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Plastic material prepared by using waste thermosetting foam plastics and preparation method thereof

A technology of foam plastics and plastic materials, applied in plastic recycling, recycling technology, reagents, etc., can solve the problems of unsatisfactory recycling, high energy consumption, and unsatisfactory recycling status

Inactive Publication Date: 2011-03-09
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, China's recycling and reuse of waste plastics is not ideal. Most of them are simply used, with low technical level and lack of market competitiveness. ", the application date is March 28, 2000, the application number is 00113344.6, the publication date is October 3, 2001, and the publication number is CN1315488; (2) Chinese patent "cold-proof heat insulation board made of waste plastics", The application date is August 3, 1999, the application number is 99218182.8, the publication date is May 23, 2001, and the publication number is CN2431332; (3) Chinese patent "waste plastic and plant fiber composite material", the application date is 1989 On October 15th, the application number was 89107953.X, and the publication date was May 1, 1991, and the publication number was CN1051008; (4) Chinese patent "radiation cross-linked 150°C flame-retardant polyolefin heat-shrinkable material", application date On December 24, 1999, the application number is 99125748.0, and the publication date is June 21, 2000, and the publication number is CN1257090; (5) Chinese patent "Method for making low-pressure heat-shrinkable material from waste plastics", the application date is 2002 On September 24, 2003, the application number was 02133015.8, and the publication date was March 12, 2003, and the publication number was CN1401704
[0003] According to the above patents, most waste plastics are used to make composite materials such as plastic wood and produce lubricating oil, gasoline, diesel oil, heat shrinkable materials, etc. after thermal cracking. The preparation method is complicated, the technical level is low, the energy consumption is large, and it is easy to cause secondary waste. secondary pollution
At present, the recycling status of thermosetting foam plastic waste in my country is not ideal. Most of them only develop and utilize thermoplastic foam plastics that are easy to regenerate, and there is a lack of recycling methods for thermosetting foam plastics that are difficult to regenerate.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0065] (1) 68g of waste thermosetting SAN foamed plastics powder, 10g of recycled rubber powder, and 5g of epoxy resin powder E-20 are put into a mixer and fully mixed;

[0066] (2) Add dioctyl phthalate 6g, brominated epoxy resin 5g, carbon black 3g, 1g polyamide 650, silane coupling agent 1g, 0.5g antioxidant 1010 and 0.5g light aging to the mixer in turn Stir with the agent GW-540, and each time the aforementioned additive is added, the next additive must be added in sequence after mixing evenly;

[0067] (3) Mix the powder in step (2) and stir evenly to obtain a plastic material.

[0068] The waste thermosetting SAN foam plastic powder is 20 mesh powder, and the recovered rubber powder is 20 mesh butadiene rubber powder. The prepared plastic material is sealed and packaged, and can be formed by traditional hot pressing after heating to 160°C. 2 Impact strength, 30MPa compressive strength, 25MPa bending strength and 270MPa Young's modulus.

Embodiment 2

[0070] (1) 60g of waste thermosetting phenolic foamed plastics powder, 15g of reclaimed rubber powder, and 7g of epoxy resin powder E-20 are put into a mixer and fully mixed;

[0071] (2) add chlorinated paraffin 5g, triphenol phosphate 5g, carbon black 3g, 1g polyamide 651, silane coupling agent 1g, 1g antioxidant 1010 and 1g light aging agent GW-540 to stirrer successively and stir, wherein each When adding one of the aforementioned additives, wait until the mixture is uniform before adding the next additive in sequence;

[0072] (3) Mix the powder in step (2) and stir evenly to obtain a plastic material.

[0073] The waste thermosetting phenolic foam plastic powder is 100 mesh powder, and the recycled rubber powder is 100 mesh neoprene powder. The prepared plastic material is sealed and packaged. After heating to 140°C, it can be formed by traditional thermocompression. The thermoformed sheet has a density of 15kJ / m 2 Impact strength, 50MPa compressive strength, 30MPa ben...

Embodiment 3

[0075] (1) Put 60g of waste thermosetting polyurethane foam plastic powder and 5g of butyl rubber powder into a mixer and mix well:

[0076] (2) Add 8 g of chlorinated paraffin, 5 g of triphenol phosphate, 0.5 g of silane coupling agent, 0.8 g of antioxidant 1010, and 0.2 g of light-resistant aging agent GW-540 into the mixer in turn, and stir for every addition of the aforementioned auxiliary agent Wait until the mixture is uniform before adding the next additive in sequence;

[0077] (3) Mix the powder in step (2) and stir evenly to obtain a plastic material.

[0078] The waste thermosetting polyurethane foam plastic powder is 500 mesh powder, and the recycled rubber powder is 80 mesh butyl rubber powder. The prepared plastic material is sealed and packaged, and can be formed by traditional hot pressing after heating to 100°C. 2 Impact strength, 50MPa compressive strength, 40MPa bending strength and 350MPa Young's modulus.

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Abstract

The invention discloses a plastic material prepared by waste thermosetting foam plastics and a preparation method thereof. The plastic material is prepared by uniformly stirring the following raw materials, wherein the raw materials comprise the following components in parts by mass: 50-80 parts of waste thermosetting foam plastic powder, 0-20 parts of recycled rubber powder, 0-10 parts of solid ethoxyline resin powder, 5-10 parts of plasticizing agent, 2-5 parts of flame retardant agent, 0-3 parts of pigment, 0-1 parts of curing agent, 0.5-1 part of silane coupling agent, 0.5-1 part of antioxidant 1010 and 0.2-1 part of aging resistant agent GW-540. The compression plastic material prepared by the formed materials solves the problem of recycling difficultly regenerated waste thermosetting foam plastic powder and can be made into various plates in a hot-press way without adhesive, and a product has favorable performance and the characteristics of safety, environmental protection, water prevention and flame resistance.

Description

technical field [0001] The invention relates to a plastic material and a preparation method thereof, more specifically, to a plastic material prepared from waste thermosetting foam plastics and a preparation method thereof. Background technique [0002] The rapid development of the manufacturing industry and the automobile industry has brought convenience to people's lives, but it has also brought a large amount of thermosetting foam plastic waste, which has caused great pressure on the ecological environment. How to improve the comprehensive recycling efficiency of plastic products and the quality of recycled products, reduce plastic solid waste and control environmental pollution in the recycling process has become a worldwide issue. At present, China's recycling and reuse of waste plastics is not ideal. Most of them are simply used, with low technical level and lack of market competitiveness. ", the application date is March 28, 2000, the application number is 00113344.6...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L101/00C08K13/02C08J11/04C08L27/06C08L75/04C08L25/12C08L61/06
CPCY02P20/143Y02W30/62
Inventor 刘晓非李琳
Owner TIANJIN UNIV