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Process method for preparing glazed floor tiles from metallurgical comprehensive wastewater sedimentation sludge

A technology of comprehensive wastewater and process method, which is applied in the field of preparation of building decoration materials, can solve the problems of environmental secondary pollution, land occupation, and no report of metallurgical comprehensive wastewater deposition sludge, etc., and achieves reduced production costs, low water absorption, and good quality. Effects of Environmental Benefits and Economic Benefits

Inactive Publication Date: 2012-02-22
武钢集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The formed metallurgical comprehensive wastewater deposits and sludge are piled up in large quantities, not only occupying land, but also causing serious secondary pollution to the environment
Although there are many reports on the resource utilization of the above-mentioned domestic sewage sludge or sludge with low heavy metal content, there is no relevant report on the resource utilization of metallurgical comprehensive wastewater sedimentation sludge generated in the production of metallurgical industry.

Method used

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  • Process method for preparing glazed floor tiles from metallurgical comprehensive wastewater sedimentation sludge
  • Process method for preparing glazed floor tiles from metallurgical comprehensive wastewater sedimentation sludge
  • Process method for preparing glazed floor tiles from metallurgical comprehensive wastewater sedimentation sludge

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Ingredients:

[0023] Metallurgical comprehensive wastewater sedimentary sludge powder made after drying the sedimentary sludge of comprehensive metallurgical wastewater: 80 parts by weight

[0024] Modifier D: 10 parts by weight, wherein the mixing weight ratio of potassium feldspar and spodumene is 5:1

[0025] Modifier C: 10 parts by weight of diopside

[0026] Process method:

[0027] refer to figure 1 , the above ingredients are mixed and sent to a ball mill for mixing and granulation to make fine and uniform particles with a particle size of 0.5 mm and then aged for 48 hours; then sent to a mold for compression molding; after drying, bisque firing and glazing are carried out to obtain The adobe of colored glaze floor tiles is sent to a roller kiln for firing at a firing temperature of 1120°C with a cycle of 60 minutes, so that the adobes can fully undergo physical and chemical changes to obtain colored glaze floor tiles.

[0028] The samples of the above-menti...

Embodiment 2

[0031] Ingredients:

[0032] Metallurgical comprehensive wastewater sedimentary sludge powder made after drying the sedimentary sludge of comprehensive metallurgical wastewater: 85 parts by weight

[0033] Modifier D: 5 parts by weight, wherein the mixing weight ratio of potassium feldspar and spodumene is 6:1

[0034] Modifier C: 10 parts by weight of diopside

[0035] Process method:

[0036] refer to figure 1 , the above ingredients are mixed and sent to a ball mill for mixing and granulation to make fine and uniform particles with a particle size of 0.6 mm and then stale for 24 hours; then sent to a mold for compression molding; after drying, bisque firing and glazing are carried out to obtain The adobe of the colored glazed floor tile is sent to a roller kiln for firing at a firing temperature of 1000°C with a cycle of 70 minutes, so that the adobe can fully undergo physical and chemical changes to obtain a colored glazed floor tile.

Embodiment 3

[0038] Ingredients:

[0039] Metallurgical comprehensive wastewater sedimentary sludge powder made after drying the sedimentary sludge of comprehensive metallurgical wastewater: 80 parts by weight

[0040] Modifier D: 5 parts by weight, wherein the mixing weight ratio of potassium feldspar and spodumene is 6:1

[0041] Modifier C: 15 parts by weight of diopside

[0042] Process method:

[0043] refer to figure 1 , the above ingredients are mixed and sent to a ball mill for mixing and granulation to make fine and uniform particles with a particle size of 0.6 mm and then aged for 36 hours; then sent to a mold for compression molding; after drying, bisque firing and glazing are carried out to obtain The adobe of the colored glazed floor tile is sent to a roller kiln for firing at a firing temperature of 1150°C with a cycle of 65 minutes, so that the adobe can undergo physical and chemical changes sufficiently to obtain a colored glazed floor tile.

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Abstract

The invention relates to a process method for preparing colored glaze floor tiles from metallurgical comprehensive wastewater deposition sludge, which solves the problems of large accumulation of metallurgical comprehensive wastewater deposition sludge, heavy environmental pollution, and ineffective resource utilization in the existing metallurgical industry. The technical solution is to mix 80-85wt% of metallurgical comprehensive wastewater deposition sludge powder with 5-10wt% of potassium feldspar and spodumene mixture as modifier D, and 10-15wt% of diopside as modifier C Carry out granulation, aging, compression molding, drying, bisque firing and glazing to obtain the adobe of colored glaze floor tiles, and then fire the adobe at high temperature to obtain colored glaze floor tiles, wherein, as the modifier D potassium feldspar and spodumene mixed The weight ratio is 5-6:1. The invention has the advantages of simple process, low production cost, high silt utilization and environmental friendliness, and the prepared glazed floor tiles have high strength and excellent performances, far exceeding JC / T765-8896 national building material industry standards.

Description

technical field [0001] The invention relates to a preparation method of a building decoration material, in particular to a process method for preparing colored glaze floor tiles by using the sludge deposited in metallurgical industry as a raw material. Background technique [0002] A large number of researches have been carried out at home and abroad on the resource utilization of sludge with different characteristics. For example, using East Lake bottom mud and fly ash as the main raw materials, supplemented by pegmatite granite and quartz additives, the porcelain bricks with water absorption and rupture modulus meeting the relevant national quality standards are fired (Journal of China University of Geosciences, 2004, 29( 03): 347-351.), but its bottom mud content is low, about 60%, so that it is necessary to increase the amount of auxiliary materials added, making the production cost higher. Application No. 200610031101. The dewatered sludge of urban sewage is dried and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/00C04B35/622
Inventor 吴高明肖波杜健敏吴建锋张大华胡智泉吴声浩玉晖蒋豪杰朱静
Owner 武钢集团有限公司