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Aqueous laminating adhesive for gold and silver cards and preparation method thereof

A water-based laminating adhesive, gold and silver technology, applied in the direction of adhesive types, hydrocarbon copolymer adhesives, ester copolymer adhesives, etc., can solve the problem of insufficient bonding strength, poor post-processing performance, Problems such as poor initial viscosity, to achieve the effect of improving initial viscosity and bonding strength, improving post-processing performance, and improving bonding strength

Inactive Publication Date: 2011-11-02
BEIJING COMENS YANSHAN TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the various laminating adhesives used in the market are solvent-based laminating adhesives, which require a large amount of toluene solvent, which pollutes the environment and is not good for the physical and mental health of operators.
However, the ordinary emulsion-type laminating adhesives on the market have some defects in the coating of gold and silver cards, mainly manifested in insufficient bonding strength and poor initial viscosity; When the film paper is peeled off, the ink is difficult to remove, and it is prone to delamination; the post-processing performance is not good, and creasing, embossing, and wrinkling or delamination occur during die-cutting, etc.

Method used

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  • Aqueous laminating adhesive for gold and silver cards and preparation method thereof
  • Aqueous laminating adhesive for gold and silver cards and preparation method thereof
  • Aqueous laminating adhesive for gold and silver cards and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] This embodiment provides a water-based laminating glue for gold and silver cards, which is a water-based acrylic emulsion. Water is the raw material, and the laminating adhesive with a solid content of 45-55% is prepared through the steps of pre-emulsification, seed reaction, polymerization reaction and compounding;

[0029] Wherein, the monomer in the described raw material comprises hard monomer, soft monomer and the functional monomer containing-COOH,-OH group; Described hard monomer is made of methyl methacrylate (MMA) and styrene ( St) composition; the soft monomer is composed of butyl acrylate (BA) and isooctyl acrylate (EHA); the functional monomer containing -COOH and -OH groups in the monomer is composed of methacrylic acid (MAA) or acrylic acid (AA), any of hydroxyethyl acrylate (HEA) or hydroxypropyl acrylate (HPA), and ethylene glycol diacrylate (EGMA).

[0030] According to the total weight of each raw material of the monomer as 100%, the dosage of each ra...

Embodiment 2

[0045] This embodiment provides a water-based laminating glue, which is a water-based acrylic emulsion, which can be used in the compounding of gold and silver cards. The laminating glue includes:

[0046]

[0047]

[0048] The preparation method of above-mentioned water-based acrylic acid emulsion laminating adhesive is carried out according to the following steps:

[0049] (1) Pre-emulsification: in the emulsification kettle, drop into deionized water accounting for 30% of the total weight of deionized water, emulsifying agent A accounting for 50% of the total weight of emulsifying agent A, accounting for emulsifying agent B of 50% of the total weight of emulsifying agent B and All the monomers were stirred and emulsified for more than 30 minutes to prepare the pre-emulsion;

[0050] (2) Seed reaction: Add deionized water accounting for 55% of the total weight of deionized water, the remaining emulsifier A, the remaining emulsifier B, and buffer into the polymerization...

Embodiment 3

[0054] This embodiment provides a water-based acrylic emulsion laminating adhesive, which can be used in the compounding of gold and silver cards. The laminating adhesive includes:

[0055]

[0056]

[0057] The preparation method of above-mentioned water-based acrylic acid emulsion laminating adhesive is carried out according to the following steps:

[0058] (1) Pre-emulsification: in the emulsification kettle, drop into deionized water accounting for 25% of the total weight of deionized water, emulsifying agent A accounting for 60% of the total weight of emulsifying agent A, accounting for emulsifying agent B of 60% of the total weight of emulsifying agent B and All the monomers were stirred and emulsified for more than 30 minutes to prepare the pre-emulsion;

[0059] (2) Seed reaction: put deionized water accounting for 60% of the total weight of deionized water, the remaining emulsifier A, the remaining emulsifier B, and buffer into the polymerization reactor, start ...

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Abstract

Belonging to the field of aqueous binder preparation, the invention discloses an aqueous laminating adhesive for gold and silver cards and a preparation method thereof. With a solid content of 45-55%, the laminating adhesive is an aqueous laminating adhesive employing monomers, an emulsifier, an initiator, a buffering agent, a pH conditioning agent, aqueous auxiliary agents and deionized water asthe raw materials, which undergo the steps of pre-emulsification, seed reaction, polymerization and complex formulation. Wherein, the monomers include hard monomers, soft monomers and functional monomers containing -COOH and -OH groups; the hard monomers consist of methyl methacrylate and styrene; the soft monomers consist of butyl acrylate monomer and enthyl hexyl acrylate; the functional monomers containing -COOH and -OH groups are composed of any of methacrylic acid and acrylic acid, any of hydroxyethyl acrylate and hydroxypropyl acrylate, and ethylene glycol diacrylate; the emulsifier is composed of alkyl ether ammonium sulfate and KD AHPS with a ratio of 1:0.4-0.8 by weight.

Description

technical field [0001] The invention relates to the field of adhesive manufacturing, in particular to a water-based laminating adhesive for gold and silver cards and a preparation method thereof. Background technique [0002] Gold and silver cards are obtained by printing a layer of gold and silver ink on the surface of paper. After this printing paper is combined with plastic film, it can obtain special effects of gold and silver. It is used for some high-end gifts, health products, wine, daily necessities, cosmetics Such packaging gives people a very intuitive stimulating effect, makes the packaged goods appear more high-end, and can increase the value of the goods. Therefore, it is widely used in the packaging industry and is an important form of paper packaging. Most of the various laminating adhesives used in the market are solvent-based laminating adhesives, which require a large amount of toluene solvent, which pollutes the environment and is also unfavorable to the p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/08C09J125/14C08F220/18C08F2/24C08F212/08C08F222/14
Inventor 陈小锋沈峰邓煜东
Owner BEIJING COMENS YANSHAN TECH
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