Novel method for comprehensively treating waste mortar formed by processing photovoltaic cell crystalline silicon

A photovoltaic cell and comprehensive treatment technology, applied in waste treatment, silicon compounds, chemical instruments and methods, etc., can solve problems such as environmental pollution and waste of resources, and achieve the effect of improving efficiency and reducing consumption

Inactive Publication Date: 2011-10-12
尹克胜
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current treatment technology can only recycle the PEG and SiC micropowder, while the most valuable Si micropowder (crystalline silicon cutting debris) is treated as waste because of the chemical reaction during the treatment process, resulting in serious waste of resources and environmental pollution.

Method used

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  • Novel method for comprehensively treating waste mortar formed by processing photovoltaic cell crystalline silicon
  • Novel method for comprehensively treating waste mortar formed by processing photovoltaic cell crystalline silicon
  • Novel method for comprehensively treating waste mortar formed by processing photovoltaic cell crystalline silicon

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Such as figure 1 The hydraulic separation process flow chart of the comprehensive treatment method for photovoltaic cell crystalline silicon processing waste mortar is shown in the flow chart: mixed with 10-40% PEG (polyethylene glycol-abrasive suspending agent), 15-30% SiC micropowder (cutting abrasive), 10- The quaternary mixture system of 1% iron powder (cutting tool wear material) and 65-29% Si micropowder (crystalline silicon cutting debris)——waste mortar, at normal temperature, after centrifugation, filtration, etc., remove it About 80% PEG, then use water as a solvent to wash and remove the PEG adsorbed on the surface of the mixed micropowder, and complete the PEG separation operation in process 1. After further processing, the separated PEG is returned to the crystalline silicon processing process as a product for recycling; the remainder is The ternary sand containing iron powder, SiC micropowder, and Si micropowder enters process 2 for iron removal: in the lat...

Embodiment 2

[0030] Such as figure 2 The airflow sorting process flow chart of the comprehensive treatment method for photovoltaic cell crystalline silicon processing waste mortar is shown in the flow chart: mixed with 1040% PEG (polyethylene glycol-abrasive suspending agent), 15-30% SiC micropowder (cutting abrasive), 10-1% The quaternary mixture system of iron powder (cutting tool wear material) and 65-29% Si micropowder (crystalline silicon cutting debris)—waste mortar, after centrifugation and filtration in process 1, about 80% of it is removed PEG, and then use ethanol as a solvent to wash and remove the PEG adsorbed on the surface of the mixed micropowder to complete the PEG separation operation. After the separated PEG is processed, it is returned to the crystal silicon processing process as a product for recycling, and the solvent is evaporated and condensed for recycling; The ternary sand of iron powder, SiC micropowder, and Si micropowder enters process 2 for iron removal. In th...

Embodiment 3

[0032] Such as image 3The comprehensive treatment method for photovoltaic cell crystalline silicon processing waste mortar is shown in the flow chart of the high-purity micropowder production process: the waste mortar, a quaternary mixture mixed with PEG, SiC, iron, and Si, is subjected to centrifugation, filtration, and solvent washing in process 1. Operation, using methanol as a washing solvent to complete the PEG separation operation, the separated PEG is returned to the crystalline silicon processing process as a product for recycling, and the solvent methanol is evaporated and condensed for recycling; the residue is ternary sand containing iron, SiC, and Si, which enters the process 2 Carry out iron removal operation, use electromagnet to absorb and remove the iron powder; obtain Si and SiC binary sand, send it to process 3 for hydraulic separation: use the hardness, density and particle size of abrasive Si powder and abrasive SiC powder difference, in the hydraulic sedi...

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Abstract

The invention discloses a novel method for comprehensively treating waste mortar formed by processing photovoltaic cell crystalline silicon. Aiming to different physicochemical properties of four components of the waste mortar formed by processing photovoltaic cell crystalline silicon and under the condition of ensuring that Si micropowder is not subjected to a chemical reaction, PEG (Polyethylene Glycol) and iron are separated and recovered; SiC and Si binary sand is treated by adopting various treatment methods to obtain corresponding SiC and Si series products; the SiC and Si micropowder is hydraulically sorted or sorted by air current by utilizing the granularity difference and the density difference of the SiC micropowder and the Si micropowder in the binary sand to obtain SiC micropowder and Si miropowder; the Si miropowder is washed and purified with purified water and reagent-grade inorganic acid to obtain high-purity Si miropowder; the sorted Si miropowder is fed into an electrical furnace for melting and recasting to obtain a silicon cast ingot material; the binary sand is fed into the furnace for melting and recasting to obtain a metallurgical silicon cast ingot material and a Si and SiC mixed cast ingot material; a proper amount of carbon is fed into the binary sand to react and generate SiC; and SiC, Si and Fe ternary sand is fed into the electrical furnace for melting and recasting to obtain a silicoferrite material for metallurgy.

Description

technical field [0001] The invention relates to a new method for comprehensive treatment of waste mortar from processing crystalline silicon of photovoltaic cells, and belongs to the field of comprehensive treatment of waste from processing crystalline silicon of solar photovoltaic cells. Background technique [0002] Solar energy is the only energy source for life on earth and the main energy source for future human beings. Solar cells are the most direct and convenient way to convert solar energy into electrical energy. "Silicon" is one of the most abundant materials on earth. Since scientists discovered the semiconducting properties of crystalline silicon in the 19th century, it has changed almost everything, even human thinking, in today's society. The figure and function of "silicon" can be seen everywhere in our lives. Crystalline silicon solar photovoltaic cells have become The fastest growing industry in the past, its production process can be roughly divided into f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B33/02C01B33/037C01B31/36C10M175/00B09B3/00
CPCY02W30/20
Inventor 尹克胜尹晏生葛现成
Owner 尹克胜
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