Sheet-like article and method for producing the same

A manufacturing method and sheet-like technology, applied in the directions of papermaking, plant fibers, textiles, and papermaking, etc., can solve the problems of difficult flakes, difficult carbon nanotube conductivity, and inability to form carbon nanotubes.

Inactive Publication Date: 2010-09-08
TOKUSHU TOKAI PAPER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the immobilization method proposed here, since aggregates of the carbon nanotubes themselves are generated at the time of preparation of the liquid slurry, the network of the carbon nanotubes cannot be formed satisfactorily in the sheet.
Therefore, since it is difficult to give full play to the conductivity of carbon nanotubes, and in order to reduce the conductivity of the flakes, a large amount of carbon nanotubes must be added
[0009] As described above, it is difficult to form sheets containing carbon nanotubes and / or carbon nanohorns having extremely effective electrical properties, such as conductive materials, electromagnetic wave shields, microwave absorbing and exothermic bodies, or electrodes, using conventional techniques.

Method used

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  • Sheet-like article and method for producing the same
  • Sheet-like article and method for producing the same
  • Sheet-like article and method for producing the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0069] Disperse 50% by mass of hardwood bleached kraft pulp and 50% by mass of coniferous bleached kraft pulp in water, and beat them with a double-motion disc refiner to prepare a raw material liquid slurry with a beating degree of 350 ml according to Canadian standard freeness. Next, after adding and mixing 2% by mass of cationized starch (trade name "Neotack L-1", manufactured by Nippon Food Processing Co., Ltd.) as a fixative to the mass of pulp, 5% by mass was mixed in terms of solid content concentration relative to the mass of pulp. % of the anionic surfactant-type carbon nanotube dispersion liquid obtained by [dispersion method 1] was prepared as a raw material slurry. Use the raw material slurry to reach 100g / m by wet papermaking method by papermaking wire 2 made into flakes.

Embodiment 2

[0071] Instead of the anionic surfactant-type carbon nanotube dispersion obtained by [dispersion method 1], a cationic surfactant-type carbon nanotube dispersion obtained by [dispersion method 2] was used instead of cationized starch While using 3% by mass of carboxymethyl cellulose, a quantitative 100 g / m was prepared in the same manner as in Example 1. 2 of flakes.

Embodiment 3

[0073] Same as Example 1, except that instead of the anionic surfactant-type carbon nanotube dispersion obtained by [dispersion method 1], a physical dispersion treatment type carbon nanotube dispersion obtained by [dispersion method 3] was used Made a quantitative 100g / m 2 of flakes.

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Abstract

Disclosed is a sheet-like article containing fibers to the surfaces of which carbon nanotubes and / or carbon nanohorns are adhered. Since many carbon nanotubes and / or carbon nanohorns are adhered to the fiber surfaces in a uniformly dispersed state without agglomerating together, the carbon nanotubes and / or carbon nanohorns form a network structure on the fibers. The sheet-like article is preferably obtained by wet-papermaking the fibers and a liquid dispersion of the carbon nanotubes and / or carbon nanohorns. By using fibers mainly containing cellulose fibers, there can be obtained a preferable sheet-like article.

Description

technical field [0001] The present invention relates to a sheet-like object formed by fibers with carbon nanotubes and / or carbon nanohorns attached to the surface and a manufacturing method thereof. The sheet-like object can be used for conductive materials, electromagnetic wave shields, and electromagnetic wave absorbers , microwave absorbing exothermic body, electrode, ultrafilter, planar exothermic body, catalyst carrier, etc. Background technique [0002] Carbon nanotubes or carbon nanohorns have extremely low electrical conductivity characteristics based on their special structure. They are used as conductive materials, electromagnetic wave shields, electromagnetic wave absorbers, microwave absorbers, electrodes, ultrafilters, Materials such as planar heat sinks have attracted attention. Therefore, several flakes containing carbon nanotubes or carbon nanohorns have also been investigated. [0003] For example, in Patent Document 1, it is proposed to use carbon fiber a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H21/14C01B31/02D06M11/74D21H13/50D21H15/12D06M101/06
CPCD21H13/50D21H15/12D21H21/14B82Y40/00D06M11/74D06M23/08D06M2101/06D10B2505/04D10B2201/00
Inventor 秋山宏介今井将德
Owner TOKUSHU TOKAI PAPER
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