Aqueous laminating adhesive for gold and silver cards and preparation method thereof
A water-based laminating adhesive, gold and silver technology, applied in the direction of adhesive types, hydrocarbon copolymer adhesives, ester copolymer adhesives, etc., can solve the problem of insufficient bonding strength, poor post-processing performance, Problems such as poor initial viscosity, to achieve the effect of improving initial viscosity and bonding strength, improving post-processing performance, and improving bonding strength
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Embodiment 1
[0028] This embodiment provides a water-based laminating glue for gold and silver cards, which is a water-based acrylic emulsion. Water is the raw material, and the laminating adhesive with a solid content of 45-55% is prepared through the steps of pre-emulsification, seed reaction, polymerization reaction and compounding;
[0029] Wherein, the monomer in the described raw material comprises hard monomer, soft monomer and the functional monomer containing-COOH,-OH group; Described hard monomer is made of methyl methacrylate (MMA) and styrene ( St) composition; the soft monomer is composed of butyl acrylate (BA) and isooctyl acrylate (EHA); the functional monomer containing -COOH and -OH groups in the monomer is composed of methacrylic acid (MAA) or acrylic acid (AA), any of hydroxyethyl acrylate (HEA) or hydroxypropyl acrylate (HPA), and ethylene glycol diacrylate (EGMA).
[0030] According to the total weight of each raw material of the monomer as 100%, the dosage of each ra...
Embodiment 2
[0045] This embodiment provides a water-based laminating glue, which is a water-based acrylic emulsion, which can be used in the compounding of gold and silver cards. The laminating glue includes:
[0046]
[0047]
[0048] The preparation method of above-mentioned water-based acrylic acid emulsion laminating adhesive is carried out according to the following steps:
[0049] (1) Pre-emulsification: in the emulsification kettle, drop into deionized water accounting for 30% of the total weight of deionized water, emulsifying agent A accounting for 50% of the total weight of emulsifying agent A, accounting for emulsifying agent B of 50% of the total weight of emulsifying agent B and All the monomers were stirred and emulsified for more than 30 minutes to prepare the pre-emulsion;
[0050] (2) Seed reaction: Add deionized water accounting for 55% of the total weight of deionized water, the remaining emulsifier A, the remaining emulsifier B, and buffer into the polymerization...
Embodiment 3
[0054] This embodiment provides a water-based acrylic emulsion laminating adhesive, which can be used in the compounding of gold and silver cards. The laminating adhesive includes:
[0055]
[0056]
[0057] The preparation method of above-mentioned water-based acrylic acid emulsion laminating adhesive is carried out according to the following steps:
[0058] (1) Pre-emulsification: in the emulsification kettle, drop into deionized water accounting for 25% of the total weight of deionized water, emulsifying agent A accounting for 60% of the total weight of emulsifying agent A, accounting for emulsifying agent B of 60% of the total weight of emulsifying agent B and All the monomers were stirred and emulsified for more than 30 minutes to prepare the pre-emulsion;
[0059] (2) Seed reaction: put deionized water accounting for 60% of the total weight of deionized water, the remaining emulsifier A, the remaining emulsifier B, and buffer into the polymerization reactor, start ...
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