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Triphenylamine derivative, a method for manufacturing triphenylamine derivates and electronic photographic photoreceptor

A manufacturing method and electrophotography technology, applied in the direction of chemical instruments and methods, preparation of organic compounds, preparation of amino hydroxyl compounds, etc., can solve the problem of crystallization of photosensitive layer, poor dispersion, insufficient compatibility of solvent-soluble binder resin, It is difficult to obtain the sensitivity characteristics and other issues, to achieve excellent sensitivity characteristics, improve charge transport efficiency, and improve the effect of charge movement

Inactive Publication Date: 2010-03-24
KYOCERA DOCUMENT SOLUTIONS INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0008] However, the triphenylamine derivatives (HTM-A~B) represented by formulas (a)~(b) are methyl or methoxy groups due to the substituents on the para-position of the arylamine groups, so the solubility and Insufficient compatibility with binder resin
[0009] From this, it was found that when such a triphenylamine derivative is used as a hole-transporting agent for an electrophotographic photoreceptor, crystallization and poor dispersion in the photosensitive layer tend to occur, so it is difficult to obtain desired sensitivity characteristics.

Method used

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  • Triphenylamine derivative, a method for manufacturing triphenylamine derivates and electronic photographic photoreceptor
  • Triphenylamine derivative, a method for manufacturing triphenylamine derivates and electronic photographic photoreceptor
  • Triphenylamine derivative, a method for manufacturing triphenylamine derivates and electronic photographic photoreceptor

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no. 1 approach

[0058] The first embodiment is a triphenylamine derivative represented by the following general formula (1).

[0059]

[0060] (In general formula (1), R 1 ~R 13 independently hydrogen atom, alkyl group with 1 to 8 carbon atoms, alkoxy group with 1 to 8 carbon atoms, phenoxy group, aryl group with 6 to 20 carbon atoms or aryl group with 7 to 20 carbon atoms Alkyl group, Ar may have an alkyl group with 1 to 8 carbon atoms, an alkoxy group with 1 to 8 carbon atoms, a hydrocarbon ring with 3 to 14 carbon atoms, or a heterocyclic ring with 3 to 10 membered rings as a substituent In the aryl group having 6 to 20 carbon atoms, the number of substituents n is an integer of 0 to 4, and the repetition numbers o and p are independently integers of 0 to 1. )

[0061] Hereinafter, the triphenylamine derivative which has the specific structure of 1st Embodiment is demonstrated concretely.

[0062] The triphenylamine derivative of the first embodiment is characterized in that it is a...

no. 2 approach

[0106] The second embodiment is a method for producing triphenylamine derivatives, which is characterized in that it is a method for producing triphenylamine derivatives represented by the general formula (1) of the first embodiment, including performing the process represented by the following reaction formula (1) The process of reaction.

[0107]

[0108] (In general formula (2) and (5), X 1 and x 2 They are independently independent halogen atoms, and the other substituents in the general formulas (2) to (5) are the same as those described in the general formula (1). )

[0109] Hereinafter, the second embodiment will be specifically described focusing on differences from those described in the first embodiment.

[0110] 1. Preparation process

[0111] This preparatory step is a step for obtaining compounds represented by the following general formulas (2) and (5) as material substances in the reaction formula (1).

[0112] In addition, since the compounds represente...

no. 3 approach

[0165] A third embodiment is an electrophotographic photoreceptor having a photosensitive layer on a substrate, wherein the photosensitive layer contains a triphenylamine derivative represented by the general formula (1).

[0166] Hereinafter, the third embodiment will be specifically described by dividing it into a single-layer electrophotographic photoreceptor and a laminated electrophotographic photoreceptor, focusing on the differences from those described in the first embodiment and the second embodiment.

[0167] 1. Single-layer electrophotographic photoreceptor

[0168] The electrophotographic photoreceptor containing the triphenylamine derivative according to the first to second embodiments is preferably constituted as a single-layer electrophotographic photoreceptor.

[0169] The reason is that, by constituting the electrophotographic photoreceptor containing the triphenylamine derivatives according to the first to second embodiments as a single-layer electrophotographi...

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Abstract

The present invention provides a triphenylamine derivative having excellent solubilization of a solvent and capable of dissolving with binding resin and improving effectively light sensitivity when the triphenylamine derivative is used as a hole transport agent of electronic photographic photoreceptor, a method for manufacturing the triphenylamine derivative and an electronic photographic photoreceptor. The invention employs triphenylamine derivative represented by formula (1) and (6).

Description

technical field [0001] The present invention relates to a triphenylamine derivative, a method for producing the same, and an electrophotographic photoreceptor. In particular, it relates to a triphenylamine derivative which has excellent solubility in solvents and compatibility with binder resins, and is useful for effectively improving sensitivity characteristics by being used as a hole-transporting agent for electrophotographic photoreceptors, and its Manufacturing method and electrophotographic photoreceptor. Background technique [0002] Currently, an organic photoreceptor (OPC) composed of a binder resin (binder resin), a charge generating agent, a charge transporting agent (hole transporting agent, electron transporting agent), etc. photoreceptor. Compared with conventional inorganic photoreceptors, such an organic photoreceptor is easier to manufacture and has a variety of options for photoreceptor materials, so it has the advantage of a greater degree of freedom in ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C217/92C07C213/08G03G5/06
Inventor 冈田英树菅井章雄洼嶋大辅
Owner KYOCERA DOCUMENT SOLUTIONS INC
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