F2201/46115A01N59/00C02F1/4674C01B11/16C01B11/04
Inventor 伊藤秀孝
Owner イーデオ