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Method of producing an optical device

A technology of optical devices and porous films, applied in the direction of optical components, optics, instruments, etc., can solve the problems of reduced density, reduced thickness, and inability to obtain optical characteristics, and achieve low-cost effects

Inactive Publication Date: 2011-06-01
CANON KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

With this approach, a small portion of the light-incident side of the film dissolves in water and makes the density lower
However, since this method only reduces the density in the portion of the film near the surface and not in the substrate-side portion of the film, it is difficult to form a film with a lower refractive index by this method
[0010] In each of the above-mentioned water immersion treatment methods, the film starts to dissolve from a portion near the film surface and there is a possibility that the thickness is reduced to such an extent that desired optical characteristics cannot be obtained

Method used

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  • Method of producing an optical device
  • Method of producing an optical device
  • Method of producing an optical device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Figure 1A represents the sputter deposition system according to Example 1. The system forms an optical film by sputtering a metal target and reacting the metal with a reactive gas flowing into a chamber of the system. Targets of various shapes may be provided in the target unit 100 depending on usage. Example 1 used a ring-shaped target to form a film, but a target having a different shape may be used to form a film. This sputter deposition system is capable of forming a film while changing the position of the target unit 100 relative to the optical device substrate 101 , which means that thickness unevenness across the entire plane of the substrate 101 can be adjusted as needed.

[0033]In the film forming step, a Mg metal target was set in the target unit 100, a unit having an opening was connected in front of the target unit 100 (substrate side), and the rear side was ground in a vacuum antechamber 102. A synthetic quartz substrate that was machined and had a thic...

Embodiment 2

[0042] MgF was formed on a synthetic quartz substrate by sputtering in the same manner as in Example 1 2 membrane. The resulting porous film was immersed in pure water heated to 50°C. MgF with respect to immersion time 2 The refractive index of the film is shown in Figure 4 middle. As in Example 1, under N as a dry atmosphere 2 The reflectance of the film was measured in a purge atmosphere, and the refractive index was calculated from the measured reflectance.

[0043] Depend on Figure 4 The graph of the graph confirms the reduction of the refractive index as in the water immersion treatment of Example 1. It was also confirmed from this graph that the rate of decrease in the refractive index was improved by increasing the temperature of the liquid in which the film was immersed.

Embodiment 3

[0045] A synthetic quartz substrate ground on each side and having a thickness of 2 mm was prepared. Sputtering is used to form a dense six-layer film on each side of the substrate in which MgF 2 membrane and LaF 3 The films are stacked alternately with each other. On the six-layer film on each side of the substrate, MgF 2 A film is formed as the topmost layer. Then, using a spectroscope to measure the N 2 Dry topmost MgF in purging environment 2 Spectral reflectance properties of films to calculate MgF 2 The refractive index of the film. As each six-layer film was formed, the reflectance was measured and the thickness and other properties of the film were calculated. The MgF of Example 1 was formed by building on a film whose properties had been calculated 2 A model of the film, from which the refractive index is calculated by simulation. Calculated topmost MgF 2 The filling factor of the film was 0.72. The absorbance (absorbance) of the film was also measured usin...

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Abstract

An optical device that includes a low refractive index film is produced at a low cost. To attain this object, in a process of producing an optical device that includes a multilayer film in which low refractive index films and high refractive index films are alternately laminated, a porous film is formed on a substrate by a sputtering deposition system which uses a target unit. The porous film is immersed in a liquid to lower the refractive index of the film. By forming in simple steps a low refractive index film that is lower in refractive index than conventionally used films, a high quality optical device can be obtained at a low cost.

Description

technical field [0001] The present invention relates to the preparation of high-quality optical devices including optical films, such as lenses and prisms or mirrors including anti-reflection films. Background technique [0002] The performance requirements of anti-reflection films in recent years include wide incident angle characteristics and wide band. A known method of meeting these requirements is to form multilayer optical films from a variety of materials with different refractive indices. A greater difference in refractive index between the materials used means greater improvement in the optical performance of the multilayer optical film, and results in an optical film whose performance is high for light in the visible range. [0003] In the field of semiconductor lithography (lithography) systems, high integration and high functionality have been developed, and in order to minimize the limit size of the line width, a high NA projection lens is highly designed. As ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B1/11G02B5/02G02B1/115
CPCG02B1/12G02B2207/107G02B1/113Y10T428/24997
Inventor 寺西康治福井慎次坂野溪帅
Owner CANON KK